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贵阳市饮用水源地邻苯二甲酸酯污染特征及健康风险

杨沛林,  王济,  王志康,  张广龙,  秦樊鑫

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文章导航 > 环境工程  > 2020 >  38(1): 172-177,27
杨沛林, 王济, 王志康, 张广龙, 秦樊鑫. 贵阳市饮用水源地邻苯二甲酸酯污染特征及健康风险[J]. 环境工程, 2020, 38(1): 172-177,27. doi: 10.13205/j.hjgc.202001028
引用本文: 杨沛林, 王济, 王志康, 张广龙, 秦樊鑫. 贵阳市饮用水源地邻苯二甲酸酯污染特征及健康风险[J]. 环境工程, 2020, 38(1): 172-177,27. doi: 10.13205/j.hjgc.202001028
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YANG Pei-lin, WANG Ji, WANG Zhi-kang, ZHANG Guang-long, QIN Fan-xin. PHTHALATE ESTERS POLLUTION CHARACTERISTICS AND HEALTH RISK OF DRINKING WATER SOURCES IN GUIYANG[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 172-177,27. doi: 10.13205/j.hjgc.202001028
Citation: YANG Pei-lin, WANG Ji, WANG Zhi-kang, ZHANG Guang-long, QIN Fan-xin. PHTHALATE ESTERS POLLUTION CHARACTERISTICS AND HEALTH RISK OF DRINKING WATER SOURCES IN GUIYANG[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(1): 172-177,27. doi: 10.13205/j.hjgc.202001028
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贵阳市饮用水源地邻苯二甲酸酯污染特征及健康风险

doi: 10.13205/j.hjgc.202001028

  • 1. 贵州师范大学, 生命科学学院, 贵阳, 550001;

  • 2. 贵州师范大学, 地理与环境科学学院, 贵阳, 550025;

  • 3. 贵州民族大学, 生态环境工程学院, 贵阳, 550025;

  • 4. 贵阳市环境监测中心站, 贵阳, 550002

基金项目: 

贵州省科技厅基础项目（黔科合基础[2016]1071）；贵州省教育厅拔尖人才项目"四环素与纳米氧化锌共存下对SBR系统活性污泥活性影响机理研究"（黔教合KY字[2017]066）；贵州省科技支撑计划项目"喀斯特地区蔬菜基地农业系统中重金属减控关键技术研究"（黔科合支撑[2017]2580）。

详细信息
    作者简介:

    杨沛林(1992-),男,硕士研究生,主要研究方向为水土污染防治。919791753@qq.com

    通讯作者:

    秦樊鑫(1978-),男,博士,正高级实验师。qinfanxin@gznu.edu.cn

PHTHALATE ESTERS POLLUTION CHARACTERISTICS AND HEALTH RISK OF DRINKING WATER SOURCES IN GUIYANG

  • 1. School of Life Sciences, Guizhou Normal University, Guiyang 550025, China;

  • 2. School of Geography&Environmental Science, Guizhou Normal University, Guiyang 550025, China;

  • 3. College of Ecoenvironmental Engineering, GuizhouMinzu University, Guiyang 550025, Chian;

  • 4. Guiyang Environmental Monitoring Center Station, Guizhou 550002, China

    摘要
  • 摘要: 为了解贵阳市饮用水源地水环境中邻苯二甲酸酯（PAEs）的污染情况，采用三重四级杆串联质谱联用技术（GC/MSMS）对阿哈水库、红枫湖、百花湖水体中PAEs有机污染物进行定量分析。结果显示：研究区域水体中的PAEs主要为邻苯二甲酸二乙酯（DEP）、邻苯二甲酸二丁酯（DBP）、邻苯二甲酸二异丁酯（DIBP）、邻苯二甲酸二（2-乙基）己酯（DEHP）；PAEs在丰水期、平水期、枯水期呈现出不稳定状态；研究区水源地水体中PAEs的致癌和非致癌风险值均低于可接受参考值；健康风险评价模型一计算的健康风险值远低于美国环境保护署（USEPA）、国家辐射防护委员会（ICRP）、瑞典环境保护局等机构的推荐值，评价模型二计算的健康风险值与上述机构接近。贵阳市饮用水源地PAEs未对人体造成健康风险或构成致癌风险，水体中PAE的含量与国内部分饮用水源中PAEs的含量基本上处于同一水平。
    Abstract: To better understand phthalate esters (PAEs) pollution in key areas of drinking water sources in Guiyang, water samples were collected for content analysis, quantitative analysis of organic pollutants of PAEs in Aha Reservoir, Hongfeng Lake and Baihua Lake Waters by triple quadrupole mass spectrometry (GC/MSMS). Results showed that the PAEs in the water of the study area were mainly DEP,DBP, DIBP, DEHP. PAEs were unstable in the wet season, the flat water period and the dry season; the carcinogenic and non-carcinogenic risk values of PAEs in the water source of the study area were lower than the acceptable reference values; the health risk value calculated by Method I was much lower than the recommended values of the USEPA, ICRP and Swedish EPA, etc. The health risk values calculated by Method II was close to the recommended values of the above-mentioned organizations.The PAEs in the drinking water sources of Guiyang did not pose health risks or cancer risk. The content of PAEs in water was basically at the same level as that of some domestic drinking water sources.
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    • 参考文献(41)
  • LI Z H, GERTY G, NANTHI B, et al. Contamination and remediation of phthalic acid esters in agricultural soils in China: a review[J].Agronomy for Sustainable Development,2015,35(2):519-534.
    SUN J T,PAN L L,TSANG D C W,et al.Organic contamination and remediation in the agricultural soils of China: a critical review[J].Science of The Total Environment,2018,615(15):724-740.
    KAPANEN A,STEPHEN J R,BRVGGEMANN J,et al.Diethyl phthalate in compost:ecotoxi-cological effects and response of the microbial com-munity[J].Chemosphere,2007,67(11):2201-2209.
    HAUSER R, CALAFAT A M. Phthalates and human health[J].Occupational and Environmental Medicine,2005,62(11):806-818.
    HAUSER R, MEEKER J D, DUTY S, et al. Altered semen quality in relation to urinary concentrations of phthalate monoester and oxidative metabolites[J].Epidemiology,2006,17(6):682-691.
    FROMME H, BOLTE G, KOCH H M, et al. Occurrence and daily variation of phthalate metabolites in the urine of an adult population[J].International Journal of Hygiene and Environmental Health,2007,210(1):21-33.
    JUAN GABRIEL MARCH,VICTOR CERDÀ.An innovative arrangement for invial membrance-assisted liquid-liquid microextraction:application to the determination of esters phthalic acid in alcoholic beverages by gas chromatography-mass spectrometry[J].Analytical and Bioanalytical Chemistry,2015,407(14):4213-4217.
    SRIVASTAVA ABHINAV,SHARMA VINOD P,TRIPATHI RANU,et al.Occurrence of phthalic acid esters in Gomti River Sediment,India[J].Environmental Monitoring and assessment,2010,169(1):397-406.
    EREMINA N, PASCHKE A, MAZLOVA E A, et al. Distribution of polychlorinated biphenyls, phthalic acid esters, polycyclic aromatic hydrocarbons and organochlorine substances in the Moscow River, Russia[J].Environmental pollution, 2016, 210: 409-418.
    徐怀洲,宋宁慧,张圣虎,等.骆马湖邻苯二甲酸酯分布特征及健康风险评价[J].生态与农村环境学报,2017,33(10):928-934.
    KONG Y L,SHEN J M,CHEN Z L,et al.Profiles and risk assessment of phthalate acid esters(PAEs) in drinking water sources and treatment plants,East China[J].Environmental Science and Pollution Research,2017,24(30):23646-23657.
    田林锋,胡继伟,罗桂林,等.贵州百花湖沉积物重金属稳定性及潜在生态风险性研究[J].环境科学学报,2012,32(4):885-894.
    秦国兵,吴俣学,姚俊杰,等.贵阳市阿哈水库浮游生物量及鲢鳙鱼生物治理的渔产潜力[J].贵州农业科学,2017,45(11): 83-85.
    黄志敏,陈椽,刘之威,等.贵州百花湖夏季浮游植物昼夜垂直分布特征[J].生态学报,2014,34(19):5389-5397.
    李小峰,李秋华,秦好丽,等.百花湖消落带常见植物氮磷钾营养元素含量分布特征研究[J].环境科学报,2013,33(4):1089-1097.
    吕迎春,刘丛强,王仕禄,等.贵州喀斯特水库红枫湖、百花湖ρ(CO2)季节变化研究[J].环境科学,2007,28(12):2674-2681.
    JAWOREK K, CZAPLICKA M. Determination of phthalates in polymer materials-comparison of GC/MS and GC/ECD methods[J].Polimeros, 2013, 23(6): 718-724.
    USEPA,2006.Method 8270D-Semivolatile Organic Compounds by Gas Chormatography/Mass Spectrometry[Z]2007.
    许凯.贵阳市主城区水域及饮用水源地PAEs监测及生态风险评价[D].贵阳:贵州师范大学,2015.
    USEPA.Available in formation on assessment exposure from pesticides in food[R].Washington DC: US Environmental Protection Agency Office of Pesticide Programs,2000:14-16.
    USEPA.Guidelines for Carcinogen Risk Assessment[S].2005.
    US Environmental Protection Agency.Guidelines for exposure assessment[R].Washington DC:Risk Assessment Forum,1992:4-5.
    US Environmental Protection Agency.Risk assessment guidance for superfund: volume I Human health evaluation manual part a,development of risk-based preliminary remediation goals[R].Washington DC: Office of Emergency and Remedial Response,1989:4-12.
    US Environmental Protection Agency.Risk assessment guidance for superfund:volume I Human health evaluation manual part b,development of risk-based preliminary remediation goals[R].Washington DC:Office of Emergency and Remedial Response,1991:51-52.
    USEPA.EPA/540/1-89/002.Risk assessment guidance for superfund.Human health evaluation manual[R].Washington DC:Office of Emergency and Remedial Response,1989.
    张会兴,张征,宋莹.地下水污染健康风险评价理论体系研究[J].环境保护科学,2013,39(3):59-63.
    中华人民共和国卫生部,中国国家标准化管理委员会.GB 5749—2006.生活饮用水卫生标准[S].北京:中国标准出版社,2006.
    马武生,韦林洪,王征远,等.集中式饮用水源地邻苯二甲酸酯类物质分布特征与健康风险评估[J].中国环境监测,2017,33(6):69-77.
    康真,于天一,吕嵩,等.松花江吉林-同江段水源水邻苯二甲酸酯类有机污染物健康风险评价[J].中国卫生工程学,2017,16(4): 445-447

    ,450.
    LIU X W, SHI J H, BO T, et al.Occurrence and risk assessment of selected phthalates in drinking water from waterworks in China[J].Environmental Science and Pollution Research,2015,22(14):10690-10698.
    耿梦娇,昌盛,刘琰,等.滹沱河冲洪积扇深层孔隙水中多环芳烃和酞酸酯的污染水平与饮水健康风险评估[J].中国环境科学,2016,36(12):3824-3830.
    GAO D W,WEN Z D. Phthalate esters in the environment: a critical review of their occurrence,biodegradation,and removal during wastewater treatment processes[J]. Science of the Total Environment,2016,541:986-1001.
    WANG X F, LOU X M, ZHANG N H, et al. Phthalate esters in main source water and drinking water of Zhejiang Province (China):Distribution and health risks[J].Environmental Toxicology Chemistry,2015,34(10):2205-2212.
    白小舰.华南地区典型饮用水源地邻苯二甲酸酯的健康风险评估研究[D].兰州:兰州交通大学,2013.
    USEPA.EPA 50/2-90/001.Technical support document for water quality-based toxics control[R].Washington DC:Office of Water,Regulations and Standards,1991.
    WANG W L, WU Q Y, WANG C, et al. Health risk assessment of phthalate esters (PAEs) in drinking water sources of China[J].Environmental Science and Pollution Research,2015,22(5):3620-3630.
    WHO.Concise International Chemical Assessment Documents(CICADs)[EB/OL].http://www.who.int/ipcs/publications/cicad/,2000.
    US EPA.Provisional Toxicity Factor[EB/OL].http://www.epa.gov/,2003.
    US EPA.Minimal Risk Levels (MRLs) for Hazardous Substances[EB/OL].http://www.atsdr.cdc.gov/mrls/.2007.
    张应华,刘志全,李广贺,等.基于不确定性分析的健康环境风险评价[J].环境科学,2007,28(7):1409-1415.
    王永杰,贾东红,孟庆宝,等.健康风险评价中的不确定性分析[J].环境工程,2003,21(6):66-69.
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