酸性条件下微米级锌铜双金属降解罗丹明B

李炜; 王可欣; 龚珍林; 张继光; 刘保霞; 马梦婕; 兰叶青

doi:10.13205/j.hjgc.202011010

酸性条件下微米级锌铜双金属降解罗丹明B

doi: 10.13205/j.hjgc.202011010

1. 南京农业大学资源与环境科学学院, 南京 210095;
2. 江苏中烟工业有限责任公司, 南京 210011;
3. 南京工业大学能源科学与工程学院, 南京 211816;
4. 中国农业科学院烟草研究所, 山东青岛 266101;
5. 南京农业大学理学院, 南京 210095

详细信息

作者简介:
李炜(1989-),男,工程师,主要研究方向为环境污染与控制。1019275782@qq.com

通讯作者:
兰叶青(1960-),男,博士,教授,主要研究方向为重金属和有机污染物控制。lanyq102@njau.edu.cn

计量
- 文章访问数: 173
- HTML全文浏览量: 35
- PDF下载量: 6
- 被引次数: 0
出版历程
- 收稿日期: 2019-10-09
- 网络出版日期: 2021-04-23
- 刊出日期: 2021-04-23

EFFICIENT DEGRADATION OF RHODAMINE B BY MICRO-SCALE ZINC-COPPER (mZn/Cu) BIMETALLIC PARTICLES UNDER ACIDIC CONDITION

1. College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095, China;
2. China Tobacco Jiangsu Industrial Co., Ltd, Nanjing 210011, China;
3. School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China;
4. Tobacco Research Institute, Chinese Academy of Agricultural Sciences, Qingdao 266101, China;
5. College of Sciences, Nanjing Agricultural University, Nanjing 210095, China

摘要

摘要: 通过置换反应得到最佳组成的微米级锌铜双金属（以下简称mZn/Cu），以罗丹明B为目标污染物，研究了溶液初始pH、mZn/Cu用量和罗丹明B浓度等因素对mZn/Cu降解罗丹明B的影响，并通过单因素实验，确定了罗丹明B降解的最优条件。与单金属材料相比，由于mZn/Cu构成微电池显著提高了其供给电子的能力和化学活性，从而导致罗丹明B被更为有效降解。通过向反应体系中充入氮气去除溶解氧和加入自由基捕集剂叔丁醇和对苯醌，罗丹明B的降解率均有显著降低，并证实了在酸性条件下溶解氧从mZn/Cu表面获得电子，产生出具有强氧化性的羟基自由基和超氧根自由基，最终导致罗丹明B的氧化降解。由此可见，研究不仅基于通过简单置换反应获得的mZn/Cu材料提出了1种新的高级氧化技术，而且还探讨了其作用机理，从而为实现低成本、高效率的水体有机污染物降解提供有价值的参考。
- 罗丹明B /
- 微米级锌铜双金属 /
- 自由基 /
- 降解机理
Abstract: In this paper, micro-scale zinc-copper (mZn/Cu) bimetallic particles were prepared via replacement reaction and applied in the removal of Rhodamine B. The effects of initial pH, mZn/Cu dosage and initial concentration on the degradation of Rhodamine B were investigated. The optimal conditions for the degradation of of Rhodamine B was determined through single-factor experiment. As compared with single metals, the formation of microbatteries on mZn/Cu greatly improved its ability to provide electrons and its chemical activity, resulting in more efficient degradation of Rhodamine B. When N₂ was bubbled into the reaction system to remove the dissolved oxygen and the scavengers such as tert-butyl alcohol (TBA) and benzoquinone (BQ) were introduced, the degradation of Rhodamine B was also greatly inhibited. This proved that under acidic and aerobic conditions, the dissolved oxygen could accepted electrons from the surface of mZn/Cu to produce ·OH and O₂^-· radicals responsible for the rapid removal of Rhodamine B. Thus, this study not only provided a low-cost and high-efficiency technology for the degradation of organic contaminants in aqueous solution, but also put insight into the mechanism of the reaction.
- Rhodamine B /
- micro-scale zinc-copper bimetallic particles /
- radicals /
- degradation mechanism

HTML全文

参考文献(24)

尤宏, 姚杰, 罗薇楠, 等. TiO₂/SiO₂ 催化剂光催化降解罗丹明B的表观动力学[J]. 环境科学, 2006, 27(11):2154-2158.

王春英, 江桐桐, 周丹, 等. 掺铁钨酸铋的制备及光催化降解罗丹明B的研究[J]. 江西理工大学学报, 2013,34(1):7-12.

ABBASI M, SOLEYMANI A R, PARSA J B. Degradation of Rhodamine B by an electrochemical ozone generating system consist of a Ti anode coated with nanocomposite of Sn-Sb-Ni oxide[J]. Process Safety and Environmental Protection, 2015, 94:140-148.

LENG Y Q, GUO W L, SHI X, et al. Degradation of rhodamine B by persulfate activated with Fe₃O₄:effect of polyhydroquinone serving as an electron shuttle[J]. Chemical Engineering Journal, 2014, 240:338-343.

HOU M F, LIAO L, ZHANG W D, et al. Degradation of rhodamine B by Fe⁰-based Fenton process with H₂O₂[J]. Chemosphere, 2011, 83(9):1279-1283.

ALHAMEDI F H, RAUF M A, ASHRAF S S. Degradation studies of Rhodamine B in the presence of UV/H₂O₂[J]. Desalination, 2009, 239(1/2/3):159-166.

KALLEL M, BELAID C, BOUSSAHEL R, et al. Olive mill wastewater degradation by Fenton oxidation with zero-valent iron and hydrogen peroxide[J]. Journal of Hazardous Materials, 2009, 163(2/3):550-554.

LIAO C J, CHUNG T L, CHEN W L, et al. Treatment of pentachlorophenol-contaminated soil using nano-scale zero-valent iron with hydrogen peroxide[J]. Journal of Molecular Catalysis A:Chemical, 2007, 265(1/2):189-194.

KEENAN C R, SEDLAK D L. Factors affecting the yield of oxidants from the reaction of nanoparticulate zero-valent iron and oxygen[J]. Environmental Science & Technology, 2008, 42(4):1262-1267.

SUZUKI TASUMA, MORIBE M, OYAMA YUKINORI, et al. Mechanism of nitrate reduction by zero-valent iron:equilibrium and kinetics studies[J]. Chemical Engineering Journal, 2012, 183:271-277.

WEN G, WANG S J, MA J, et al. Oxidative degradation of organic pollutants in aqueous solution using zero valent copper under aerobic atmosphere condition[J]. Journal of Hazardous Materials, 2014, 275:193-199.

XU W Y, GAO T Y. Dechlorination of carbon tetrachloride by the catalyzed Fe-Cu process[J]. Journal of Environmental Sciences, 2007, 19(7):792-799.

MA L M, DING Z G, GAO T Y, et al. Discoloration of methylene blue and wastewater from a plant by a Fe/Cu bimetallic system[J]. Chemosphere, 2004, 55(9):1207-1212.

LIEN H L, ZHANG W X. Enhanced dehalogenation of halogenated methanes by bimetallic Cu/Al[J]. Chemosphere, 2002, 49(4):371-378.

LAI B, ZHANG Y H, CHEN Z Y, et al. Removal of p-nitrophenol (PNP) in aqueous solution by the micron-scale iron-copper (Fe/Cu) bimetallic particles[J]. Applied Catalysis B:Environmental, 2014, 144:816-830.

JI Q Q, LI J, XIONG Z K, et al. Enhanced reactivity of microscale Fe/Cu bimetallic particles (mFe/Cu) with persulfate (PS) for p-nitrophenol (PNP) removal in aqueous solution[J]. Chemosphere, 2017, 172:10-20.

LI W, CHEN C, ZHU J Y, ZHOU LX, Lan Y Q, Efficient removal of aniline by micro-scale zinc-copper (mZn/Cu) bimetallic particles in acidic solution:an oxidation degradation mechanism via radicals[J]. Journal of hazardous materials, 2019, 366:482-491.

ZHANG J, WU Y, QIN C, et al. Rapid degradation of aniline in aqueous solution by ozone in the presence of zero-valent zinc[J]. Chemosphere, 2015, 141:258-264.

XIE H, YE X L, DUAN K Y, et al. CuAu-ZnO-graphene nanocomposite:a novel graphene-based bimetallic alloy-semiconductor catalyst with its enhanced photocatalytic degradation performance[J]. Journal of Alloys and Compounds, 2015, 636:40-47.

SHU H Y, CHANG M C, CHEN C C, et al. Using resin supported nano zero-valent iron particles for decoloration of Acid Blue 113 azo dye solution[J]. Journal of Hazardous Materials, 2010, 184(1/2/3):499-505.

QIU X H, FANG Z Q, LIANG B, et al. Degradation of decabromodiphenyl ether by nano zero-valent iron immobilized in mesoporous silica microspheres[J]. Journal of Hazardous Materials, 2011, 193:70-81.

PENG A, HUANG M Y, CHEN Z Y, et al. Oxidative coupling of acetaminophen mediated by Fe³⁺-saturated montmorillonite[J]. Science of the Total Environment, 2017, 595:673-680.

KIM D G, KO S O. Cu@Fe₃O₄ core-shell nanoparticle-catalyzed oxidative degradation of the antibiotic oxytetracycline in pre-treated landfill leachate[J]. Chemosphere, 2018, 191:639-650.

JUN B M, ELANCHEZHIYAN S S D, YOON Y, et al. Accelerated photocatalytic degradation of rhodamine B over carbonate-rich lanthanum-substituted zinc spinel ferrite assembled reduced graphene oxide by ultraviolet (UV)-activated persulfate[J]. Chemical Engineering Journal, 2020,393:124733.

施引文献

资源附件(0)

访问统计