负载Cu改性活性炭吸附VOCs性能的研究
doi: 10.13205/j.hjgc.201501022
EFFECT OF ADDITIVE QUANTITY OF STALKS ON H2 S AND NH3 EMISSION DURING KITCHEN WASTE COMPOSTING
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摘要: 采用浸渍焙烧法对活性炭进行铜负载改性,并用于甲苯、乙酸乙酯及甲苯-乙酸乙酯二元混合气体的吸附。结果表明:醋酸铜负载量1.5%时活性炭吸附性能最好,对于单组分气体吸附,改性活性炭对甲苯和乙酸乙酯的吸附量较未改性前分别提高了29.7%和21.3%,穿透时间分别延迟了19.3%、18.6%;对于二元混合气体吸附,改性后活性炭较未改性活性炭对甲苯和乙酸乙酯的吸附量分别提高了19.4%和33.0%。采用BET、SEM、FTIR、XRD等分析表明,铜负载改性后的活性炭比表面积变大、总孔容变大,且铜与VOC的络合作用是改性后吸附量提高的主要原因。Abstract: H2 S and NH3 emissions not only reduced the nutrient content of compost,and caused odor pollution during organic waste composting. The kitchen waste was chosen as the research object,and the corn stalk was taken as the bulking agent. The added proportions ( mass,wet basis) of corn stalk were set as 5% 10% 15% and 20%. The effects of additive quantity of corn stalk on H2 S and NH3 emission in kitchen waste composting were investigated. The results indicated that all compost products met with national sanitation standard and reached maturity according to composting temperature except treatment T4. Poor O2 transfer was the main reason for H2 S production during waste composting. H2 S release occurred mainly within the first two weeks in this study for all treatments. The H2 S emissions decreased with the increase of additive quantity of stalks. The productions of H2 S were reduced by 35. 5% 44. 7% and 64. 2% for T2,T3 and T4 that compared to T1,respectively. The NH3 had a similar trend to that of H2 S. About 62. 2% ~ 72. 2% of the total NH3 released in the high temperature stage for all treatments. The productions of NH3 were reduced by 36. 9% 45. 2% and 76. 3% for T2,T3 and T4 that compared to T1, respectively. Thus adding corn straws can not only promote the kitchen waste compost,decrease H2 S and NH3 emission in the composting process,but also realize the resource utilization of corn straw.
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Key words:
- kitchen waste /
- corn straw /
- composting /
- H2 S
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