国内外铝灰资源化利用技术发展现状

邢修君; 吴跃东

doi:10.13205/j.hjgc.202103021

国内外铝灰资源化利用技术发展现状

doi: 10.13205/j.hjgc.202103021

邢修君¹,
吴跃东^2, ,

1. 中国冶金科工股份有限公司, 北京 100028;
2. 中冶建筑研究总院有限公司, 北京 100088

详细信息

作者简介:
邢修君,男,工程师。主要从事工程管理与科研工作。xingxiujun@mcc.com.cn

通讯作者:
吴跃东,男,博士,工程师。主要从事冶金固废资源化利用研究。wuyuedong2015@163.com

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- 被引次数: 0
出版历程
- 收稿日期: 2020-05-06
- 网络出版日期: 2021-07-19

REVIEW ON DEVELOPMENT ON THE UTILIZATION OF ALUMINUM DROSS

XING Xiu-jun¹,
WU Yue-dong^{2
, ,}

1. China Metallurgical Group Corporation Co., Ltd, Beijing 100028, China;
2. Central Research Institute of Building and Construction Co., Ltd, Beijing 100088, China

摘要

摘要: 2019年中国约有350万t的铝灰副产品产物，但铝灰利用低，大规模堆积，易引发严重的环境问题。针对铝灰资源化利用问题，对铝灰的来源、危害以及处理工艺进行了论述探讨。目前，一次铝灰的处理工艺主要有炒灰法、压榨回收法及球磨筛分法等，但存在装备化程度低，劳动强度大，处理过程环保问题突出等问题；二次铝灰可进行资源化利用作为制备脱硫剂、硫酸铝、聚合硫酸铝以及耐火材料等的原料，但这些综合资源化利用方法仍不够高效。因此，建议继续开发一次铝灰金属铝回收工艺，推广离心分离法和电化学法等环保工艺，改变现有工艺装备化程度低，工人作业条件差、劳动强度大等缺点，实现一次铝灰的清洁化生产；并结合调研本地产品市场行情，对二次铝灰中有价成分进行了功能性评估，制定合理且符合市场的综合利用方法。
- 铝灰 /
- 现状 /
- 资源利用
Abstract: In China, aluminum dross is produced with an output of about 3.5 million tons in 2019. Whereas, the resource utilization rate is in a low level, which results in a serious environmental problem. Facing the situation of resource utilization, the sources of aluminum dross, dangers and treatments are discussed in this paper in detail. Nowadays, the treatment methods of aluminum dross include stir-fry method, press method and ball mill method, but these methods have some disadvantages, such as low level of equipment, high labor intensity and poor working condition. The secondary aluminum dross can be used as the raw materials of the preparation of desulfurizer, aluminum sulfate, refractory, etc., but these resource utilization methods are not effective. It is necessary to develop a new and effective method to realize the harmless treatment and resource utilization of aluminum dross. To change the situation and realize clean production, a new method should be developed to treat primary aluminum dross or promote eco-friendly technologies such as centrifuging and electrochemical methods. Then, considering the production market, the valuable composition in the secondary aluminum dross should be evaluated, and then a reasonable comprehensive utilization method should be developed.
- aluminum dross /
- situation /
- resource utilization

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参考文献(25)

[1]	贾成厂. 金属:地壳与人体中的金属[J]. 金属世界, 2018(2):22-26.
[2]	GOPIENKO V G, KISELEV V P, ZOBNINA N S. Methods of manufacture of aluminum powders and their of application[J]. Soviet Powder Metallurgy & Metal Ceramics, 1984, 23(12):926-930.
[3]	李家镜. 利用铝灰制备Sialon材料的研究[D]. 上海:上海交通大学, 2012.
[4]	BATEMAN W, GUESR G, EVANS R. Decoating of aluminum products and the environment[J]. Light Metal, 1999, 57:1099-1106.
[5]	PAWLEK R. Secondary aluminium industry annual review[J]. Light Metal Age, 2001, 59(8):16-19.
[6]	KEVORKIJAN V. The quality of aluminum dross particles and cost-effective reinforcement for structural aluminum-based composites[J]. Composites Science and Technology, 1999, 59(11):1945-1751.
[7]	周伟. 含氟铝灰制备微晶玻璃及物相转移特性研究[D]. 北京:北方工业大学, 2019.
[8]	SHINAZTO M C, HYPOLITO R. Solid waste from aluminum recycling process:characterization and reuse of it seconomically valuable constituents[J]. Waste Management & Research, 2005, 25(1):37-46.
[9]	倪红军, 陈祥, 吕帅帅, 等. 铝渣合成无机材料的研究现状及进展[J]. 现代化工, 2015, 35(11):19-22.
[10]	张宁燕, 宁平, 谢天鉴, 等. 铝灰有价组分回收及综合利用研究进展[J]. 硅酸盐通报, 2017, 36(6):1951-1956.
[11]	MANFREDI O, WUTH W, BOHLINGER I. Characterizing the physical and chemical properties of aluminum dross[J]. JOM, 1997, 49(11):48-51.
[12]	FUKUMOTO S, HOOKABE T, TSUBAKINO H. Hydrolysis behavior of aluminum nitride in various solutions[J]. Journal of Materials Science, 2000, 35(11):2743-2748.
[13]	郭冉, 刘雄章, 李青达. 铝灰高值化回收利用技术现状[J]. 无机盐工业, 2017, 49(11):11-15.
[14]	TSAKIRIDIS P E. Aluminium salt slag characterization and utilization:a review[J]. Journal of Hazardous Materials, 2012, 217-218:1-10.
[15]	HWANG J Y, HUANG X, XU Z. Recovery of metals from aluminium dross and salt cake[J]. Journal of Minerals and Materials Characterization and Engineering, 2006, 5(1):47-62.
[16]	高飞. 铝渣处理设备国产化技术应用[J]. 有色冶金节能, 2013(4):44-47.
[17]	杜淄川, 李会泉, 包炜军, 等. 高铝粉煤灰碱溶脱硅过程反应机理[J]. 过程工程学报, 2011, 11(3):442-447.
[18]	钟华萍, 李坊平. 从热铝灰中回收铝[J]. 铝加工, 2001, 24(1):54-55.
[19]	周扬民. 铝灰的无害化处理及综合利用研究[D]. 云南:昆明理工大学, 2014.
[20]	YANG S F, WANG T M, SHIE Z Y J, et al. Fine Al₂O₃ powder produced by radio frequency plasma from aluminum dross[J]. IEEE Transactions on Plasma Science, 2014, 42(12):3751-3755.
[21]	YUASA G, YAJIMA T, UKAI A, et al. Refining Practice and Application of the Ladle Furnace (LF) Process in Japan[J]. ISIJ International, 1984, 24(4):412-418.
[22]	蔡艳秀. 铝灰的回收利用现状及发展趋势[J]. 资源再生, 2007(10):27-29.
[23]	宋明. 二次铝灰回收氧化铝的工艺研究[D]. 山东:青岛科技大学, 2018.
[24]	MAILAR G, SUJAY R N, SREEDHARA B M, et al. Investigation of concrete produced using recycled aluminium dross for hot weather concreting conditions[J]. Resource-Efficient Technologies, 2016, 2(2):68-80.
[25]	LI A P, ZHANG H J, YANG H M. Evaluation of aluminum dross as raw material for high-alumina refractory[J]. Ceramics International, 2014, 40:12585-12590.