净水污泥与粉末活性炭复合制备吸附剂去除氨氮研究

李荣; 许多; 魏杰; 王东田

doi:10.13205/j.hjgc.202009016

净水污泥与粉末活性炭复合制备吸附剂去除氨氮研究

doi: 10.13205/j.hjgc.202009016

李荣¹,
许多¹,
魏杰²,
王东田^1,2, ,

1. 苏州科技大学环境科学与工程学院, 江苏苏州 215009;
2. 苏州科技大学化学生物与材料工程学院, 江苏苏州 215009

基金项目:

国家自然科学基金"净水污泥吸附剂的制备及吸附去除废水中氨氮的行为与机制"（51778392）；江苏省研究生科研与实践创新计划项目"净水污泥与废弃活性炭制备吸附剂及去除氨氮研究（SJCX18_0872）。

详细信息

作者简介:
李荣(1994-),女,硕士,主要研究方向为污水处理与回用技术。1643787369@qq.com

通讯作者:
王东田,博士,教授,主要研究方向为净水污泥资源化利用。dongtianw@163.com

计量
- 文章访问数: 154
- HTML全文浏览量: 32
- PDF下载量: 12
- 被引次数: 0
出版历程
- 收稿日期: 2019-08-07

PREPARATION OF ADSORBENT BY COMBINED DRINKING WATER TREATMENT SLUDGE AND POWDERED ACTIVATED CARBON AND ITS AMMONIUM REMOVAL PERFORMANCE

LI Rong¹,
XU Duo¹,
WEI Jie²,
WANG Dong-tian^{1,2
, ,}

1. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China;
2. School of Chemistry, Biology and Materials Engineering, Suzhou University of Science and Technology, Suzhou 215009, China

摘要

摘要: 将净水污泥与粉末活性炭复合制备吸附剂，用于去除水中的氨氮。研究了净水污泥与粉末活性炭的最佳复合比例及煅烧温度，并采用EDX、SEM、XRD、FTIR、BET对吸附剂进行表征。考察了吸附时间、溶液初始pH、吸附剂投加量、氨氮初始浓度对氨氮吸附效果的影响。结果表明：复合吸附剂的吸附性能优于原泥，当吸附时间为5 h，pH为9时氨氮去除效果最佳。对实验结果进行吸附等温线及吸附动力学模型拟合，发现复合吸附剂对氨氮的吸附过程符合Langmuir等温吸附模型及二级动力学方程。
- 吸附 /
- 净水污泥 /
- 粉末活性炭 /
- 复合吸附剂 /
- 氨氮
Abstract: The adsorbent was prepared by combining the drinking water treatment sludge with the powdered activated carbon, in order to remove ammonia nitrogen from the water. The optimum composite mass ratio and calcination temperature of drinking water treatment sludge and powdered activated carbon were studied. The adsorbents were characterized by EDX, SEM, XRD, FTIR and BET. The influences of different parameters such as contact time of composite adsorbent, initial pH of ammonia nitrogen, dosage of adsorbent and initial concentration of ammonia nitrogen were investigated. The results indicated that the adsorption performance of the composite adsorbent was better than that of the raw sludge adsorbent. When the contact time was 5h and the pH was 9, the ammonia nitrogen removal effect was the best. The adsorption isotherms and adsorption kinetic model were fitted by the experimental results. It was found that the adsorption process of the composite adsorbent on ammonia nitrogen accorded with the Langmuir isotherm adsorption model and the second-order kinetic model.
- adsorption /
- drinking water treatment sludge /
- powdered activated carbon /
- composite adsorbent /
- ammonia nitrogen

HTML全文

参考文献(22)

ABO-EL-ENEIN S A, AHMED S, ABO E S A. Drinking water treatment sludge as an efficient adsorbent for heavy metals removal[J]. Applied Clay Science, 2017,146:343-349.

DEVI P, SAROHA A. Utilization of sludge based adsorbents for the removal of various pollutants:a review[J]. Science of the Total Environment, 2017,578:16-33.

马顺君,李梅,高海燕,等. 日本自来水厂污泥减量及再生利用处置综述[J]. 中国给水排水,2019,35(6):22-27.

MAHMOUD M F, RAZEK T M A, ELGENDY A S,et al. Utilization of drinking water treatment slurry to produce aluminum sulfate coagulant[J]. Water Environment Research, 2017,89(2):186-191.

ABHILASH T N. Influence of sludge characteristics on coagulant recovery from water treatment sludge:a preliminary study[J]. Journal of Material Cycles and Waste Management, 2017,19(3):1228-1234.

MAHMOUD M F, AHMED S E. Evaluation of sludge handling using acidification and sequential aluminum coagulant recovery:case study of El-Sheikh Zayed WTP[J]. Research and Technology-Aqua, 2017,66(6):403-415.

MOHAMED A, ABDALLAH A. A parametric study of alum recovery from water treatment sludge[J]. Water Science and Technology, 2016,74(2):516-523.

OLGA K,VIKTOR K, RENATA B, et al. Eco-efficient recycling of drinking water treatment sludge and glass waste:development of ceramic bricks[J]. Journal of Material Cycles and Waste Management, 2018,20(2):1228-1238.

VSEVOLOD M, KIRILL A, OTAVIO M F, et al. Water cleaning sludge as principal component of composites to enhance mechanical properties of ecologically clean red ceramics[J]. Journal of Cleaner Production, 2017,145:367-373.

ZHU S Y, FANG S, HUO M X, et al. A novel conversion of the groundwater treatment sludge to magnetic particles for the adsorption of methylene blue[J]. Journal of Hazardous Materials, 2015,292:173-179.

张玉妹,韩乙萱,魏杰,等. 碱改性净水污泥对水中氨氮的吸附效能研究[J]. 环境科学学报,2014,34(10):2484-2490.

江宇,朱加豆,李荣,等. 净水污泥负载零价纳米铁去除水中Cr(Ⅵ)[J]. 环境工程,2018,36(9):16-20.

杨兰.超声辅助处理净水污泥用于去除废水中磷和氨氮研究[D].杭州:浙江工业大学,2015.

张玉妹,杨兰,刘宗元,等. 净水污泥对水中氨氮的吸附效能研究[J]. 安全与环境学报,2016,16(1):192-196.

HAMID P, MOSTAFA L, MARZIEH K. Adsorption of methylene blue from aqueous solutions using water treatment sludge modified with sodium alginate as a low cost adsorbent[J]. Water Science and Technology, 2017,75(2):281-295.

RASHED M N, EL-DAIM EL TAHER M A, SOMAYA M M F.Adsorption of methylene blue using modified adsorbents from drinking water treatment sludge[J].Water Science and Technology, 2016, 74(8):1885-1898.

BAL K K C, ASHOK A, TROY J. Comparative study of ground water treatment plants sludges to remove phosphorous from wastewater[J]. Journal of Environmental Management, 2016,180:17-23.

YANG L, WEI J, LIU Z Y, et al. Material prepared from drinking waterworks sludge as adsorbent for ammonium removal from wastewater[J]. Applied Surface Science, 2015,330:228-236.

de OLIVEIRA A, MATHEUS C W, da ROCHA C H, et al. Performance of rendering mortars containing sludge from water treatment plants as fine recycled aggregate[J]. Journal of Cleaner Production, 2018,192:159-168.

HWANG C L, CHIANG C H, HUYNH T P, et al. Properties of alkali-activated controlled low-strength material produced with waste water treatment sludge, fly ash, and slag[J]. Construction and Building Materials, 2017,135:459-471.

王芳. 改性活性炭吸附污水中氨氮的性能[J]. 应用化工,2015,44(5):874-877.

路遥,李建芬,李红霞,等. 废弃粉末活性炭热解再生实验及表征分析[J]. 化工进展, 2018,37(1):389-394.

施引文献

资源附件(0)

访问统计