STUDY ON PHOSPHORUS RECOVERY EFFICIENCY USING THREE CRYSTAL SEEDS AND THE PRODUCTS
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摘要: 以CaO、MgO和白云石石灰(D-Lime)为晶种对模拟厌氧消化上清液进行磷回收试验,研究晶种投加量对磷去除效率的影响,分析试验反应动力学和产物表面形态。结果表明:磷浓度为0.645 mmol/L(ρ(P)=20 mg/L)、n(N)/n(P)为8:1、pH为7.80的模拟水中,投加一定量的CaO、MgO和D-Lime进行磷回收试验,磷的去除率在95%以上,试验反应过程符合准一级反应动力学。针对消化上清液中的高浓度常见离子CO32-,当c(CO32-)≥ 10 mmol/L时,其对CaO除磷具有明显抑制作用,而对D-Lime和MgO抑制作用有限。此外,投加晶种中含有Mg2+时会生成磷酸铵镁晶体(magnesium ammonium phosphate,MAP)。Abstract: Removal and recovery of phosphate from simulated supernatant of sewage sludge anaerobic digestion effluent were compared using CaO, MgO and dolemite lime(D-Lime)as the crystal seeds respectively, and the kinetics and the surface morphology of the products were analyzed. The results indicated that the removal rate of phosphate were all over 95% using the three crystal, seeds with the condition of initial phosphorus concentration of 0.645 mmol/L, molar ratio of nitrogen to phosphorus of 8:1, and pH value of 7.80. The phosphorus recovery resction was subject to the first order model. However, The high concentration of CO32- significantly inhibited the phosphorus removal rate while the CaO was used, but the decline of phosphorus removal rate were limited when the crystal seed was MgO or D-Lime. Moreover, the experimental results also demonstrated that MAP crystals could be obtained in the presence of crystal seed containing Mg2+.
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Key words:
- phosphorus recovery /
- crystal seed /
- chemical precipitation /
- kinetics
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