RESEARCH PROGRESS IN REMOVAL OF PHOSPHATE FROM WATER BY BIOCHAR
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摘要: 生物炭作为1种环境友好型吸附材料,可有效去除并回收水体中的磷,由此也成为当前的研究热点之一。综述了目前国内外生物炭吸附磷酸盐及磷素回收研究现状,主要总结了控制生物炭吸附磷酸盐的4种主要机制,阐述了影响生物炭吸附除磷过程中的主要影响因素,介绍了目前应用研究的方向并提出生物炭在实际应用中所面临的问题并对未来研究方向进行了展望,以期为未来研究及推广应用提供理论支撑。Abstract: Biochar, as an environmentally friendly adsorbent, can effectively remove and recover phosphorus from water. Therefore, it has become the research hotspot. In this paper, the current research progress of phosphate adsorption and recovery at home and abroad were reviewed. Four main mechanisms for controlling the adsorption of phosphate by biochar were summarized, and the main influencing factors in the process of phosphorus removal by biochar were described. The direction of applied research was introduced and the problems of biochar in practical application were put forward. Suggestion on the future research was proposed in order to provide theoretical support for future research and application.
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Key words:
- biochar /
- phosphate /
- adsorption /
- mechanism /
- application
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FINK G, ALCAMO J, FLÖRKE M, et al. Phosphorus loadings to the world's largest lakes:sources and trends[J]. Global Biogeochemical Cycles, 2018, 32(4):617-634. 刘毛. 人工湿地玉米芯生物炭基质净化效果与处置研究[D].武汉:武汉大学,2018. 郑冰玉,张树军,杨岸明. 磷酸铵镁结晶法用于污水处理流程中磷元素回收进展[J].环境工程,2019,37(6):90-95. NOVAIS S V, ZENERO M D O, Barreto M S C, et al. Phosphorus removal from eutrophic water using modified biochar[J]. Science of the Total Environment, 2018, 633:825-835. BACELO H, PINTOR A M A, SANTOS S C R, et al. Performance and prospects of different adsorbents for phosphorus uptake and recovery from water[J]. Chemical Engineering Journal, 2020,381:122566. MA Z H, LI Q, YUE Q Y, et al. Adsorption removal of ammonium and phosphate from water by fertilizer controlled release agent prepared from wheat straw[J]. Chemical Engineering Journal, 2011, 171(3):1209-1217. SHANABLEH A, ENSHASI G, ELSERGANY M. Phosphorous adsorption using Al3+/Fe3+-modified bentonite adsorbents:effect of Al3+ and Fe3+ combinations[J]. Desalination and Water Treatment, 2016, 57(33):15628-15634. WU H, DONG X, LIU H. Evaluating fluorescent dissolved organic matter released from wetland-plant derived biochar:effects of extracting solutions[J]. Chemosphere, 2018, 212:638-644. 熊静,王蓓丽,刘渊文,等. 生物炭去除土壤重金属的研究进展[J].环境工程,2019,37(9):182-187. BOLTON L, JOSEPH S, GREENWAY M, et al. Phosphorus adsorption onto an enriched biochar substrate in constructed wetlands treating wastewater[J]. Ecological Engineering:X, 2019, 1(C):100005. 褚军,薛建辉,金梅娟,等. 生物炭对农业面源污染氮、磷流失的影响研究进展[J].生态与农村环境学报,2014,30(4):409-415. 刘玉学,唐旭,杨生茂,等. 生物炭对土壤磷素转化的影响及其机理研究进展[J].植物营养与肥料学报,2016,22(6):1690-1695. SUN D, HALE L,KAR G,et al. Phosphorus recovery and reuse by pyrolysis:applications for agriculture and environment[J]. Chemosphere, 2018, 194:682-691. 金烁,操家顺,罗景阳. 镧改性材料对水中磷酸盐去除的研究进展[J].净水技术,2020,39(2):66-76. RAJAPAKSHA A U,CHEN S S,TSANG D C W,et al. Engineered/designer biochar for contaminant removal/immobilization from soil and water:potential and implication of biochar modification[J]. Chemosphere, 2016, 148:276-291. 易鹏,吴国娟,段文焱,等. 生物炭的改性和老化及环境效应的研究进展[J].材料导报,2020,34(3):43-49. YIN Q Q, ZHANG B D, WANG R K, et al. Biochar as an adsorbent for inorganic nitrogen and phosphorus removal from water:a review[J]. Environmental Science and Pollution Research, 2017, 24(34):26297-26309. WU B L, WAN J, ZHANG Y Y, et al. Selective phosphate removal from water and wastewater using sorption:process fundamentals and removal mechanisms[J]. Environmental Science & Technology, 2020,54(1):50-66. SINGH B P, COWIE A L, SMERNIK R J. Biochar carbon stability in a clayey soil as a function of feedstock and pyrolysis temperature[J]. Environmental Science & Technology, 2012, 46(21):11770-11778. 孔丝纺,姚兴成,张江勇,等. 生物质炭的特性及其应用的研究进展[J].生态环境学报,2015,24(4):716-723. LIANG B Q, LEHMANN J, SOLOMON D, et al. Stability of biomass-derived black carbon in soils[J]. Geochimica et Cosmochimica Acta, 2008, 72(24):6069-6078. MOHAN D, SARSWAT A, OK Y S, et al. Organic and inorganic contaminants removal from water with biochar, a renewable, low cost and sustainable adsorbent:a critical review[J]. Bioresource Technology, 2014, 160:191-202. RIDDLE M, CEDERLUND H, SCHMIEDER F, et al. Magnetite-coated biochar as a soil phosphate filter:from laboratory to field lysimeter[J]. Geoderma, 2018, 327:45-54. VIKRANT K, KIM K H, OK Y S, et al. Engineered/designer biochar for the removal of phosphate in water and wastewater[J]. Science of the Total Environment, 2018, 616:1242-1260. 祝天宇,卢泽玲,刘月娥,等. 镁改性生物炭制备条件对其氮、磷去除性能的影响[J].环境工程,2018,36(1):37-41. 许润,石程好,唐倩,等. 氢氧化镧改性介孔稻壳生物炭除磷性能[J].环境科学,2019,40(4):1834-1841. XU Q Y, CHEN Z B, WU Z S, et al. Novel lanthanum doped biochars derived from lignocellulosic wastes for efficient phosphate removal and regeneration[J]. Bioresource Technology, 2019,289:121600. WANG Z H, GUO H Y, SHEN F, et al. Biochar produced from oak sawdust by Lanthanum (La)-involved pyrolysis for adsorption of ammonium (NH4+), nitrate (NO3-), and phosphate (PO43-)[J]. Chemosphere, 2015, 119:646-653. 王盛华,朱丹晨,邵敬爱,等. MgO改性莲蓬壳生物炭的制备及其磷吸附特性[J].环境科学,2019,40(11):4987-4995. PINTO M C E, DA SILVA D D, GOMES A L A, et al. Biochar from carrot residues chemically modified with magnesium for removing phosphorus from aqueous solution[J]. Journal of Cleaner Production, 2019, 222:36-46. 刘舒蕾,彭慧君,杨佳怡,等. 水生植物生物质炭去除水体中氮磷性能[J].环境科学,2019,40(11):4980-4986. YANG Y, WEI Z B, ZHANG X L, et al. Biochar from Alternanthera philoxeroides could remove Pb (Ⅱ) efficiently[J]. Bioresource Technology, 2014, 171:227-232. 唐登勇,黄越,胥瑞晨,等. 改性芦苇生物炭对水中低浓度磷的吸附特征[J].环境科学,2016,37(6):2195-2201. LIU X N, SHEN F, QI X H. Adsorption recovery of phosphate from aqueous solution by CaO-biochar composites prepared from eggshell and rice straw[J]. Science of the Total Environment, 2019, 666:694-702. JUNG K W, LEE S, LEE Y J. Synthesis of novel magnesium ferrite (MgFe2O4)/biochar magnetic composites and its adsorption behavior for phosphate in aqueous solutions[J]. Bioresource Technology, 2017, 245:751-759. CAI R, WANG X, JI X H, et al. Phosphate reclaim from simulated and real eutrophic water by magnetic biochar derived from water hyacinth[J]. Journal of Environmental Management, 2017, 187:212-219. BOLBOL H, FEKRI M, HEJAZI-MEHRIZI M. Layered double hydroxide-loaded biochar as a sorbent for the removal of aquatic phosphorus:behavior and mechanism insights[J]. Arabian Journal of Geosciences, 2019, 12(16):503. ZHANG Z R, YAN L G, YU H Q, et al. Adsorption of phosphate from aqueous solution by vegetable biochar/layered double oxides:fast removal and mechanistic studies[J]. Bioresource Technology, 2019, 284:65-71. 崔孝强. 水体修复植物基生物炭的环境应用及其机理研究[D].杭州:浙江大学,2018. ZHANG M, GAO B, YAO Y, et al. Phosphate removal ability of biochar/MgAl-LDH ultra-fine composites prepared by liquid-phase deposition[J]. Chemosphere, 2013, 92(8):1042-1047. YIN Q Q, ZHANG B D, WANG R K, et al. Phosphate and ammonium adsorption of sesame straw biochars produced at different pyrolysis temperatures[J]. Environmental Science and Pollution Research, 2018, 25(5):4320-4329. 张倩. 层状双金属氢氧化物除磷材料及氨基酸插层改性性能研究[D].重庆:重庆大学,2018. 赵艳. 负载纳米Fe3O4生物炭的制备及其异相Fenton催化应用研究[D].南京:南京理工大学,2018. LI X P, WANG C B, ZHANG J G, et al. Preparation and application of magnetic biochar in water treatment:a critical review[J]. Science of the Total Environment, 2020,711:134847. 易蔓. 沼渣基生物质炭对规模化猪场沼液磷的回收利用研究[D].重庆:西南大学,2019. YANG Q, WANG X L, LUO W, et al. Effectiveness and mechanisms of phosphate adsorption on iron-modified biochars derived from waste activated sludge[J]. Bioresource Technology, 2018, 247:537-544. 宋小宝,何世颖,冯彦房,等. 载镧磁性水热生物炭的制备及其除磷性能[J].环境科学,2020,41(2):773-783. XU K N, LIN F Y, DOU X M, et al. Recovery of ammonium and phosphate from urine as value-added fertilizer using wood waste biochar loaded with magnesium oxides[J]. Journal of Cleaner Production, 2018, 187:205-214. YAO Y, GAO B, CHEN J J, et al. Engineered biochar reclaiming phosphate from aqueous solutions:mechanisms and potential application as a slow-release fertilizer[J]. Environmental Science & Technology, 2013, 47(15):8700-8708. XIONG W P, TONG J, YANG Z H, et al. Adsorption of phosphate from aqueous solution using iron-zirconium modified activated carbon nanofiber:performance and mechanism[J]. Journal of Colloid and Interface Science, 2017, 493:17-23. MICHÁLEKOVÁ-RICHVEISOVÁ B, FRIŠTÁK V, PIPÍŠKA M, et al. Iron-impregnated biochars as effective phosphate sorption materials[J]. Environmental Science and Pollution Research, 2017, 24(1):463-475. 易蔓,李婷婷,李海红,等. Ca/Mg负载改性沼渣生物炭对水中磷的吸附特性[J].环境科学,2019,40(3):1318-1327. LI R H, WANG J J, ZHOU B Y, et al. Enhancing phosphate adsorption by Mg/Al layered double hydroxide functionalized biochar with different Mg/Al ratios[J]. Science of the Total Environment, 2016, 559:121-129. KARTHIKEYAN P, MEENAKSHI S. Synthesis and characterization of Zn-Al LDHs/activated carbon composite and its adsorption properties for phosphate and nitrate ions in aqueous medium[J]. Journal of Molecular Liquids, 2019, 296:111766. 张博文. 铁改性花生壳生物炭吸附除磷性能及机理研究[D].北京:中国地质大学(北京),2018. EDUAH J O, NARTEY E K, ABEKOE M K, et al. Mechanism of orthophosphate (PO43--P) adsorption onto differrent biochars[J]. Environmental Technology & Innovation, 2020, 17:100572. 郅蒙蒙,王鹏飞,侯泽英,等. NH4+对镁改性生物炭除磷效果的影响[J].环境科学,2019,40(2):669-676. XUE Y J, HOU H B, ZHU S J. Characteristics and mechanisms of phosphate adsorption onto basic oxygen furnace slag[J]. Journal of Hazardous Materials, 2009, 162(2/3):973-980. ACELAS N Y, MARTIN B D, LÓPEZ D, et al. Selective removal of phosphate from wastewater using hydrated metal oxides dispersed within anionic exchange media[J]. Chemosphere, 2015, 119:1353-1360. CHEN W F, DING S Y, LIN Z R, et al. Different effects of N2-flow and air-limited pyrolysis on bamboo-derived biochars' nitrogen and phosphorus release and sorption characteristics[J]. Science of the Total Environment, 2020,711:134828. ZHONG Z X, YU G W, MO W T, et al. Enhanced phosphate sequestration by Fe (Ⅲ) modified biochar derived from coconut shell[J]. RSC Advances, 2019, 9(18):10425-10436. WU B L, FANG L P, FORTNER J D, et al. Highly efficient and selective phosphate removal from wastewater by magnetically recoverable La (OH)3/Fe3O4 nanocomposites[J]. Water Research, 2017, 126:179-188. REN J, LI N, ZHAO L, et al. Pretreatment of raw biochar and phosphate removal performance of modified granular iron/biochar[J]. Transactions of Tianjin University, 2017, 23(4):340-350. LI W, PIERRE-LOUIS A M, KWON K D, et al. Molecular level investigations of phosphate sorption on corundum (α-Al2O3) by 31P solid state NMR, ATR-FTIR and quantum chemical calculation[J]. Geochimicaet Cosmochimica Acta, 2013, 107:252-266. 李安玉,李双莉,余碧戈,等. 镁浸渍生物炭吸附氨氮和磷:制备优化和吸附机理[J].化工学报,2020,71(4):1683-1695. YIN Q Q, WANG R K, ZHAO Z H. Application of Mg-Al-modified biochar for simultaneous removal of ammonium, nitrate, and phosphate from eutrophic water[J]. Journal of Cleaner Production, 2018, 176:230-240. 蔡茹. 负载铁生物炭对富营养化水体中磷的捕集与再利用[D].长沙:湖南师范大学,2017. 任婧. 铁/生物炭复合材料的制备及对水中磷的吸附性能的研究[D].天津:天津大学,2016. JUNG K W, JEONG T U, KANG H J, et al. Characteristics of biochar derived from marine macroalgae and fabrication of granular biochar by entrapment in calcium-alginate beads for phosphate removal from aqueous solution[J]. Bioresource Technology, 2016, 211:108-116. PINTO M C E, SILVA D D, Gomes A L A, et al. Film based on magnesium impregnated biochar/cellulose acetate for phosphorus adsorption from aqueous solution[J]. RSC Advances, 2019, 9(10):5620-5627. FANG C, ZHANG T, LI P, et al. Application of magnesium modified corn biochar for phosphorus removal and recovery from swine wastewater[J]. International Journal of Environmental Research and Public Health, 2014, 11(9):9217-9237. 石程好. 镧负载稻壳基生物炭除磷性能研究[D].武汉:华中科技大学,2018.
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