从含铟废料中回收In的研究进展

冷国琴; 陶天一; 杨依帆; 陈博利; 孙峙; 黄朝晖

doi:10.13205/j.hjgc.202105020

从含铟废料中回收In的研究进展

doi: 10.13205/j.hjgc.202105020

1. 中国科学院过程工程研究所环境技术与工程研究部绿色过程与工程重点实验室北京市过程污染控制工程技术研究中心, 北京 100190;
2. 中国地质大学(北京) 材料科学与工程学院北京非金属矿物与固体废物材料利用重点实验室矿物材料国家重点实验室, 北京 100083

基金项目:

国家科技部重点专项（2017YFB0403300/2017YFB0403305）；中国科学院过程工程研究所南京绿色制造产业创新研究院的重点研发项目（E0010715）。

详细信息

作者简介:
冷国琴(1994-),女,博士研究生在读,主要研究方向为材料科学与工程。lengguoqin@126.com

通讯作者:
陶天一(1990-),女,助理研究员,主要研究方向为固废回收预处理与资源化再利用。tianyitao1990@163.com

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出版历程
- 收稿日期: 2020-07-29
- 网络出版日期: 2022-01-17

INDIUM RECOVERY PROCESSES DEVELOPMENT FROM VARIOUS In-CONTAINING WASTE

1. Beijing Engineering Research Center of Process Pollution Control, Key Laboratory of Green Process and Engineering, Division of Environment Technology and Engineering, Institute of Process Engineering, CAS, Beijing 100190, China;
2. National Laboratory of Mineral Materials, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, School of Materials Science and Technology, China University of Geosciences(Beijing), Beijing 100083, China

摘要

摘要: 铟是一种在军事、国防、能源、电子工业、医疗等领域应用广泛的稀散金属，在地壳中的储量仅为黄金储量的约1/6。随着科学技术的发展，铟的应用领域扩大，需求量逐年增长，铟的稀有性和重要性促进了从电子废弃物中回收二次铟研究的发展。从二次铟回收工艺研究的进展出发，对不同种类含铟废料中回收二次铟的工艺原理与流程进行综述，并对不同回收工艺的优势以及技术发展瓶颈进行了分析，展望了二次铟资源循环利用的发展方向。
- 二次铟 /
- 含铟废料 /
- 回收 /
- 研究进展
Abstract: Indium is a rare and dispersed metal, which has been widely used in military, national defense, energy, electronic industry, medical and other fields. The reserved content of indium on earth is one sixth of that of gold. With the development of science and technology, the application field of indium is expanding and the demand of indium is increasing. The rarity and importance of indium promoted the development of research on the recovery of secondary-indium from e-waste. This paper reviewed the processes and principles of secondary-indium recovery from different kinds of indium-containing e-wastes, and the technological development bottlenecks and prospects of different recovery procedures were also proposed.
- secondary-indium /
- indium-containing waste /
- recovery /
- research progress

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参考文献(57)

[1]	唐武军. 浅论中国铟工业的现状及其发展思路[J]. 中国金属通报,2008(25):9-11.
[2]	AM, 2016c. The Use and Application of Indium. Available at. Asian Metal. http://baike. asianmetal.cn/metal/in/application.shtml.
[3]	AM, 2016a. The Distribution and Production of Indium Resources. Available at. Asian Metal. http://baike.asianmetal.cn/metal/in/resources&production.shtml.
[4]	俞小花, 谢刚. 有色冶金过程中铟的回收[J]. 有色金属(冶炼部分),2006(1):37-39.
[5]	伍赠玲. 铟的资源、应用与分离回收技术研究进展[J]. 铜业工程, 2011(1):25-30.
[6]	周智华, 莫红兵, 徐国荣,等. 稀散金属铟富集与回收技术的研究进展[J]. 有色金属,2005(1):73-78,82.
[7]	ZHANG K H, LI B, WU Y F, et al. Recycling of indium from waste LCD:a promising non-crushing leaching with the aid of ultrasonic wave[J]. Waste Management,2017,64:236-243.
[8]	FERELLA F, BELARDI G, MARSILII A, et al. Separation and recovery of glass, plastic and indium from spent LCD panels[J]. Waste Management,2017,60:569-581.
[9]	冯同春, 杨斌, 刘大春,等. 铟的生产技术进展及产业现状[J]. 冶金丛刊,2007(2):42-46.
[10]	GUPTA B, MUDHAR N, SINGH I. Separations and recovery of indium and gallium using bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272)[J]. Separation & Purification Technology,2007,57(2):294-303.
[11]	LIN S, MAO J, CHEN W, et al. Indium in mainland China:Insights into use, trade, and efficiency from the substance flow analysis[J]. Resources, Conservation & Recycling,2019,149:312-321.
[12]	WANG H G, GU Y F, WU Y F, et al. An evaluation of the potential yield of indium recycled from end-of-life LCDs:a case study in China[J]. Waste Management,2015,46:480-487.
[13]	CHOI C H, CAO J J, ZHAO F. System dynamics modeling of indium material flows under wide deployment of clean energy technologies. Resources Conservation and Recycling. 2016,114:59-71.
[14]	侬健桃, 黄瀚. ITO废靶回收再生技术[J]. 中国资源综合利用,2005(2):17-19.
[15]	阮久莉, 郭玉文, 乔琦. 废液晶显示器资源化技术进展及问题与对策[J]. 环境科学与技术,2016,39(1):38-43.
[16]	王瑞雪, 马恩, 王艳萍, 等. 废弃液晶面板中铟回收的研究现状及展望[J]. 有色金属(冶炼部分),2019(9):38-44.
[17]	LEE C H, JEONG M K, KILICASLAN M F, et al. Recovery of indium from used LCD panel by a time efficient and environmentally sound method assisted HEBM[J]. Waste Management,2013,33(3):730-734.
[18]	DENBAARS S P, FEEZELL D, KELCHNEr K, et al. Development of gallium-nitride-based light-emitting diodes (LEDs) and laser diodes for energy-efficient lighting and displays[J]. Acta Materialia,2013,61(3):945-951.
[19]	ZHAN L, WANG Z Y, ZHANG Y L, et al. Recycling of metals (Ga, In, As and Ag from waste light-emitting diodes in sub/supercritical ethanol[J]. Resources, Conservation and Recycling,2020,155:104695.
[20]	马保中, 王成彦, 陈永强, 等. 从铜铟镓硒太阳能薄膜电池废料中回收铜铟镓硒的方法[P]:中国, CN108359802A. 2018-08-03.
[21]	刘军飞, 高永涛, 王冠, 等. 一种铜铟镓硒物料的回收方法[P]:中国, CN106987720A. 2017-07-28.
[22]	马保中, 王成彦, 陈永强, 等. 从铜铟镓硒废电池芯片中回收有价金属的方法[P]:中国, CN108425017A. 2018-08-21.
[23]	刘家祥, 甘勇, 张艳. 利用ITO废靶材回收金属铟[J]. 稀有金属,2004,28(5):947-950.
[24]	LØVIK A N, RESTREPO E, MVLLER D B. The global anthropogenic gallium system:determinants of demand, supply and efficiency improvements[J]. Environmental Science & Technology,2015,49(9):5704-5712.
[25]	卢兰兰, 毕冬勤, 刘壮, 等. 光伏太阳能电池生产过程中的污染问题[J]. 中国科学(化学),2013,43(6):687-703.
[26]	WONG C S C, DUZGOREN-AYDIN N S, AYDIN A, et al. Sources and trends of environmental mercury emissions in Asia[J]. Science of the Total Environment,2006,368(2/3):649-662.
[27]	吴鸿铖. 废弃液晶面板中铟材料的微波氯化回收及玻璃基板资源化再利用研究[D]. 上海:上海第二工业大学,2019.
[28]	ZHAN L, XIA F F, XIA Y H, et al. Recycle Gallium and Arsenic from GaAs-Based E-Wastes via Pyrolysis-Vacuum Metallurgy Separation:theory and Feasibility[J]. ACS Sustainable Chemistry & Engineering,2018,6(1):1336-1342.
[29]	ZHAN L, XIA F F, YE Q Y, et al. Novel recycle technology for recovering rare metals (Ga, In) from waste light-emitting diodes[J]. Journal of Hazardous Materials,2015,299(15):388-394.
[30]	BOSSCHE A V D, VEREYCKEN W, HOOGERSTRAETE T V, et al. Recovery of gallium, indium, and arsenic from semiconductors using tribromide ionic liquids[J]. ACS Sustainable Chemistry & Engineering,2019,7(17):14451-14459.
[31]	谭明亮, 李胜春, 潘勇进, 等.铜铟镓硒物料回收方法[P]:中国, CN108728655A. 2018-11-02.
[32]	FANG S, TAO T Y, CAO H B, et al. Selective recovery of gallium (indium) from metal organic chemical vapor deposition dust:a sustainable process[J]. ACS Sustainable Chemistry & Engineering,2019,7(10):9646-9654.
[33]	马保中, 王成彦, 陈永强, 等. 从CIGS太阳能薄膜电池腔室废料中回收有价金属的方法[P]:中国, CN108425016A. 2018-08-21.
[34]	LI Y H, LIU Z H, LI Q H, et al. Recovery of indium from used indium-tin oxide (ITO) targets[J]. Hydrometallurgy,2011, 105(3/4):207-212.
[35]	GABRIEL A P, KASPER A C, VEIT H M, et al. Acid leaching of indium from the screens of obsolete LCD monitors[J]. Journal of Environmental Chemical Engineering,2020,8(3):103758.
[36]	CAO Y, LI F, LI G M, et al. Leaching and purification of indium from waste liquid crystal display panel after hydrothermal pretreatment:optimum conditions determination and kinetic analysis[J]. Waste Management,2020,102:635-644.
[37]	SONG Q M, ZHANG L G, XU Z M. Indium recovery from In-Sn-Cu-Al mixed system of waste liquid crystal display panels via acid leaching and two-step electrodeposition[J]. Journal of hazardous materials,2020,381:120973.
[38]	陆静蓉. 废液晶显示器中铟的回收及深加工[D]. 常州:江苏理工学院,2019.
[39]	DHIMAN S, GUPTA B. Cyphos IL 104 assisted extraction of indium and recycling of indium, tin and zinc from discarded LCD screen[J]. Separation and Purification Technology,2020,237:116407.
[40]	李严辉, 张欣, 杨永峰, 等. ITO废靶中铟的回收[J]. 中国稀土学报,2002,20(1):256-258.
[41]	ASSEFI M, MAROUFI S, NEKOUEI R K, et al. Selective recovery of indium from scrap LCD panels using macroporous resins[J]. Journal of Cleaner Production,2018,180(10):814-822.
[42]	ITOH S, MARUYAMA K. Recoveries of metallic indium and tin from ITO by means of pyrometallurgy[J]. High Temperature Materials and Processes,2011,30(4/5):317-322.
[43]	HE Y X, MA E, XU Z M. Recycling indium from waste liquid crystal display panel by vacuum carbon-reduction[J]. Journal of Hazardous Materials,2014,268(15):185-190.
[44]	WANG R X, HOU Y Q, XU Z M. In-situ reaction for recycling indium from waste liquid crystal display panels by vaccum reduction with pyrolytic carbon as reductant[J]. Waste Management,2019,85:538-547.
[45]	刘欢, 华中胜, 何几文, 等. 废弃氧化铟锡中铟的回收技术综述[J]. 材料导报,2018,32(11):1916-1923.
[46]	MA E, XU Z M. Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels[J]. Journal of Hazardous Materials,2013,263:610-617.
[47]	PARK K S, SATO W, GRAUSE G, et al. Recovery of indium from In₂O₃ and liquid crystal display powder via a chloride volatilization process using polyvinyl chloride[J]. Thermochimica Acta,2009,493(1):105-108.
[48]	李胜春, 王为振, 潘勇进, 等. 从CIGS废料中综合回收硒铜铟镓[J]. 矿冶,2019,28(4):131-134.
[49]	谭明亮, 李胜春, 潘勇进,等. 一种铜铟镓硒废料的回收方法[P]:中国, CN108754435A. 2018-11-06.
[50]	于丽敏, 蒋文全, 傅钟臻,等. 铟电解精炼提纯方法的研究[J]. 材料导报, 2013, 27(4):16-19.
[51]	CIRO E, DELL'ERA A, PASQUALI M, et al. Indium electrowinning study from sulfate aqueous solution using different metal cathodes[J]. Journal of Environmental Chemical Engineering,2020,8(2):103688.
[52]	张丁川, 邓勇, 袁聪聪, 等. 粗铟真空蒸馏多级冷凝法提纯的实验研究[J]. 真空科学与技术学报,2017,37(1):94-99.
[53]	李贻成, 刘越, 章长生, 等. 区域熔炼法制备高纯铟的研究[J]. 矿冶工程, 2014, 34(2):104.
[54]	ZHOU Z H, RUAN J M, MO H B. Preparation of 6N high-purity indium by method of physical-chemical purification and electrorefining[J]. Journal of Materials Science,2005,40(24):6529-6533.
[55]	李情. 区域熔炼提纯铟及仿真模拟[D]. 桂林:桂林理工大学,2018.
[56]	卢兴伟, 彭巨擘, 伍美珍, 等. 电解精炼法制备高纯铟[J]. 矿冶, 2018, 27(6):59-62.
[57]	JIANG W L, DENG Y, XU B Q, et al. Application of vacuum distillation in refining crude indium[J].Rare Metals,2013,32(6):627-631.