LIME COAGULATION-SUBMERGED EVAPORATION SYNERGISTIC TREATMENT FOR NANOFILTRATION MEMBRANE CONCENTRATE OF LANDFILL LEACHATE
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摘要: 为提高垃圾渗滤液膜浓缩液减量化水平,采用石灰混凝-浸没蒸发协同处理纳滤膜浓缩液,获得了处理过程中水质变化规律。结果表明:单独采用石灰混凝处理,在石灰投加量为2 g/L时,膜浓缩液混凝软化效果最佳;随着石灰投加量增加,此时,膜浓缩液pH=10.58,硬度去除率为29.1%,COD去除率为24.1%,NH3-N去除率为67.3%。。采用石灰混凝-浸没蒸发协同处理,石灰投加量为2 g/L、浓缩倍率为10时,蒸发残液软化效果进一步提升,较单独处理,硬度去除率由29.1%提升至65.9%,COD去除率由24.1%提升至41.2%,NH3-N去除率由67.3%提升至81.4%;K+浓度由样液中4300 mg/L提高到36210 mg/L、Na+浓度由5860 mg/L提高到48300 mg/L,为资源化利用提供了条件;冷凝液ρ(COD)由26.3 mg/L降低至16.3 mg/L,ρ(NH3-N)由2.0 mg/L降低至1.4 mg/L,出水可满足GB 16889—2008《生活垃圾填埋场污染控制标准》相关要求。Abstract: In order to improve quantitative reduction of the landfill leachate membrane concentrate, the nanofiltration membrane concentrate was treated by lime coagulation-submerged evaporation, and the change rule of water quality was obtained. The results showed that in the lime-coagulation treatment alone, the softening effect of membrane concentration was best when the dosage of lime was 2 g/L; with the increase of lime dosage, the pH of the membrane concentrate, and the removal rate of COD, NH3-N, and metal ions (Fe3+, Mg2+, Al3+, K+ and Na+) increased. In lime coagulation-immersion evaporation synergistic treatment, when the dosage of lime was 2 g/L and the concentration ratio was 10, compared to coagulation alone, the softening effect of evaporation residue liquid was further improved, with hardness removal rate increased from 29.1% to 65.9%, COD removal rate increased from 24.1% to 41.2%, NH3-N removal rate increased from 39% to 81.4%, and K+ and Na+ concentration increased from 4300,5860 mg/L to 36210, 48300 mg/L, respectively. That provided conducive condition for the latter resource utilization. COD concentration in the condensate decreased from 26.3 mg/L to 16.3 mg/L, and NH3-N decreased from 2.0 mg/L to 1.4 mg/L, complying with the relevant requirements of the Control Standard for Domestic Waste Landfill (GB 16889—2008).
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Key words:
- landfill leachate /
- nano filtration concentrate /
- lime /
- submerged evaporation /
- water quality
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