六价铬污染场地土壤稳定化修复材料研究进展

杨文晓; 张丽; 毕学; 李焕茹; 谷倩

doi:10.13205/j.hjgc.202006003

六价铬污染场地土壤稳定化修复材料研究进展

doi: 10.13205/j.hjgc.202006003

北京润鸣环境科技有限公司, 北京 102628

基金项目:

国家重点研发计划场地土壤污染成因与治理技术专项(2018YFC1802200)。

详细信息

作者简介:
杨文晓(1990-),女,硕士,主要从事重金属污染土壤稳定化修复材料研发。yangwenxiao@bjjunmei.com

通讯作者:
张丽(1984-),女,博士,主要研究方向为重金属污染土壤稳定化修复材料及其应用。zhangliyf@bjjunmei.com

计量
- 文章访问数: 435
- HTML全文浏览量: 47
- PDF下载量: 12
- 被引次数: 0
出版历程
- 收稿日期: 2020-02-28

RESEARCH ADVANCEMENT OF STABILIZATION MATERIALS FOR HEXAVALENT CHROMIUM(Ⅵ) CONTAMINATED SITE SOILS

Beijing Junmei Environmental Technology Co., Ltd, Beijing 102628, China

摘要

摘要: 化学还原稳定化修复是工业铬污染土壤修复中应用最为广泛的技术。针对不同污染程度及理化性质的铬污染土壤,选择最为高效、经济、适用的稳定化修复材料是铬污染土壤修复工程最核心问题所在。针对上述问题,重点对现有铬污染土壤修复材料,如铁系、硫系、铁硫系、有机类及微生物菌剂的修复原理、影响因素、实际应用效果及存在问题、修复后环境风险和长期稳定性等多方面进行总结,为实际修复工程中六价铬修复材料的选择及修复实践工作的开展提供重要参考与指导建议。
- 六价铬 /
- 修复材料 /
- 稳定化 /
- 应用效果 /
- 长期稳定性
Abstract: Chemical reduction stabilization remediation is the most widely used technology for remediation of chromium contaminated soils. How to select the most efficient, economical and applicable remediation materials for chromium-contaminated soil with different pollution degrees and physicochemical properties is the core problem of chromium-contaminated soil remediation engineering. This paper mainly focused on the remediation principles, influencing factors, the actual application effect and the existing problems, the environmental risk and long-term stability of chromium-contaminated soil remediation materials, such as iron-based, sulfur-based, iron-sulfur-based, organic and microbial agents, to the reduction of hexavalent chromium-contaminated soil. It can provide references and guidance for better application of those remediation materials in the practical engineering.
- hexavalent chromium /
- remediation materials /
- stabilization /
- application effect /
- long-term stability

HTML全文

参考文献(64)

SHAHID M, SHAMSHAD S, RAFIQ M, et al. Chromium speciation, bioavailability, uptake, toxicity and detoxification in soil-plant system: a review[J]. Chemosphere, 2017, 178: 513-533.

DHAL B, THATOI H N, DAS N N, et al. Chemical and microbial remediation of hexavalent chromium from contaminated soil and mining/metallurgical solid waste: a review[J]. Journal of Hazardous Materials, 2013, 250/251: 272-291.

FU F L, DIONYSIOU D D, LIU H, et al. The use of zero-valent iron for groundwater remediation and wastewater treatment: a review [J]. Journal of Hazardous Materials, 2014, 267: 194-205.

WILKIN R T, SU C M, FORD R G, et al. Chromium removal processes during groundwater remediation by a zerovalent iron permeable reactive barrier [J]. Environmental Science & Technology, 2005, 39(12): 4599-4605.

ZHANG R Y, ZHANG N Q, FANG Z Q. In situ remediation of hexavalent chromium contaminated soil by CMC-stabilized nanoscale zero-valent iron composited with biochar[J]. Water Science & Technology, 2018, 77(5/6):1622-1631

ALOWITZ M J, SCHERER M M. Kinetics of nitrate, nitrite, and Cr(Ⅵ) reduction by iron metal [J]. Environmental Science & Technology, 2002, 36(3): 299-306.

ZHOU N, GONG K D, HU Q, et al. Optimizing nanocarbon shell in zero-valent iron nanoparticles for improved electron utilization in Cr(Ⅵ) reduction [J]. Chemosphere, 2020, 242: 125-235.

ZHU F, LI L W, REN W T, et al. Effect of pH, temperature, humic acid and coexisting anions on reduction of Cr(Ⅵ) in the soil leachate by nZVI/Ni bimetal material [J]. Environmental Pollution, 2017, 227: 444-450.

LIU T Z, RAO P H, IRENE M C. Influences of humic acid, bicarbonate and calcium on Cr(Ⅵ) reductive removal by zero-valent iron [J]. Science of the Total Environment, 2009, 407: 3407-3414.

LIU T Z, IRENE M C. Influences of humic acid on Cr(Ⅵ) removal by zero-valent iron from groundwater with various constituents: implication for long-term PBR performance [J]. Water Air and Soil Pollution, 2011, 216: 473-483.

IRENE M C, CHESTER S C, KEITH C K. Hardness and carbonate effects on the reactivity of zero-valent iron for Cr(Ⅵ) removal [J]. Water Research, 2006, 40: 595-605.

王旌,罗启仕,张长波,等.铬污染土壤的稳定化处理及其长期稳定性研究[J].环境科学,2013,34(10):4036-4041.

WANG Q, CISSOKO N, ZHOU M, et al. Effects and mechanism of humic acid on chromium(Ⅵ) removal by zero-valent iron(Fe⁰) nanoparticles [J]. Physics and Chemistry of the Earth, Parts A/B/B, 2011, 36(9/10/11): 442-446.

PETALA E, DIMOS K, DOUVALIS A, et al. Nanoscale zero-valent iron supported on mesoporous silica: characterization and reactivity for Cr(Ⅵ) removal from aqueous solution [J]. Journal of Hazardous Materials, 2013, 261: 295-306.

LI X Q, CAO J S, ZHANG W X. Stoichiometry of Cr(Ⅵ) immobilization using nanoscale zerovalent iron (nZVI): a study with High-resolution X-Ray photoelectron spectroscopy (HR-XPS) [J]. Industrial & Engineering Chemistry Research, 2008, 47: 2131-2139.

CAO J S, ZHANG W X. Stabilization of chromium ore processing residue (COPR) with nanoscale iron particles [J]. Journal of Hazardous Materials, 2006, 132(2/3): 213-219.

SHJEPCEVIC N, KERKEZ D, TOMASEVIC P D, et al. Use of two different approaches to the synthesis of nano zero valent iron for sediment remediation [J]. Global NEST Journal, 2019, 21(4): 455-460.

COMBA S, SETHI R. Stabilization of highly concentrated suspensions of iron nanoparticles using shear-thinning gels of xanthan gum [J]. Water Research, 2009, 43(15): 3717-3726.

WANG Q, QIAN H J, YANG Y P, et al. Reduction of hexavalent chromium by carboxymethyl cellulose-stabilized zero-valent iron nanoparticles [J]. Journal of Contaminant Hydrology, 2010, 114: 35-42.

LI F, VIPULANANDAN C,MOHANTY K K. Microemulsion and solution approaches to nanoparticle iron production for degradation of trichloroethylene[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2003,223:103-112.

GRÖHLICH A, LANGER M, MITRAKAS M, et al. Effect of organic matter on Cr(Ⅵ) removal from groundwaters by Fe(Ⅱ) reductive precipitation for groundwater treatment [J]. Water, 2017, 9(6): 389.

CARLOS E B D, VIOLETA L L, BRYAN B. A review of chemical, electrochemical and biological methods for aqueous Cr(Ⅵ) reduction [J]. Journal of Hazardous Materials, 2012, 223/224: 1-12.

BUERGE I J, HUG S J. Kinetics and pH dependence of chromium(Ⅵ) reduction by iron(Ⅱ) [J]. Environmental Science & Technology, 1997, 31(5): 1426-1432.

QIN G, MCGUIRE M J, BLUTE N K, et al. Hexavalent chromium removal by reduction with ferrous sulfate, coagulation, and filtration: a pilot-scale study [J]. Environmental Science & Technology, 2005, 39(16): 6321-6327.

DERMATAS D, CHRYSOCHOOU M, MOON D H, et al. Ettringite-induced heave in chromite ore processing residue (COPR) upon ferrous sulfate treatment [J].Environmental Science & Technology, 2006, 40: 5786-5792.

WEAMAN J C, BERTSCH P M, SCHWALLIE L. In situ Cr(Ⅵ) reduction within coarse-textured, oxide-coated soil and aquifer systems using Fe(Ⅱ) solutions [J]. Environmental Science & Technology, 1999, 22: 938-944.

ZHANG T T, XUE Q, LI J S, et al. Effect of ferrous sulfate dosage and soil particle size on leachability and species distribution of chromium in hexavalent chromium-contaminated soil stabilized by ferrous sulfate [J]. Environmental Progress & Sustainable Energy, 2019, 38(2): 500-507.

JAMES B R, BARTLETT R J. Behavior of chromium in soils. VI. Interactions between oxidation-reduction and organic complexation[J]. Journal of Environmental Quality, 1983, 12(2): 173-176.

LI D, GUI C X, JI G Z, et al. An interpretation to Cr(Ⅵ) leaching concentration rebound phenomenon with time in ferrous-reduced Cr(Ⅵ)-bearing solid matrices [J]. Journal of Hazardous Materials, 2019, 378:120734.

PAPASSIOPI N, PINAKIDOU F, KATSIKINI M, et al. A XAFS study of plain and composite iron(Ⅲ) and chromium(Ⅲ) hydroxides[J]. Chemosphere, 2014, 111: 169-176.

PAN C, LIU H, CATALANO J G. Rates of Cr(Ⅵ) generation from (Cr_xFe_(1-x))(OH)₃ soilds upon reaction with manganese oxide[J]. Environmental Science & Technology, 2017, 51: 12416-12423.

CHRYSOCHOOU M, JOHNSTON C P, DAHAL G. A comparative evaluation of hexavlent chromium treatment in contaminated soil by calcium polysulfide and green-tea nanoscale zero-valent iron [J]. Journal of Hazardous Materials, 2012, 201/202: 33-42.

DAHLAWI S M, SIDDIQUI S. Calcium polysulphide, its applications and emerging risk of environmental pollution: a review article [J]. Environmental Science and Pollution Research, 2017, 24: 92-102.

CHRYSOCHOOU M, TING A. A kinetic of Cr(Ⅵ) reduction by calcium polysulfide [J]. Science of the Total Environment, 2011, 409: 4072-4077.

CHRYSOCHOOU M, JOHNSTON C P. Polysulfide speciation and reactivity in chromate-contaminated soil [J]. Jouurnal of Hazardous Materials, 2015, 281: 87-94.

卢鑫,罗启仕,刘馥雯,等.硫化物对电镀厂铬污染土壤的稳定化效果及其机理研究[J].环境科学学报,2017,37(6):2315-2321.

CHEN C J, LIN T H, CHEN C P, et al. The effectiveness of ferrous iron and sodium dithionite for decreasing resin-extractable Cr(Ⅵ) in Cr(Ⅵ)-spiked alkaline soils [J]. Journal of Hazardous Materials, 2009, 164: 510-516.

ISTOK J D, AMONETTE J E, COLE C R, et al. In site redox manipulation by dithionite injection: intermediate-scale laboratory experiments [J]. Ground Water, 1999, 37(6): 884-889.

LI Y Y, CUNDY A B, FENG J X, et al. Remediation of hexavalent chromium contamination in chromite ore processing residue by sodium dithionite and sodium phosphate addition and its mechanism [J]. Journal of Environmental Management, 2017, 192: 100-106.

LUGWIG R D, SU C M, LEE T R, et al. In site chemical reduction of Cr(Ⅵ) in groundwater using a combination of ferrous sulfate and sodium dithionite: a field investigation [J]. Environmental Science & Technology, 2007, 41: 5299-5305.

BEUKES J P, PIENAAR J J, LACHMANN G. The reduction of hexavalent chromium by sulphite in wastewater:an explanation of the observed reactivity pattern [J]. Water SA, 2000, 26(3): 393-396.

刘增俊,夏旭,张旭,等.铬污染土壤的药剂修复及其长期稳定性研究[J].环境工程,2015,33(2):160-163.

LIU J R, VALSARAJ K T, DEVAI I, et al. Immobilization of aqueous Hg(Ⅱ) by mackinawite (FeS) [J]. Journal of Hazardous Materials, 2008, 157: 432-440.

XIONG Z, HE F, ZHAO D Y, et al. Immobilization of mercury in sediment using stabilized iron sulfide nanoparticles [J]. Water Reserch, 2009, 43: 5171-5179.

COLES C A, RAO S R, YONG R N. Lead and cadmium interactions with mackinawite: retention mechanisms and the role of pH [J]. Environmental Science & Technology, 2000, 34: 996-1000.

KIM E J, KIM J H, AZAD A M, et al. Facile synthesis and characterization of Fe/FeS nanoparticles for environmental applications [J]. ACS Applied Materials & Interfaces, 2011, 3: 1457-1462.

YU Y Y, CHENG Q W, SHA C, et al. Size-controlled biosynthesis of FeS nanoparticles for efficient removal of aqueous Cr(Ⅵ) [J]. Chemical Engineering Journal, 2020, 379: 122404.

PATTERSON R R, BOURSIQUOT S. Reduction of hexavalent chromium by amorphous Iron Sulfide [J]. Environmental Science & Technology, 1997, 31: 2039-2044.

MULLET M, BOURSIQUOT S, EHRHARDT J J. Removal of hexavalent chromium from solution by mackinawite, tetragonal FeS [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 244(1/2/3): 77-85.

GRAHAM A M, BOUWER E J. Oxidative dissolution of pyrite surfaces by hexavalent chromium_surface site saturation and surface renewal[J]. Geochimica Et Cosmochimica Acta, 2012, 83: 379-396.

LI Y Y, LIANG J L, HE X, et al. Kinetics and mechanisms of amorphous FeS₂ induced Cr(Ⅵ) reduction [J]. Journal of Hazardous Materials, 2016, 320: 216-225.

WITTBRODT P R, PALMER C D. Reduction of Cr(Ⅵ) in the presence of excess soil fulvic acid [J]. Environmental Science & Technology, 1995, 29: 255-263.

HUANG S W, CHIANG P N, LIU J C, et al. Chromate reduction on humic acid derived from a peat soil-exploration of activated sites on Has for chromate removal [J]. Chemosphere, 2012, 87: 587-594.

SZULCZEWSKI M D, HELMKE P A, BLEAM W F. XANES spectroscopy studies of Cr(Ⅵ) reduction by thiols in organosulfur compounds and humic substances [J]. Environmental Science & Technology, 2001, 35: 1134-1141.

NAKAYASU K, FUKUSHIMA M, SASAKI K, et al. Comparative studies of the reduction behavior of chromium(Ⅵ) by humic substances and their precursors [J]. Environmental Toxicology and Chemistry, 1999, 18(6): 1085-1090.

RAO C P, SARKAR P S, KAIWAR S P, et al. Chromate reductase activity: characterization of Cr(Ⅵ) to Cr(Ⅲ) conversion [J]. Proceedings of the Indian Academy of Sciences (Chemical Sciences), 1990, 102(3): 219-230.

PARLAYICI S, AVCI A, PEHLIVAN E, et al. Fabrication of novel chitosan-humic acid-graphene oxide composite to improve adsorption for Cr(Ⅵ) [J]. Arabian Journal of Geosciences, 2019, 12(20): 615.

SINGARAJ S G, MAHANTY B, BALACHANDRAN D, et al. Adsorption and desorption of chromium with humic acid coated iron oxide nanoparticles [J]. Environmental Science and Pollution Research, 2019, 26: 30044-30054.

GARCÍA-HERNÁNDEZ M A, VILLARREAL-CHIU J F, GARZA-GONZÁLEZ M T. Metallophilic fungi research: an alternative for its use in the bioremediation of hexavalent chromium [J]. International Journal of Environmental Science and Technology, 2017, 14: 2023-2038.

CHUN Y L, ZHANG Y, ZHANG Y, et al. Bioreduction of chromate in a methane-based membrane biofilm reactor [J]. Environmental Science & Technology, 2016, 50: 5832-5839.

MICHEL C, BRUGNA M, AUBERT C, et al. Enzymatic reduction of chromate: comparative studies using sulfate-reduction bacteria [J]. Applied Microbiology Biotechnology, 2001, 55: 95-100.

SUZUKI T, MIYATA N, HORITSU H, et al. NAD(P)H-dependent chromium(Ⅵ) reductase of Pseudomonas ambigua G-1: a Cr(Ⅴ) intermediate is formed during the reduction of Cr(Ⅵ) to Cr(Ⅲ) [J]. Journal of Bacteriology, 1992, 174(16): 5340-5345.

LI M H, GAO X Y, LI C, et al. Isolation and identification of chromium reducing Bacillus Cereus species from chromium-contaminated soil for the biological detoxification of chromium [J]. International Journal of Environmental Research and Public Health, 2020, 17(6): 2118.

HUANG X N, MIN D, LIU D F, et al. Formation mechanism of organo-chromium(Ⅲ) complexes from bioreduction of chromium(Ⅵ) by Aeromonas hydrophila [J]. Environment International, 2019, 129: 86-94.

施引文献

资源附件(0)

访问统计