PASSIVATION OF CADMIUM IN SOIL BY WALNUT SHELL BIOCHAR
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摘要: 通过室内模拟试验,研究了核桃壳生物炭(BC400、BC500、BC600)对人工Cd污染土壤(20 mg/kg)pH、Cd赋存形态分布的影响,并探究可能的修复机理。结果显示:经56 d修复后,与空白对照组相比,10%添加量的核桃壳生物炭BC400、BC500、BC600分别使土壤pH升高了1.07、1.31、1.38,弱酸可提取态Cd含量减少了17.02%、20.20%、24.53%,可还原态Cd含量减少了8.9%、19.1%、38.2%,可氧化态Cd含量增加了44.83%、78.45%、100%,残渣态Cd含量增加了66.03%、71.43%、89.21%。同时,土壤pH与土壤中弱酸可提取态Cd含量呈显著负相关(P<0.01)。综上,核桃壳生物炭能够对Cd污染土壤起到钝化修复作用。Abstract: The effects of walnut shell biochar (BC400, BC500, BC600) on pH and Cd morphology distribution in artificial Cd-contaminated soil (20 mg/kg) were studied through laboratory simulation experiments, and possible repair mechanisms were investigated. The results showed that after 56 days of remediation, compared with the blank control group, with 10% dosage of walnut shell biochar BC400, BC500 and BC600, the soil pH increased by 1.07, 1.31 and 1.38, the content of extractable Cd decreased by 17.02%, 20.20% and 24.53%, the reducible Cd content decreased by 8.9%, 19.1% and 38.2%, the oxidizable Cd content increased by 44.83%, 78.45% and 100%, and the residual Cd content increased by 66.03%, 71.43%, 89.21%. At the same time, there was a significant negative correlation between soil pH and soil extractable Cd content (P<0.01). Walnut shell biochar was proved to have the performance in passivating and repairing Cd-contaminated soil.
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Key words:
- walnut shell biochar /
- soil heavy metals /
- Cd /
- repair
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