高碘酸钠与APAM联合调理对污泥脱水的影响

兰兵兵; 金若菲; 刘彦松; 柳广飞; 周集体

doi:10.13205/j.hjgc.202007019

高碘酸钠与APAM联合调理对污泥脱水的影响

doi: 10.13205/j.hjgc.202007019

大连理工大学环境学院, 辽宁大连 116024

基金项目:

大连市重点科技研发计划项目（2018YF24SN073）。

详细信息

作者简介:
兰兵兵(1994-),男,硕士研究生,主要研究方向为污泥脱水。lanbingbing1021@163.com

通讯作者:
金若菲(1975-),女,博士,副教授,主要研究方向为污泥资源化等。jin_ruofei@163.com

计量
- 文章访问数: 214
- HTML全文浏览量: 23
- PDF下载量: 10
- 被引次数: 0
出版历程
- 收稿日期: 2020-05-15

EFFECT OF SODIUM PERIODATE-APAM CONJUNCTION ON DEWATERABILITY OF WASTE ACTIVATED SLUDGE

Dalian University of Technology, School of Environmental Science and Technology, Dalian 116024, China

摘要

摘要: 采用高碘酸钠与阴离子聚丙烯酰胺（APAM）联合调理改善污泥脱水性。以污泥比阻和污泥滤饼含水率作为衡量污泥脱水性的指标，分析胞外聚合物（EPS）中蛋白质和多糖含量，并测定污泥Zeta电位和粒径。结果表明：当污泥初始pH为8时，88 mg/g DS（干污泥）的高碘酸钠和2 mg/g DS的APAM可以有效改善污泥脱水，联合调理后污泥比阻降低至4.82×10¹² m/kg，污泥滤饼含水率降低至69.67%。污泥经过高碘酸钠氧化后，Zeta负电性降低，可溶性胞外聚合物（S-EPS）中的蛋白质含量增加，荧光光谱显示腐植酸物质的荧光强度降低，污泥中值粒径经过高碘酸钠絮凝后减小。研究结果表明，组合调理剂可以有效改善污泥脱水性，并利于后续污泥处理与处置。
- 污泥脱水 /
- 高碘酸钠 /
- 阴离子聚丙烯酰胺 /
- 污泥比阻
Abstract: The dewaterability of waste activated sludge was improved by sodium periodate and anionic polyacrylamide (APAM) conjunction. Sludge dewaterability was determined by specific resistance to filtration and the sludge moisture content, and the contents of protein and polysaccharide in extracellular polymers substances (EPS), as well as zeta potential and particle size of the sludge were also determined. The result indicated that 88 mg/g DS (dry sludge) sodium periodate and 2 mg/g DS APAM could effectively improve sludge dewaterability under pH of 8, and specific resistance to filtration and the sludge moisture content decreased to 4.82×10¹² m/kg and 69.67%, respectively. After the oxidation of sodium periodate, the zeta potential of sludge increased, protein content of soluble extracellular polymeric substances increased. Fluorescence spectroscopy showed that humic acid in soluble extracellular polymeric substances was oxidized, and the particle size of sludge decreased. The combined conditioner can effectively improve sludge dewaterability and facilitate the subsequent sludge treatment and disposal.
- sludge dewatering /
- sodium periodate /
- anionic polyacrylamide /
- specific resistance to filtration

HTML全文

参考文献(22)

甄广印, 吴太朴, 陆雪琴, 等. 高级氧化污泥深度脱水技术研究进展[J]. 环境污染与防治, 2019, 41(9):1108-1119.

李亚林, 刘蕾, 张景玉, 等. 电渗透耦合Fe²⁺-过硫酸钠污泥脱水过程中EPS的变化特性[J]. 环境工程学报, 2019, 13(2):185-194.

DEVLIN D C, ESTEVES S R R, DINSDALE R M, et al. The effect of acid pretreatment on the anaerobic digestion and dewatering of waste activated sludge[J]. Bioresource Technology, 2011, 102(5):4076-4082.

徐振佳, 陆宇倩, 李莲, 等. 不同反应条件对污泥水热碳化脱水性能的影响[J]. 环境工程, 2019, 37(3):1-12.

连广浒,程刚,张霖钰,等.水力空化-酸化调理增强污泥脱水性能的研究[J/OL].环境工程:1-10[2020-07-29

].http://kns.cnki.net/kcms/detail/11.2097.X.20191219.1352.004.html.

徐文迪, 常沙, 傅金祥. 基于过氧化钙(CaO₂)的类芬顿污泥预处理技术研究[J]. 环境工程, 2018, 36(7):117-127.

刘怡君. 芬顿反应强化污泥脱水试验及机理研究[J]. 环境工程, 2017, 35(4):55-59.

NEYENS E, BAEYENS J, DEWIL R, et al. Advanced sludge treatment affects extracellular polymeric substances to improve activated sludge dewatering[J]. Journal of Hazardous Materials, 2004, 106(2/3):83-92.

BOKARE A D, CHOI W. Singlet-Oxygen Generation in Alkaline Periodate Solution[J]. Environmental Science & Technology, 2015, 49(24):14392-14400.

SUDALAI A, KHENKIN A, NEUMANN R. Sodium periodate mediated oxidative transformations in organic synthesis[J]. Organic & Biomolecular Chemistry, 2015, 13(15):4374-4394.

章广德, 孙明宇. 应用聚丙烯酰胺对市政污泥脱水性能影响的研究[J]. 环境科学与管理, 2017, 42(11):108-111.

WALTER W G. Standard methods for the examination of water and wastewater[M].Washington:American Public Health Association. 1989.

XIAO K K, CHEN Y, JIANG X, et al. Variations in physical, chemical and biological properties in relation to sludge dewaterability under Fe(Ⅱ)-Oxone conditioning[J]. Water Research, 2017, 109:13-23.

FRØLUND B, PALMGREN R, KEIDING K, et al. Extraction of extracellular polymers from activated sludge using a cation exchange resin[J]. Water Research, 1996, 30(8):1749-1758.

DUBOIS M, GILLES K A, HAMILTON J K, et al. Colorimetric method for determination of sugars and related substances[J]. Analytical Chemistry, 1956, 28(3):350-356.

陈丹丹, 窦昱昊, 卢平, 等. 污泥深度脱水技术研究进展[J]. 化工进展, 2019, 38(10):4722-4746.

LIN F, ZHU X L, LI J G, et al. Effect of extracellular polymeric substances(EPS)conditioned by combined lysozyme and cationic polyacrylamide on the dewatering performance of activated sludge[J]. Chemosphere, 2019, 235:679-689.

李会东, 李璟, 张哲歆, 等. 过氧化钙联合絮凝剂调理污泥改善脱水性能[J]. 环境工程学报, 2019, 13(11):2736-2742.

万甜, 闫幸辛, 任杰辉, 等. Fe(Ⅱ)活化过硫酸盐改善污泥脱水性能[J]. 环境工程学报, 2020, 14(1):189-196.

CHEN W, WESTERHOFF P, LEENHEER J A, et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter[J]. Environmental Science & Technology, 2003, 37(24):5701-5710.

SHENG G P, YU H Q. Characterization of extracellular polymeric substances of aerobic and anaerobic sludge using three-dimensional excitation and emission matrix fluorescence spectroscopy[J]. Water Research, 2006, 40(6):1233-1239.

UYGUNER C S, BEKBOLET M. Evaluation of humic acid photocatalytic degradation by UV-vis and fluorescence spectroscopy[J]. Catalysis Today, 2005, 101(3/4):267-274.

施引文献

资源附件(0)

访问统计