EFFECT OF WATER-TABLE FLUCTUATION ON PETROLEUM POLLUTANT MIGRATION AND LENS POSITION
-
摘要: 近年来石油类污染在土壤和地下水环境中日益严重,由于天然及人为因素导致的地下水水位波动会造成污染物的二次迁移,扩大污染范围,因此探究水位波动对污染物迁移的影响刻不容缓。以柴油为例,利用二维模拟槽模拟柴油在地下水水位波动带中的迁移情况,通过控制水位升降模拟地下水水位波动,研究柴油透镜体的位置、模拟槽内柴油-水-气体饱和度随水位波动的变化,分析地下水水位波动对石油类污染物在地下水非饱和带中迁移的影响。结果表明:当水位向下波动时,油相可驱替水向下迁移,透镜体位置下移,迁移的过程中部分油相被介质吸附形成残余相,导致残余相柴油的污染范围增大;而当水位向上波动时,水可驱替油相向上迁移,透镜体位置上移,迁移的过程中部分油相溶解,导致溶解相柴油的污染范围的增大。该研究可为实际污染场地的修复提供理论支撑。Abstract: In the past few years, the pollution of soil and groundwater by petroleum pollutants became increasingly serious.The fluctuation of groundwater level caused by natural and man-made factors will cause the secondary migration of pollutants and expand the pollution scale.Therefore,the remediation of petroleum pollutants in water-table fluctuation zone have to be settled urgently. In this study, picking diesel as a representative of petroleum pollutants, the migration and transformation of diesel in water-table zone was simulated in a two-dimension sand box. The main purpose of this study were to research the change of diesel lens position, diesel-water-gas saturation in a two-dimension sand box in difference water level variation mode, and to analyze the effect of water-table fluctuation on the transport behavior of petroleum pollutants in unsaturated zone of groundwater. The results showed that when the water level fluctuated downward, the oil phase could drive the water to migrate downward, and the lens position moved downward. During the migration process, part of the oil phase was adsorbed by the medium to form a residual phase, resulting in an increase in the pollution range of the residual phase diesel; when the water level fluctuated upward, the water could drive the oil phase to move upward, and the lens body position moved upward. During the migration, part of the oil phase dissolves, which led to an increase in the pollution range of the dissolved phase diesel.This research could provide theoretical support for the remediation of actual contaminated sites.
-
Key words:
- petroleum pollutants /
- water-table fluctuation /
- lens /
- unsaturated zone /
- transport behavior
-
张雷,张帝,谯兴国,等.石油类污染物在季节性冻土中迁移转化规律研究[J].环境保护科学,2019,45(3):106-109,121. 王贝贝,刘琦,张胜南,等.生物炭对土壤中释放的石油类污染物的吸附[J].石油学报(石油加工),2019,35(3):603-612. 张宏凯,左锐,王金生,等.加油站泄漏污染物的迁移分布规律[J].中国环境科学,2018,38(4):1532-1539. 苏丽娜,马晓利,陈平.含油污水灌区土壤污染特征研究[J].土壤通报,2018,49(2):478-485. CAMPO P, WANIUSIOW D, COSSEC B, et al. Toluene-induced hearing loss in phenobarbital treated rats[J]. Neurotoxicology and Teratology, 2008, 30(1):46-54. LI G, YU Q, MA W, et al. Laboratory testing on heat transfer of blocky frozen soils for backfilling of tower foundation along qinghai-tibet electric transmission line[C]//Proceedings of the 2012 Second International Conference on Electric Technology and Civil Engineering. IEEE Computer Society, 2012:1638-1642. LIU Z Y, WU H Y. Pore-scale modeling of immiscible two-phase flow in complex porous media[J]. Applied Thermal Engineering, 2016, 93:1394-1402. BLUNT M J, BIJELJIC B, DONG H, et al. Pore-scale imaging and modelling[J]. Advances in Water Resources, 2013, 51:197-216. SLEEP B E, SEHAYEK L, CHIEN C C. A modeling and experimental study of light nonaqueous phase liquid (LNAPL) accumulation in wells and LNAPL recovery from wells[J]. Water Resources Research, 2000, 36(12):3535-3545. VALVATNE P H, PIRI M, LOPEZ X, et al. Predictive pore-scale modeling of single and multiphase flow[M]//Upscaling Multiphase Flow in Porous Media. Springer, Dordrecht, 2005:23-41. 陶琴琴,刘峙嵘.轻非水相液体在土壤和地下水中迁移行为的探讨[J].广州化工,2010,38(5):204-206. LEE J Y, CHEON J Y, LEE K K, et al. Factors affecting the distribution of hydrocarbon contaminants and hydrogeochemical parameters in a shallow sand aquifer[J]. Journal of Contaminant Hydrology, 2001, 50(1/2):139-158. ROY J W, SMITH J E. Multiphase flow and transport caused by spontaneous gas phase growth in the presence of dense non-aqueous phase liquid[J]. Journal of Contaminant Hydrology, 2007, 89(3):251-269. 林广宇. 地下水位变动带石油烃污染物的迁移转化规律研究[D]. 长春:吉林大学, 2014. 杨明星. 石油有机污染组分在水位波动带中的分异演化机理研究[D]. 长春:吉林大学, 2014. KLAMMLER H, HATFIELD K, NEWMAN M A, et al. A new device for characterizing fracture networks and measuring groundwater and contaminant fluxes in fractured rock aquifers[J]. Water Resources Research, 2016, 52(7):5400-5420. 王丽. 轻非水相液体(LNAPL)污染土壤多相流实验研究[D].西安:长安大学,2009. 郑德凤,赵勇胜,王本德.轻非水相液体在地下环境中的运移特征与模拟预测研究[J].水科学进展,2002(3):321-325. KIM J, CORAPCIOGLU M Y. Modeling dissolution and volatilization of LNAPL sources migrating on the groundwater table[J]. Journal of Contaminant Hydrology, 2003, 65(1/2):137-158.
点击查看大图
计量
- 文章访问数: 129
- HTML全文浏览量: 13
- PDF下载量: 2
- 被引次数: 0