多环芳烃类有机污染土作为水泥生料的热解析实验
doi: 10.13205/j.hjgc.201501025
EXPERIMENTAL STUDY ON THE PERFORMANCE OF SLAUGHTERHOUSE SLUDGE COMPOST AND ITS INFLUENCING FACTORS
-
摘要: 采集首钢焦化车间周边土壤,分别进行了TG曲线、素土热处理及生料热处理实验,结果表明:所取土壤中含有多种PAHs类有机污染物,多环芳烃总含量约156.39 mg/kg。PAHs污染土在低于850℃条件下,失重可分为失水、有机物分解及无机碳酸盐分解三个阶段。随着加热温度的增加,素土中的总PAHs去除率升高。将污染土替代水泥硅质原料配制水泥生料,经300℃处理,污染土中PAHs除了萘、苊、二氢苊及蒽外,其他有机物均有残留,说明水泥生料对污染物有一定的吸附作用。600℃处理后,除少量菲残留外,其余有机物基本没有残留。因此,PAHs进入水泥窑协同处置,尤其要考虑生料磨及二级悬浮预热器的烟气中污染物含量。Abstract: An experimental study on composting and utilization of the slaughterhouse sludge around Yibin county was carried out,taking germination index as the reference,to evaluate the effects of temperature,added agents,fillers,pile size,initial pH,carbon to nitrogen ratio and initial moisture content on the degree of compost maturity. The results show that: Compost temperature went up initially and then decreased,getting a peak on the 13th day. The optimistic composting effect could be gained when the temperature reached to 60 ~ 70 ℃ during the high temperature phase. Adding active bacterium agents could greatly enhance the ability of organic matter degradation and shorten the time and improve the fertilizer s performance; Using sawdust as the filling material could promote the process of composting greatly; In order to facilitate rapid decomposition of sludge,the initial pH value should be controlled at about 7. 5,carbon nitrogen ratio ( C/N) is about 25,the initial moisture content of 55%. The study can provide theoretical references for the harmless and economical utilization on slaughterhouse sludge.
-
Key words:
- slaughterhouse sludge /
- composting /
- germination index /
- compost temperature /
- circular economy
点击查看大图
计量
- 文章访问数: 282
- HTML全文浏览量: 6
- PDF下载量: 193
- 被引次数: 0