CSCD来源期刊
中国科技核心期刊
RCCSE中国核心学术期刊
JST China 收录期刊

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

医疗废物焚烧飞灰脱毒减害技术研究进展

张凯茹 邓东阳 贾文超 陈桂华 吴明亮 鞠勇明 李燕

张凯茹, 邓东阳, 贾文超, 陈桂华, 吴明亮, 鞠勇明, 李燕. 医疗废物焚烧飞灰脱毒减害技术研究进展[J]. 环境工程, 2020, 38(9): 175-184. doi: 10.13205/j.hjgc.202009028
引用本文: 张凯茹, 邓东阳, 贾文超, 陈桂华, 吴明亮, 鞠勇明, 李燕. 医疗废物焚烧飞灰脱毒减害技术研究进展[J]. 环境工程, 2020, 38(9): 175-184. doi: 10.13205/j.hjgc.202009028
ZHANG Kai-ru, DENG Dong-yang, JIA Wen-chao, CHEN Gui-hua, WU Ming-liang, JU Yong-ming, LI Yan. RESEARCH PROGRESS IN DETOXIFICATION TECHNOLOGY OF MEDICAL WASTE INCINERATOR FLY ASH[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(9): 175-184. doi: 10.13205/j.hjgc.202009028
Citation: ZHANG Kai-ru, DENG Dong-yang, JIA Wen-chao, CHEN Gui-hua, WU Ming-liang, JU Yong-ming, LI Yan. RESEARCH PROGRESS IN DETOXIFICATION TECHNOLOGY OF MEDICAL WASTE INCINERATOR FLY ASH[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(9): 175-184. doi: 10.13205/j.hjgc.202009028

医疗废物焚烧飞灰脱毒减害技术研究进展

doi: 10.13205/j.hjgc.202009028
基金项目: 

广东省国际合作项目(2018A050506045);广东省自然科学基金(2018A030313226);广东省基础与应用基础研究基金(2020A1515010969);山西省自然科学基金(201701D121034)。

详细信息
    作者简介:

    张凯茹(1994-),女,硕士,主要研究方向为固体废弃物无害化处理及资源化利用。949851033@qq.com

    通讯作者:

    李燕(1975-),女,博士,教授,主要研究方向为胶体与界面化学。liyan_china@126.com

RESEARCH PROGRESS IN DETOXIFICATION TECHNOLOGY OF MEDICAL WASTE INCINERATOR FLY ASH

  • 摘要: 医疗废物焚烧飞灰(MWIFA)富含高浓度的氯盐、碳组分、重金属和二噁英(PCDD/Fs),已被列入我国《国家危险废物名录》,管理处置不当将对环境和人类健康造成严重危害。关于医疗废物焚烧飞灰处理处置的综合研究较少。介绍了医疗废物焚烧飞灰中重金属及二噁英等有毒有害物质的污染特征,分析了化学药剂稳定法、水泥固化技术、热处理技术、水热处理技术和浮选技术等多种飞灰处理技术的研究现状,重点阐述了上述后3种技术用于处理医疗废物焚烧飞灰中重金属和二噁英的研究进展及存在的问题,并对其应用前景进行了展望。
  • PAWEL S, MAŁGORZATA C, AGATA S, et al. Immobilization of hospital waste incineration ashes in glass-ceramic composites[J]. Ceramics International, 2018, 44:728-734.
    LEE C C, HUFFMAN G L. Review:medical waste management/incineration[J]. Journal of Hazardous Materials, 1996, 48:1-30.
    LIU F, LIU H Q, WEI G X, et, al. Characteristics and treatment methods of medical waste incinerator fly ash:a review[J]. Processes, 2018, 6(10):173.
    VAVVA C, VOUTSAS E, MAGOULAS K. Process development for chemical stabilization of fly ash from municipal solid waste incineration[J]. Chemical Engineering Research and Design, 2017, 125:57-71.
    LI J X, DONG Z L, YANG E H. Strain hardening cementitious composites incorporating high volumes of municipal solid waste incinerator fly ash[J]. Construction and Building Materials, 2017, 146:183-191.
    JIANG Y H, XI B D, LI X J, et al. Effect of water-extraction on characteristics of melting and solidification of fly ash from municipal solid waste incinerator[J]. Journal of Hazardous Materials, 2009, 161:871-877.
    HU Y Y, ZHANG P F, LI J P, et al. Stabilization and separation of heavy metals in incinerator fly ash during the hydrothermal treatment process[J].Journal of Hazardous Materials, 2015, 299:149-157.
    QIU Q L, JIANG X G, CHEN Z L, et al. Microwave-assisted hydrothermal treatment with soluble phosphate added for heavy metals solidification in MSWI fly ash[J]. Energy Fuels, 2017, 31:5222-5232.
    LIU H Q, WEI G X, ZHANG R, et al. Simultaneous removal of heavy metals and PCDD/Fs from hospital waste incinerator fly ash by flotation assisted with hydrochloric acid[J]. Separation Science and Technology, 2014, 49:1019-1028.
    PAN X C, YAN J H, XIE Z M. Detoxifying PCDD/Fs and heavy metals in fly ashes from medical waste incinerators with a DC double arcs plasma torch[J]. Journal of Environmental Sciences, 2013, 25(7):1362-1367.
    WU H L, LU S Y, YAN J H, et al. Thermal removal of PCDD/Fs from medical waste incinerator fly ash:effect of temperature and nitrogen flow rate[J]. Chemosphere, 2011, 84:361-367.
    YAMAGUCHI H, SHIBUYA E, KANAMARU Y, et al. Hydrothermal decomposition of PCDDs/PCDFs in MSWI fly ash[J]. Chemosphere, 1996, 32:203-208.
    LIU H Q, LIU F, WEI G X, et al. Effects of surfactants on the removal of carbonaceous matter and dioxins from weathered incinerator fly ash[J]. Aerosol and Air Quality Research, 2017, 17(9):2338-2347.
    WANG P, HU Y N, CHENG H F. Municipal solid waste (MSW) incineration fly ash as an important source of heavy metal pollution in China[J]. Environmental Pollution, 2019, 252:461-475.
    Healthcare Without Harm. Non-incineration medical waste treatment technologies in Europe[G]. Healthcare Without Harm Europe, Prague, 2004.
    Canadain Standards Association. Guidelines for the management of biomedical waste in canada[S]. Canadian Council of Ministers of the Environment, Ottawa, 1992.
    TZANAKOS K, MIMILIDOU A, ANASTASIADOU K, et al. Solidification/stabilization of ash from medical waste incineration into geopolymers[J]. Waste Management, 2014, 34:1823-1828.
    WANG Y F, WANG L C, HSIEH L T, et al. Effect of temperature and CaO addition on the removal of polychlorinated dibenzo-p-dioxins and dibenzofurans in fly ash from a medical waste incinerator[J]. Aerosol and Air Quality Research, 2012, 12:191-199.
    WEI G X, LIU H Q, LIU F, et al. Reburning treatment of the froths obtained after the flotation of incinerator fly ash[J]. Aerosol and Air Quality Research, 2017, 17:1084-1096.
    王磊. 水热法外加硅铝源稳定医疗废物焚烧飞灰中重金属的研究[D]. 杭州:浙江大学, 2012.
    LIU H Q, WEI G X, ZHANG R. Removal of carbon constituents from hospital solid waste incinerator fly ash by column flotation[J]. Waste Management, 2013, 33:168-174.
    AYLIN A, ESRA T K, AYLIN Y. Compressive strength and heavy metal leaching of concrete containing medical waste incineration ash[J]. Construction and Building Materials, 2017, 138:326-332.
    金立梅. 垃圾焚烧发电厂飞灰热处理过程中重金属挥发特性研究[D]. 武汉:华中科技大学, 2015.
    刘汉桥, 魏国侠, 张曙光, 等. 医疗垃圾焚烧飞灰中重金属的蒸发特性[J]. 过程工程学报, 2009, 9(5):892-896.
    XIE Y J, ZHU J X. Leaching toxicity and heavy metal bioavailability of medical waste incinerator fly ash[J]. Journal of Material Cycles and Waste Management, 2013, 15:440-448.
    刘汉桥, 武振华, 徐仙, 等. 医疗垃圾焚烧飞灰的酸浸及硫化[J]. 环境科学与技术, 2015,38(9):88-92.
    TOSINE H M, CLEMENT R E, OZVACIC V, et al. Levels of PCDD/PCDF and other chlorinated organics in municipal refuse[J]. Chemosphere, 1985, 14:821-827.
    HOU S, ALTARAWNEH M, KENNEDY E M, et al. Formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) from oxidation of 4,4-dichlorobiphenyl (4,4-DCB)[J]. Proceedings of the Combustion Institute, 2019, 37:1075-1082.
    DICKSON L C, LENOIR D, HUTZINGER O. Surface-catalyzed formation of chlorinated dibenzodioxins and dibenzofurans during incineration[J]. Chemosphere, 1989, 19:277-282.
    BORN J G P, MULDER P, LOUW R. Fly ash mediated reactions of phenol and monochlorophenols:oxychlorination, deep oxidation, and condensation[J]. Environmental Science and Technology, 1993, 27:1849-1863.
    MCKAY G. Dioxin characterisation; formation and minimisation during municipal solid waste (MSW) incineration, review[J]. Chemical Engineering Journal, 2002, 86:343-368.
    GUNES G, SARAL A, YILDIZ S, et al. Determination of optimum dose of adsorbent for PCDD/F removal in the flue gas of a medical waste incineration plant[J]. Chemical Engineering Research and Design, 2015, 104:695-702.
    DONG J I, LEE J K, KO Y H, et al. The effect of activated carbon injection rate to dioxin emission level in an incinerator SDA+B/F APC[C]//Proceeding of 21th International Symposium on Halogenated Environmental Organic Pollutants and Persistent Organic Pollutants, 2001.
    SHEMWELL B, LEVENDIS Y A, SIMONS G A. Laboratory study on the high-temperature capture of HCl gas by dry-injection of calcium-based sorbents[J]. Chemosphere, 2001, 42:785-796.
    LIU W B, ZHENG M H, ZHANG B, et al. Inhibition of PCDD/Fs formation from dioxin precursors by calcium oxide[J]. Chemosphere, 2005, 60:785-790.
    ZHANG M M, YANG J, ALFONS B, et al. PCDD/F catalysis by metal chlorides and oxides[J]. Chemosphere, 2016, 159:536-544.
    XIA G, AJIT G, PHILLIP M P, et al. Role of Fe2O3 in fly ash surrogate on PCDD/Fs formation from 2-monochlorophenol[J]. Chemosphere, 2019, 226:809-816.
    CHEN T, YAN J H, LU S Y, et al. Characteristic of polychlorinated dibenzo-p-dioxins and dibenzofurans in fly ash from incinerators in China[J]. Journal of Hazardous Materials, 2008, 150:510-514.
    WEI G X, LIU H Q, ZHANG R, et al. Application of microwave energy in the destruction of dioxins in the froth product after flotation of hospital solid waste incinerator fly ash[J].Journal of Hazardous Materials, 2017, 325:230-238.
    YAN J H, PENG Z, LU S Y, et al. Degradation of PCDD/Fs by mechanochemical treatment of fly ash from medical waste incineration[J].Journal of Hazardous Materials, 2007, 147:652-657.
    CHEN M W, LIN T C, WANG L C, et al. The PCDD/F removal efficiency of a medical waste incinerator dual-bag filter system[J]. Aerosol and Air Quality Research, 2014, 14:1223-1231.
    陈佳, 陈彤, 王奇, 等.中国危险废物和医疗废物焚烧处置行业二噁英排放水平研究[J]. 环境科学学报, 2014, 34(4):973-979.
    YAN M, LI X D, LU S Y, et al. Persistent organic pollutant emissions from medical waste incinerators in China[J]. Journal of Material Cycles and Waste Management, 2011, 13(3):213-218.
    沈东升, 郑元格, 姚俊, 等. 典型固体废物焚烧飞灰的污染物特性研究[J]. 环境科学, 2011, 32(9):2610-2616.
    彭政. 垃圾焚烧飞灰二噁英的控制技术研究[D]. 杭州:浙江大学, 2007.
    PENG Z, DING Q, SUN Y Z, et al. Characterization of mechanochemical treated fly ash from a medical waste incinerator[J]. Journal of Environmental Sciences, 2010, 22(10):1643-1648.
    王宇峰, 李晓东, 金剑, 等. 水热法降解医疗废物焚烧飞灰中二恶英的研究[J]. 中国电机工程学报, 2010, 30(26):56-61.
    陈冠飞. 零价铁去除医疗垃圾焚烧飞灰中重金属的研究[D]. 新乡:河南师范大学, 2017.
    SUKANDAR, PADMI T, TANAKA M, et al. Chemical stabilization of medical waste fly ash using chelating agent and phosphates:heavy metals and ecotoxicity evaluation[J]. Waste Management, 2009, 29:2065-2070.
    DELIYANNI E A, KYZAS G Z, MATIS K A. Various flotation techniques for metal ions removal[J]. Journal of Molecular Liquids, 2017, 225:260-264.
    MINOCHA A K, JAIN N, VERMA C L. Effect of inorganic materials on the solidification of heavy metal sludge[J]. Cement and Concrete Research, 2003, 33:1695-1701.
    刘汉桥, 魏国侠, 张曙光, 等. 活性炭对医疗垃圾焚烧飞灰水泥固化的影响[J]. 过程工程学报, 2008, 8(5):953-956.
    KATSUURA H, INOUE T, HIRAOKA M, et al. Full-scall plant study on fly ash treatment by the acid extraction process[J]. Waste Management, 1996, 16(5/6):491-499.
    FERONE C, COLANGELO F, MESSINA F, et al. Recycling of pre-washed municipal solid waste incinerator fly ash in the manufacturing of low temperature setting geopolymer materials[J]. Materials, 2013, 6:3420-3437.
    ANASTASIADOU K, CHRISTOPOULOS K, MOUSIOS E, et al. Solidification/stabilization of fly and bottom ash from medical waste incineration facility[J]. Journal of Hazardous Materials, 2012, 207/208:165-170.
    MA W C, CHEN D M, PAN M H, et al. Performance of chemical chelating agent stabilization and cement solidification on heavy metals in MSWI fly ash:a comparative study[J]. Journal of Environmental Management, 2019, 247:169-177.
    ECKE H, SAKANAKURA H, MATSUTO T, et al. State-of-the-art treatment processes for municipal solid waste incinet ation residues in Japan[J]. Waste Management and Research, 2000, (18):41-51.
    刘汉桥, 蔡九菊, 邵春岩, 等. 我国垃圾焚烧灰熔融炉的应用前景[J]. 工业炉, 2006, 28(5):7-11.
    HAGENMAIER H, KRAFT M, BRUNNER H, et al. Catalytic effects of fly ash from waste incineration facilities on the formation and decomposition of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans[J]. Environmental Science and Technology, 1987, 21(11):1080-1084.
    SONG G J, KIM S H, SEO Y C, et al. Dechlorination and destruction of PCDDs/PCDFs in fly ashes from municipal solid waste incinerators by low temperature thermal treatment[J]. Chemosphere, 2008, 71:248-257.
    WU H L, LU S Y, YAN J H, et al. Thermal removal of PCDD/Fs from medical waste incinerator fly ash:effect of temperature and nitrogen flow rate[J]. Chemosphere, 2011, 84:361-367.
    金剑, 李晓东, 池涌, 等. 水热-碳酸钠法稳定化医疗废物焚烧炉飞灰中重金属的研究[J]. 环境科学, 2010, 31(4):1101-1107.
    JIAN J, LI X D, YONG C, et al. Co-disposal of heavy metals containing waste water and medical waste incinerator fly ash by hydrothermal process with addition of sodium carbonate, a case study on Cu(Ⅱ) removal[J]. Water, Air, & Soil Pollution, 2010, 209:391-400.
    王磊, 金剑, 李晓东, 等. 碱性水热法同步稳定城市垃圾/医疗废物焚烧飞灰与废水中重金属的研究[J]. 环境科学, 2010, 31(8):1973-1980.
    ZHANG F S, ITOH H. Extraction of metals from municipal solid waste incinerator fly ash by hydrothermal process[J]. Journal of Hazardous Materials, 2006, B136:663-670.
    HU Y Y, ZHANG P F, LI J Y, et al. Stabilization and separation of heavy metals in incinerator fly ash during the hydrothermal treatment process[J]. Journal of Hazardous Materials, 2015, 299:149-157.
    RUSEN A, SUNKAR A S, TOPKAYA Y A. Zinc and lead extraction from Çinkur leach residues by using hydrometallurgical method[J]. Hydrometallurgy, 2008, 93:45-50.
    SINADÍNOVIC D, KAMBÉROVI Ž, ŠUTIC A. Leaching kinetics of lead from lead (Ⅱ) sulphate in aqueous calcium chloride and magnesium chloride Solutions[J]. Hydrometallurgy, 1997, 47:137-147.
    MA D C, FENG Q G, CHEN B Q, et al. Insight into chlorine evolution during hydrothermal carbonization of medical waste model[J]. Journal of Hazardous Materials, 2019, 380, 120847.
    王宇峰. 医疗废物焚烧飞灰重金属的迁移、浸出特性及二恶英的水热法降解研究[D]. 杭州:浙江大学, 2011.
    SHI D Z, MA J Y, WANG H L, et al. Detoxification of PCBs in fly ash from MSW incineration by hydrothermal treatment with composite silicon-aluminum additives and seed induction[J]. Fuel Processing Technology, 2019, 195:106157.
    YAMASAKI N, YASUI T, MATSUOKA K. Hydrothermal decomposition of polychlorinated biphenyls[J]. Environmental Science and Technology, 1980, 14:550-552.
    MOUTON J, MERCIER G, BLAIS J F. Amphoteric surfactants for PAH and lead polluted-soil treatment using flotation[J]. Water, Air, & Soil Pollution, 2009, 197:381-393.
    LIU H Q, LIU F, WEI G X, et al. Two-Step flotation treatment for removal of toxic matter from hospital solid waste incinerator fly ash[J]. Aerosol and Air Quality Research, 2017, 17:1329-1340.
  • 加载中
计量
  • 文章访问数:  252
  • HTML全文浏览量:  38
  • PDF下载量:  9
  • 被引次数: 0
出版历程
  • 收稿日期:  2019-11-16

目录

    /

    返回文章
    返回