光热催化氧化VOCs的研究进展

李娟娟; 张梦; 蔡松财; 于恩琪; 陈儆; 贾宏鹏

doi:10.13205/j.hjgc.202001002

光热催化氧化VOCs的研究进展

doi: 10.13205/j.hjgc.202001002

李娟娟^1,2,
张梦^1,2,
蔡松财^1,2,
于恩琪^1,2,
陈儆³,
贾宏鹏^1,2, ,

1. 中国科学院城市环境研究所, 福建厦门 361021;
2. 中国科学院大学, 北京 100049;
3. 中国科学院海西研究院厦门稀土材料研究所, 福建厦门 361021

基金项目:

国家自然科学基金（21976172）；福建省科技厅引导性项目（2019Y0074）。

详细信息

作者简介:
李娟娟(1984-),女,博士,副研究员,主要研究方向为光驱动催化氧化VOCs。juanjuanli@iue.ac.cn

通讯作者:
贾宏鹏(1977-),男,博士,研究员,主要研究方向为VOCs催化氧化。hpjia@iue.ac.cn

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出版历程
- 收稿日期: 2019-11-25

LIGHT-DRIVEN THERMOCATALYSIS/PHOTO-THERMOCATALYSIS OF VOCs: RECENT ADVANCES AND FUTURE PERSPECTIVES

LI Juan-juan^1,2,
ZHANG Meng^1,2,
CAI Song-cai^1,2,
YU En-qi^1,2,
CHEN Jing³,
JIA Hong-peng^{1,2
, ,}

1. Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China;
3. Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China

摘要

摘要: 挥发性有机污染物（volatile organic compounds，VOCs）是加重大气复合污染的重要前体物之一。催化氧化技术是在催化剂的作用下，将VOCs氧化分解为无毒的CO₂和H₂O，是目前最有效的治理手段之一。综述了国内外VOCs催化氧化技术的研究进展，针对传统的热催化氧化技术的高能耗和光催化净化技术的低效率等问题，重点总结了光热催化剂的设计理念和对其作用机制的认知，展望了VOCs光热催化氧化技术未来的发展应用方向。
- VOCs /
- 催化氧化 /
- 光驱动热催化 /
- 光热协同催化 /
- 催化剂设计
Abstract: Volatile organic compounds (VOCs) is one of the major contributors to air pollution. In particular, catalytic oxidation is generally considered as the most efficient way to entirely decompose the wide range of VOCs into harmless products of CO₂ and H₂O. This review summarizes recent progress of researches into various catalysts for the catalytic destruction of VOCs, and emphatically highlights the scientific understanding in the catalyst design and reaction mechanism of light-driven thermocatalysis/photo-thermocatalysis, based on the traditional thermal catalysis with high energy consumption and the photocatalysis with low quantum efficiency in VOCs purification. Since the direct conversion of renewable clean solar energy into thermal and chemical energy to drive catalytic reaction is highly desirable, this review also presents a broad perspective on the state of strategy research for light-driven photo-thermocatalysis and prospects for strategy research in the future.
- VOCs /
- catalytic oxidation /
- light-driven thermocatalysis /
- light-driven photo-thermocatalysis /
- catalyst design

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参考文献(50)

GEORGE C, AMMANN M, D'ANNA B, et al. Heterogeneous photochemistry in the atmosphere [J]. Chemical Reviews, 2015, 115(10): 4218-4258.

DAI C H, ZHOU Y Y, PENG H, et al. Current progress in remediation of chlorinated volatile organic compounds: a review [J]. Journal of Industrial and Engineering Chemistry, 2018, 62: 106-119.

HE C, CHENG J, ZHANG X, et al. Recent advances in the catalytic oxidation of volatile organic compounds: a review based on pollutant sorts and sources [J]. Chemical Reviews, 2019, 119(7): 4471-4568.

LIOTTA L F. Catalytic oxidation of volatile organic compounds on supported noble metals [J]. Applied Catalysis B-Environmental, 2010, 100(3/4): 403-412.

LIU Y X, DENG J G, XIE S H, et al. Catalytic removal of volatile organic compounds using ordered porous transition metal oxide and supported noble metal catalysts [J]. Chinese Journal of Catalysis, 2016, 37(8): 1193-1205.

TANG W X, LIU G, LI D Y, et al. Design and synthesis of porous non-noble metal oxides for catalytic removal of VOCs [J]. Science China-Chemistry, 2015, 58(9): 1359-1366.

CHEN J, JIANG M Z, XU W J, et al. Incorporating Mn cation as anchor to atomically disperse Pt on TiO₂ for low-temperature removal of formaldehyde [J]. Applied Catalysis B-Environmental, 2019, 259: 118013-118023.

LI H J, QI G S, TANA, ZHANG X J, et al. Low-temperature oxidation of ethanol over a Mn_0.6Ce_0.4O₂ mixed oxide [J]. Applied Catalysis B-Environmental, 2011, 103(1): 54-61.

NIU J R, DENG J G, LIU W, et al. Nanosized perovskite-type oxides La_1-xSr_xMO_3-δ (M=CO, Mn; x=0, 0.4) for the catalytic removal of ethylacetate [J]. Catalysis Today, 2007, 126: 420-429.

SEDJAME H J, FONTAINE C, LAFAYE G, et al. On the promoting effect of the addition of ceria to platinum based alumina catalysts for VOCs oxidation [J]. Applied Catalysis B-Environmental, 2014, 144: 233-242.

HOU J T, LIU L L, LI Y Z, et al. Tuning the K⁺ concentration in the tunnel of OMS-2 nanorods leads to a significant enhancement of the catalytic activity for benzene oxidation [J]. Environmental Science & Technology, 2013, 47(23): 13730-13736.

CHEN X, CHEN X, CAI S C, et al. Catalytic combustion of toluene over mesoporous Cr₂O₃-supported platinum catalysts prepared by in situ pyrolysis of MOFs [J]. Chemical Engineering Journal, 2018, 334: 768-779.

CHEN J, CHEN X, XU W J, et al. Hydrolysis driving redox reaction to synthesize Mn-Fe binary oxides as highly active catalysts for the removal of toluene [J]. Chemical Engineering Journal, 2017, 330: 281-293.

WANG X Y, KANG Q, LI D. Catalytic combustion of chlorobenzene over MnO_x-CeO₂ mixed oxide catalysts [J]. Applied Catalysis B-Environmental, 2009, 86: 166-175.

DE RIVAS B, LOPEZ-FONSECA R, JIMENEZ-GONZALEZ C, et al. Synthesis, characterisation and catalytic performance of nanocrystalline Co₃O₄ for gas-phase chlorinated VOC abatement [J]. Journal of Catalysis, 2011, 281: 88-97.

ARMAROLI N, BALZANI V. The future of energy supply: challenges and opportunities [J]. Angewandte Chemie-International Edition, 2007, 46: 52-66.

LI J J, CAI S C, XU Z, et al. Solvothermal syntheses of Si and Zn co-doped TiO₂ with enhanced electron-hole separation and efficient photodegradation of gaseous toluene under visible-light [J]. Journal of Hazardous Materials, 2017, 325: 261-270.

LI J J, WENG B, CAI S C, et al. Efficient promotion of charge transfer and separation in hydrogenated TiO₂/WO₃ with rich surface-oxygen-vacancies for photodecomposition of gaseous toluene [J]. Journal of Hazardous Materials, 2018, 342: 661-669.

WANG L Y, XU X C, WU S J, et al. Nonstoichiometric tungsten oxide residing in a 3D nitrogen doped carbon matrix, a composite photocatalyst for oxygen vacancy induced VOC degradation and H₂ production [J]. Catalysis Science & Technology, 2018, 8: 1366-1374.

WANG J M, XU X C, CAO F, et al. In situ fabrication of alpha-Fe₂O₃/CaFe₂O₄ p-n heterojunction with enhanced VOCs photodegradation activity [J]. Advanced Powder Technology, 2019, 30: 590-595.

ZHANG Y H, TANG Z R, FU X Z, et al. Nanocomposite of Ag-AgBr-TiO₂ as a photoactive and durable catalyst for degradation of volatile organic compounds in the gas phase [J]. Applied Catalysis B-Environmental, 2011, 106: 445-452.

TRUC N T T, PHAM T D, THUAN D V, et al. Superior activity of Cu-NiWO₄/g-C₃N₄ Z direct system for photocatalytic decomposition of VOCs in aerosol under visible light [J]. Journal of Alloys and Compounds, 2019, 798: 12-18.

GAO W Q, ZHANG X F, SU X W, et al. Construction of bimetallic Pd-Ag enhanced AgBr/TiO₂ hierarchical nanostructured photocatalytic hybrid capillary tubes and devices for continuous photocatalytic degradation of VOCs [J]. Chemical Engineering Journal, 2018, 346: 77-84.

LIU H L, MA Y P, CHEN J Y, et al. Highly efficient visible-light-driven photocatalytic degradation of VOCs by CO₂-assisted synthesized mesoporous carbon confined mixed-phase TiO₂ nanocomposites derived from MOFs [J]. Applied Catalysis B-Environmental, 2019, 250: 337-346.

HU Y, LI D Z, ZHENG Y,et al. BiVO₄/TiO₂ nanocrystalline heterostructure: a wide spectrum responsive photocatalyst towards the highly efficient decomposition of gaseous benzene [J]. Applied Catalysis B-Environmental, 2011, 104: 30-36.

DAO V D, SON L T, NGUYEN T D,et al. Superior visible light photocatalytic activity of g-C₃N₄/NiWO₄ direct Z system for degradation of gaseous toluene [J]. Journal of Solid State Chemistry, 2019, 272: 62-68.

CHEN X, CAI S C, YU E Q,et al. Photothermocatalytic performance of ACo₂O₄ type spinel with light-enhanced mobilizable active oxygen species for toluene oxidation [J]. Applied Surface Science, 2019, 484: 479-488.

LI J J, CAI S C, YU E Q,et al. Efficient infrared light promoted degradation of volatile organic compounds over photo-thermal responsive Pt-rGO-TiO₂ composites [J]. Applied Catalysis B-Environmental, 2018, 233: 260-271.

LI J J, CAI S C, CHEN X, et al. Engineering rGO nanosheets-adsorption layer supported Pt nanoparticles to enhance photo-thermal catalytic activity under light irradiation [J]. Journal of Materials Chemistry A, 2019, 7: 11985-11995.

MENG X G, LIU L Q, OUYANG S X,et al. Nanometals for Solar-to-Chemical Energy Conversion: from Semiconductor-Based Photocatalysis to Plasmon-Mediated Photocatalysis and Photo-Thermocatalysis [J]. Advanced Materials, 2016, 28: 6781-6803.

CAI S C, LI J J, YU E Q, et al. Strong photothermal effect of plasmonic Pt nanoparticles for efficient degradation of volatile organic compounds under solar light irradiation [J]. ACS Applied Nano Materials, 2018, 1: 6368-6377

HOU J T, LI Y Z, MAO M Y, et al. Full solar spectrum light driven thermocatalysis with extremely high efficiency on nanostructured Ce ion substituted OMS-2 catalyst for VOCs purification [J]. Nanoscale, 2015, 7(6): 2633-2640.

HOU J T, LI Y Z, MAO M Y,et al. The effect of Ce ion substituted OMS-2 nanostructure in catalytic activity for benzene oxidation [J]. Nanoscale, 2014, 6(24): 15048-15058.

LI J J, YU E Q, CAI S C, et al. Noble metal free, CeO₂/LaMnO₃ hybrid achieving efficient photo-thermal catalytic decomposition of volatile organic compounds under IR light [J]. Applied Catalysis B-Environmental, 2019, 240: 141-152.

XIE X, LI Y Z, YANG Y, CHEN C,et al. UV-Vis-IR driven thermocatalytic activity of OMS-2/SnO₂ nanocomposite significantly enhanced by novel photoactivation and synergetic photocatalysis-thermocatalysis [J]. Applied Surface Science, 2018, 462: 590-597.

LI Y, LAN L, SHI Z K, et al. Defects lead to a massive enhancement in the UV-Vis-IR driven thermocatalytic activity of Co₃O₄ mesoporous nanorods [J]. Journal of Materials Chemistry A, 2018, 6: 7194-7205.

YANG Y, LI Y Z, MAO M Y, et al. UV-Visible-Infrared Light Driven Thermocatalysis for Environmental Purification on Ramsdellite MnO₂ Hollow Spheres Considerably Promoted by a Novel Photoactivation [J]. ACS Applied Materials & Interfaces, 2017, 9(3): 2350-2357.

MAO M Y, LI Y Z, LV H Q, et al. Efficient UV-vis-IR light-driven thermocatalytic purification of benzene on a Pt/CeO₂ nanocomposite significantly promoted by hot electron-induced photoactivation [J]. Environmental Science-Nano, 2017, 4: 373-384.

LAN L, LI Y Z, ZENG M,et al. Efficient UV-vis-infrared light-driven catalytic abatement of benzene on amorphous manganese oxide supported on anatase TiO₂ nanosheet with dominant {001} facets promoted by a photothermocatalytic synergetic effect [J]. Applied Catalysis B-Environmental, 2017, 203: 494-504.

REN L, MAO M Y, LI Y Z,et al. Novel photothermocatalytic synergetic effect leads to high catalytic activity and excellent durability of anatase TiO₂ nanosheets with dominant {001} facets for benzene abatement [J]. Applied Catalysis B-Environmental, 2016, 198: 303-310.

CHEN J, LI Y Z, FANG S M, et al. UV-Vis-infrared light-driven thermocatalytic abatement of benzene on Fe doped OMS-2 nanorods enhanced by a novel photoactivation [J]. Chemical Engineering Journal, 2018, 332: 205-215.

YANG Y, LI Y Z, ZHANG Q,et al. Novel photoactivation and solar-light-driven thermocatalysis on epsilon-MnO₂ nanosheets lead to highly efficient catalytic abatement of ethyl acetate without acetaldehyde as unfavorable by-product [J]. Journal of Materials Chemistry A, 2018, 6: 14195-14206.

ZENG M, LI Y Z, MAO M Y, et al. Synergetic Effect between Photocatalysis on TiO₂ and Thermocatalysis on CeO₂ for Gas-Phase Oxidation of Benzene on TiO₂/CeO₂ Nanocomposites [J]. ACS Catalysis, 2015(5): 3278-3286.

SHI Z K, LAN L, LI Y Z, et al. Co₃O₄/TiO₂ Nanocomposite formation leads to improvement in ultraviolet-visible-infrared-driven thermocatalytic activity due to photoactivation and photocatalysis-thermocatalysis Synergetic Effect [J]. ACS Sustainable Chemistry & Engineering, 2018(6): 16503-16514.

MA Y, LI Y Z, MAO M Y, et al. Synergetic effect between photocatalysis on TiO₂ and solar light-driven thermocatalysis on MnO_x for benzene purification on MnO_x/TiO₂ nanocomposites [J]. Journal of Materials Chemistry A, 2015(3): 5509-5516.

ZHENG Y, WANG W, JIANG D,et al. Ultrathin mesoporous Co₃O₄ nanosheets with excellent photo-/thermo-catalytic activity [J]. Journal of Materials Chemistry A, 2015,4(1): 105-112.

LI Y Z, HUANG J C, PENG T,et al. Photothermocatalytic synergetic effect leads to high efficient detoxification of benzene on TiO₂ and Pt/TiO₂ nanocomposite [J]. Chemcatchem, 2010,2(9): 1082-1087.

ZOU N M, CHEN G Q, MAO X W,et al. Imaging catalytic hotspots on single plasmonic nanostructures via correlated super-resolution and electron microscopy [J]. ACS Nano, 2018(12): 5570-5579.

TAN T H, SCOTT J, NG Y H, et al. Understanding plasmon and band gap photoexcitation effects on the thermal-catalytic oxidation of ethanol by TiO₂-supported gold [J]. ACS Catalysis, 2016(6): 1870-1879.

CHEN J Y, HE Z G, LI G Y,et al. Visible-light-enhanced photothermocatalytic activity of ABO₃-type perovskites for the decontamination of gaseous styrene [J]. Applied Catalysis B-Environmental, 2017, 209: 146-154.

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