固相好氧反硝化同步去除水中硝酸盐和阿特拉津可行性研究
doi: 10.13205/j.hjgc.201501014
NITROSATION PROCESS CONTROL IN LOW C/N WASTEWATER TREATMENT BY THREE-PHASE BIOLOGICAL FLUIDIZED BED
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摘要: 研究了利用固相好氧反硝化同步去除水中硝酸盐和阿特拉津的可行性。通过释碳性能的比较得出淀粉基颗粒是适宜的反硝化碳源,在间歇式实验中,初始硝态氮浓度为55~60 mg/L时,平均反硝化速率为7.03 mg/(L·h),能有效去除水中的硝酸盐。当水中阿特拉津浓度低于10 mg/L时,对好氧反硝化脱氮没有影响,浓度增加至20 mg/L,对反硝化有抑制作用。在好氧反硝化条件下,阿特拉津初始浓度分别为0.1,1 mg/L时,24 h后去除率分别为93%和94.8%,阿特拉津的去除主要通过吸附作用。Abstract: Combined with partial nitrification and biological fluidized bed,The process was started with low C/N synthetic wastewater,and the influence on the nitration and nitrosation process was studied by the concentration of COD,ammonia nitrogen, DO and pH in sewage. The study showed that a shorter HrT and less seed sludge was better for the growing of biofilm,and could successfully realize the fast start of biological fluidized bed. High concentration of ammonia nitrogen in influent could contribute to the accumulation of nitrite in reactor, but this accumulation was not stable. When pH in reactor was around 7. 5 ~8. 1, amd DO was about 1. 5 ~2. 5 mg /L,the maximum rate of nitrosation could reach 75%,and the ammonia nitrogen removal rate was more than 85%. The concentration of NO- 2 -N and NO- 3 -N in effluent decreased with the increasing concentration of COD in influent. When the concentration of COD in influent was 50 mg /L,the concentration of nitrate reduced sharply and the concentration of nitrite reduced slowly,nitrogen removal by simultaneous nitrification and denitrification occurred in reactor.
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Key words:
- three-phase biological fluidized bed /
- low C/N /
- nitrite /
- partial nitrification
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