铬污染场地修复技术进展

王兴润; 李磊; 颜湘华; 田永强

doi:10.13205/j.hjgc.202006001

铬污染场地修复技术进展

doi: 10.13205/j.hjgc.202006001

1. 中国环境科学研究院, 北京 100012;
2. 西南大学, 重庆 400715;
3. 四川大学, 成都 610065

基金项目:

国家重点研发计划项目"制革类、铬化工类和电镀类场地污染土壤风险管控与修复技术"(2018YFC1802200)。

详细信息

作者简介:
王兴润(1981-),男,博士,研究员,主要从事铬污染土壤修复研究。wangxr@craes.org.cn

通讯作者:
李磊(1987-),男,博士,副教授,主要从事铬污染土壤修复研究。lilei503@126.com

计量
- 文章访问数: 1221
- HTML全文浏览量: 118
- PDF下载量: 37
- 被引次数: 0
出版历程
- 收稿日期: 2020-04-06

PROGRESS IN REMEDIATION OF CHROMIUM-CONTAMINATED SITES

1. Chinese Research Academy of Environmental Sciences, Beijing 100012, China;
2. Southwest University, Chongqing 400715, China;
3. Sichuan University, Chengdu 610065, China

摘要

摘要: 土壤中六价铬污染主要来源于铬化工、电镀和制革等行业。简述了我国涉铬行业概况,铬污染土壤的来源及铬特性,重点综述了国内外铬污染场地修复技术研究与应用进展,分析了各种修复方法的优缺点,并列举分析了国内外的修复工程案例。我国是铬盐生产大国,铬化工场地污染尤为严重且复杂。电镀类铬污染场地呈现铬、镍、铜、锌多重金属复合污染特点。制革类铬污染场地具有铬有机物复合污染特征。目前铬污染土壤的修复技术主要是基于六价铬的还原稳定化原理,具体包括化学还原、化学淋洗、电动力学修复以及生物修复技术等。考虑到技术适用性和经济性,目前铬污染土壤修复工程绝大部分采用化学还原的修复技术。开发经济、环境友好型修复材料,探讨其修复机理和长期安全性是未来铬污染场地修复技术的发展方向。
- 铬污染场地 /
- 修复技术 /
- 研究进展
Abstract: The contamination of hexavalent chromium in the soil mainly derives from chromium-related industries such as chromium chemical industry, electroplating, tanning and so on. This paper briefly described the general situation of chromium industry in China, as well as the source and characteristics of chromium-contaminated soil. The research and application progress of remediation technology for chromium-contaminated site at home and abroad were reviewed, including the contrastive analysis of various remediation methods. Additionally, remediation engineering cases were also listed and analysed in this paper. China has a powerful chromium salts production industry which brings about seriously pollution of chromium in soil. The electroplated chromium-contaminated site presented the characteristics of chromium-nickel-copper-zinc composite pollution. The tannery chromium contaminated site had the characteristic of combined pollution of chromium and organic compounds. At present, the remediation technology of chromium-contaminated soil was mainly based on the principle of reduction and stabilization of hexavalent chromium, including chemical reduction, chemical leaching, electrokinetic remediation, biological remediation technology and so on. Considering the technical applicability and economy, most of the chromium-contaminated soil remediation projects currently employed chemical reduction remediation technology. As for the development of chromium-contaminated site remediation technology, preparing cheap and environmentally friendly remediation materials, as well as discussing the remediation mechanism and long-term safety would be the potential research hotpots.
- chromium contaminated site /
- remediation technology /
- research progress

HTML全文

参考文献(45)

中国生态环境部. 土壤环境质量建设用地土壤污染风险管控标准(试行):GB 36600—2018[S]. http://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/trhj/201807/W020190626595212456114.pdf, 2018.

国家环境保护总局.地下水质量标准:GB/T 14848—2017[S]. http://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/shjbh/shjzlbz/199410/W020061027512167894817.pdf, 1994.

蔡焕兴,梁金利,段雪梅,等. 铬渣污染场地修复技术研究进展[J]. 环境监控与预警, 2012, 4(5): 48-50.

纪柱. 铬污染土壤的修复[J]. 无机盐工业, 2008, 40(2): 47-50.

曹宏斌, 熊梅. 我国工业源六价铬排放来源与分布研究[M]. 北京: 中国环境出版社, 2017.

成思危. 铬盐生产工艺[M]. 北京:化学工业出版社, 1988.

PAPP J F. U.S. Geological Survey, Mineral Commodity Summaries[M]. 2012: 42-43.

环境保护部环境应急与事故调查中心. 铬污染应急处置技术[M]. 北京:中国环境科学出版社, 2015.

胡如南,陈松祺. 实用镀铬技术[M]. 2版. 北京:国防工业出版社, 2013.

王谦. 电镀行业六价铬污染防治最佳可行技术评估的研究[M]. 南京:南京大学, 2013.

单志华,陈慧. 制革化学[M]. 北京:科学出版社, 2019.

唐勇刚,龚慧红. 海宁皮革行业经济形势分析[J]. 西部皮革, 2014, 36(10): 8-11.

刘立军. 辛集皮衣产业现状分析及发展研究[D]. 苏州:苏州大学, 2008.

赵伦山, 张本仁. 地球化学[M]. 北京:地质出版社,2001.

陈刚, 吴士斌, 王亚锋. 铬污染土壤修复技术研究[J]. 河南科技, 2017(23): 146-148.

王鑫. 铬污染土壤的修复技术研究综述[J]. 环境工程, 2015, 33(增刊1): 847-849.

国家发展和改革委员会. 铬渣污染综合整治方案[R]. 发改环资[2005] 2113号.

裴廷权, 王里奥, 钟山, 等. 典型铬渣简易掩埋场铬渣及土壤铬污染特征和处置分析[J]. 环境工程学报, 2008, 2(7): 994-999.

徐腾, 南丰, 蒋晓锋, 等. 制革场地土壤和地下水中铬污染来源及污染特征研究进展[J/OL]. 土壤学报, 2020. http://kns.cnki.net/kcms/detail/32.1119.P.20200403.

1142.002.html.

BARTLET R J. Chromium cycling in soils and water: links, gaps and methods[J]. Environmental Health Perspectives, 1991, 92: 17-24.

TESSIER A. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytical Chemistry, 1979, 51(7): 844-851

桂新安, 杨海真, 王少平, 等. 铬在土壤中的吸附解吸研究进展[J]. 土壤通报, 2007, 38(5): 1007-1012.

杨峰. Cr(Ⅲ)-有机酸配合物的氧化及其在土壤中的吸附迁移性研究[D]. 南京:南京农业大学, 2013.

王青. 铬对人体与环境的影响及防治[J]. 微量元素与健康研究, 2011, 28(5): 64-66.

刘晓娟, 程滨, 赵瑞芬, 等. 铬在环境中的迁移行为及毒害研究进展[J]. 山西农业科学, 2018, 46(6):1061-1064.

U.S.EPA. In-situ treatment of soil and groundwater contaminated with chromium technical resource guide[R]. EPA/625/R-00/005, 2000.

梁金利, 蔡焕兴, 段雪梅, 等. 还原法修复六价铬污染土壤的研究[J]. 环境科学与管理, 2013, 38(3): 80-83.

孙孝庆. 电动力修复铬污染土壤研究[D]. 沈阳:辽宁科技大学, 2016.

卢鑫, 罗启仕, 刘馥雯, 等. 硫化物对电镀厂铬污染土壤的稳定化效果及其机理研究[J]. 环境科学学报, 2017, 37(6): 2315-2321.

SEMER R, REDDY K R. Evaluation of soil washing process to remove mixed contaminants from a sandy loam[J]. Journal of Hazardous Materials, 1996, 56(1): 45-57.

PICHTEL J, PICHTEL T M. Comparison of solvents for ex situ removal of chromium and lead from contaminated soil[J]. Environmental Engineering Science, 1997, 14(2): 96-103.

MAO X H, JIANG R, XIAO W, et al. Use of surfactants for the remediation of contaminated soils: a review[J]. Journal of Hazardous Materials, 2015, 285: 419-435.

LEE G, HERING J G. Oxidative dissolution of chromium(Ⅲ) hydroxide at pH 9, 3, and 2 with product inhibition at pH 2[J]. Environmental Science & Technology, 2005, 39: 4921-4928.

BEIYUAN J, LAU A Y T, TSANG D C W, et al. Chelant-enhanced washing of CCA-contaminated soil: coupled with selective dissolution or soil stabilization[J]. Science of The Total Environment, 2018, 612: 1463-1472.

PETIGARA B R, BLOUGH N V, MIGNEREY A C. Mechanisms of hydrogen peroxide decomposition in soils[J]. Environmental Science & Technology, 2002, 36: 639-645.

REDDY K R, USHA S P, SRINIVAS N, et al. Effect of soil composition on the removal of chromium by electro-kinetics[J]. Journal of Hazardous Materials, 1997, 55(24): 135-158.

REDDY K R, SUPRAJA C. Electro-kinetic remediation of heavy metal contaminated soils under reducing environments[J]. Waste Management, 1999, 19(4): 269-282.

REDDY K R, CHARLIE Y X, SUPRAJA C. Assessment of electro-kinetic removal of heavy metals from soils by sequential extraction analysis[J]. Journal of Hazardous Materials, 2001, 84(2): 279-296.

张学洪, 罗亚平, 黄海涛. 一种新发现的湿生铬超积累植物－李氏禾(Leersia hexandra Swartz) [J]. 生态学报, 2006, 26(3): 158-161.

JOBBY R, JHA P, YADAV A K, et al. Biosorption and biotransformation of hexavalent chromium [Cr(Ⅵ)]: a comprehensive review [J]. Chemosphere, 2018, 207: 255-266.

WU S L, ZHANG X, SUN Y Q, et al. Transformation and immobilization of chromium by arbuscular mycorrhizal fungi as revealed by SEM-EDS, TEM-EDS, and XAFS [J]. Environmental Science & Technology, 2015, 49(24): 14036-14047.

KATSIFAS E A, GIANNOUTSOU. Chromium recycling of tannery waste through microbial fermentation[J]. Journal of Industrial Microbiology ＆ Biotechnology, 2004, 31(2): 57-63.

DESJARDIN V. Effect of microbial activity on the mobility of chromium in soils[J]. Waste Management, 2002, 22(2): 195-200.

LUO Y T, YE B H, YE J E, et al. Ca²⁺ and SO₄^2- accelerate the reduction of Cr(Ⅵ) by Penicillium oxalicum SL2[J]. Journal of Hazardous Materials, 2020, 382: 121072.

柴立元, 陈丽鹃, 黄燕. 表面活性剂对Achromobacter sp. CH-1解毒铬渣的影响[J]. 中南大学学报(自然科学版), 2009, 40(1):40-46.

施引文献

资源附件(0)

访问统计