电解锰渣基方沸石的制备及其对Pb<sup>2+</sup>的吸附性能

曾越; 李徐立; 陈宇驰; 万沙; 周旻; 侯浩波

doi:10.13205/j.hjgc.202011029

电解锰渣基方沸石的制备及其对Pb²⁺的吸附性能

doi: 10.13205/j.hjgc.202011029

曾越^1,2,
李徐立^1,2,
陈宇驰^1,2,
万沙^1,2,
周旻^1,2,
侯浩波^1,2, ,

1. 武汉大学资源与环境科学学院, 武汉 430072;
2. 武汉大学湖北环境修复材料工程技术研究中心, 武汉 430079

详细信息

作者简介:
曾越(1995-),女,硕士研究生,主要研究方向为固体废物资源化与环境修复。Jane.zengyue@qq.com

通讯作者:
侯浩波(1963-),男,博士,教授,主要研究方向为固体废物资源化与环境修复。Hhb-bhh@163.com

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出版历程
- 收稿日期: 2019-10-22
- 网络出版日期: 2021-04-23
- 刊出日期: 2021-04-23

PREPARATION OF ANALCITE BASED ON ELECTROLYTIC MANGANESE SLAG AND STUDY ON ITS Pb²⁺ ADSORPTION PROPERTY

ZENG Yue^1,2,
LI Xu-li^1,2,
CHEN Yu-chi^1,2,
WAN Sha^1,2,
ZHOU Min^1,2,
HOU Hao-bo^{1,2
, ,}

1. School of Resource and Environment Science, Wuhan University, Wuhan 430072, China;
2. Provincial Engineering Research Center for Environmental Remediation Materials, Wuhan University, Wuhan 430079, China

摘要

摘要: 以电解锰渣为原料，经过"弱酸除杂-碱融活化-室温陈化-晶化"水热合成反应体系，在分别外加铝源和硅源的条件下制备方沸石ANA-A及ANA-S，运用XRF、XRD、SEM-EDS和BET等表征手段对2种方沸石的化学组成、晶相结构、微观形貌和比表面积进行分析。结果表明：在煅烧温度750℃、合成温度180℃、水热反应时间8 h的条件下，外加铝源和硅源均可合成方沸石。进一步研究2种沸石对水溶液中Pb²⁺的静态吸附性能，其所合成的电解锰渣基ANA-A及ANA-S方沸石均可以很好地用Langmuir等温模型拟合，属于单分子层吸附，饱和吸附量分别为161.29，185.19 mg/g，对初始浓度为100 mg/L的Pb²⁺去除率分别为93.69%和95.47%，且均符合Lagergren准二级动力学模型，属于化学吸附；两者中ANA-S的吸附效果更好。
- 电解锰渣 /
- 水热合成 /
- 方沸石 /
- Pb²⁺吸附
Abstract: With electrolytic manganese slag as raw material, after the weak acid complexing, activation of alkali-melt, aging at room temperature and crystallization of hydrothermal synthesis system, analcite ANA-A and ANA-S was prepared by adding aluminum and silicon respectively. Performance of the two kinds of analcime such as chemical composition, crystal phase structure, microstructure, and specific surface area were analyzed by using characterization methods of XRF, XRD, SEM, EDS and BET. The results showed that the analcite could be successfully synthesized with both the addition of aluminum and silicon at the calcination temperature of 750 ℃, the synthesis temperature of 180 ℃, and the hydrothermal reaction time of 8 h. Further study on two kinds of zeolite Pb²⁺ in aqueous solution of static adsorption showed that ANA-A and ANA-S could fitting Langmuir isotherm model well, accorded to the monolayer adsorption. Their saturated adsorption capacity were 161.29 mg/g and 185.19 mg/g, and the initial concentration of 100 mg/L of Pb²⁺ removal rate reached 93.69% and 95.47% respectively, comlied with the lagergren quasi-second order kinetics model, and were defined as chemical adsorption. ANA-S has better adsorption effect between the two adsorbers.
- electrolytic manganese slag /
- hydrothermal method /
- analcite /
- Pb²⁺ adsorption

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