沸石负载氧化铁吸附剂吸附除磷研究
doi: 10.13205/j.hjgc.201504011
PHOSPHORUS ADSORPTION FROM WASTEWATER BY IRON-OXIDE-COATED-ZEOLITE
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摘要: 采用铁盐溶液蒸发法制备沸石负载氧化铁吸附剂,探讨其对磷的吸附性能。结果表明:随着沸石负载氧化铁吸附剂投加量的增加,单位质量吸附剂对磷的吸附量先升高后降低;磷的去除率随负载铁含量的增加而升高;p H=7时,去除率高达92.6%;吸附剂对磷的去除率受共存离子的影响较小;吸附数值可采用Freundlich等温模型拟合,相关性显著;吸附过程很好地遵循准二级动力学模型;采用Na OH为再生剂效果较好,再生率随着Na OH溶液浓度的提高而提高。Abstract: In this paper,iron-oxide-coated-zeolite has been prepared by using natural zeolite and ferric nitrate. The absorbing effect of IOCZ on phosphorus was discussed. Results showed that: With the increase of the dosage of IOCZ,the adsorption amount first increased and then decreased. The removal rate of phosphorus went up with the increase of iron content. When the pH of solution was 7,the removal rate was 92. 6%. The influence of coexisting ions on phosphorus removal of absorbent was small. The adsorbing data fitted the Freundlich isothermal model and the adsorption process of phosphorus satisfactorily followed the pseudo-second order kinetic model. Using NaOH as regenerating agent had a good performance on regenaration, and the regeneration increased with the concentration of NaOH solution.
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Key words:
- iron-oxide-coated-zeolite /
- phosphorus removal /
- adsorption /
- adsorption reuse
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