CSCD来源期刊
中国科技核心期刊
RCCSE中国核心学术期刊
JST China 收录期刊

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

挥发性有机物(VOCs)吸附材料的研究进展

刘帅 张亚妮 薛明 崔翔宇 李兵 李俊华

刘帅, 张亚妮, 薛明, 崔翔宇, 李兵, 李俊华. 挥发性有机物(VOCs)吸附材料的研究进展[J]. 环境工程, 2021, 39(6): 79-89. doi: 10.13205/j.hjgc.202106013
引用本文: 刘帅, 张亚妮, 薛明, 崔翔宇, 李兵, 李俊华. 挥发性有机物(VOCs)吸附材料的研究进展[J]. 环境工程, 2021, 39(6): 79-89. doi: 10.13205/j.hjgc.202106013
LIU Shuai, ZHANG Ya-ni, XUE Ming, CUI Xiang-yu, LI Bing, LI Jun-hua. RESEARCH PROGRESS ON ADSORPTION MATERIALS FOR VOLATILE ORGANIC COMPOUNDS (VOCs)[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(6): 79-89. doi: 10.13205/j.hjgc.202106013
Citation: LIU Shuai, ZHANG Ya-ni, XUE Ming, CUI Xiang-yu, LI Bing, LI Jun-hua. RESEARCH PROGRESS ON ADSORPTION MATERIALS FOR VOLATILE ORGANIC COMPOUNDS (VOCs)[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(6): 79-89. doi: 10.13205/j.hjgc.202106013

挥发性有机物(VOCs)吸附材料的研究进展

doi: 10.13205/j.hjgc.202106013
基金项目: 

国家科技重大专项课题(2016ZX05040-004);石油石化污染物控制与处理国家重点实验室基金(20182002196)

详细信息
    作者简介:

    刘帅(1993-),男,博士,主要研究方向为挥发性有机物吸附材料。18810305857@163.com

    通讯作者:

    李俊华(1970-),男,教授,博士生导师,主要研究方向为大气污染控制技术。lijunhua@tsinghua.edu.cn

RESEARCH PROGRESS ON ADSORPTION MATERIALS FOR VOLATILE ORGANIC COMPOUNDS (VOCs)

  • 摘要: 目前,我国面临严重的挥发性有机物(VOCs)污染问题。吸附法是研究与应用最为广泛的VOCs治理技术。主要介绍了吸附净化VOCs原理和几种常见的VOCs吸附材料,包括活性炭、新型多孔炭材料、沸石分子筛、黏土基吸附剂、金属有机框架和介孔硅。详述了各吸附材料的VOCs吸附能力和优缺点,判断了其应用价值,并指出了为提升大规模工业化应用潜力,后续研发的VOCs吸附材料应满足高吸附量、高疏水性、高热稳定性和再生能力强4个特征。
  • [1] PARK J H,GOLDSTEIN A H,TIMKOVSKY J,et al.Active atmosphere-ecosystem exchange of the vast majority of detected volatile organic compounds[J].Science,2013,341(6146):643-647.
    [2] MADRONICH S.Ethanol and ozone[J].Nature Geoscience,2014,7(6):395-397.
    [3] NIU H,MO Z W,SHAO M,et al.Screening the emission sources of volatile organic compounds (VOCs) in China by multi-effects evaluation[J].Frontiers of Environmental Science&Engineering,2016,10(5):25-35.
    [4] TROSTL J,CHUANG W K,GORDON H,et al.The role of lowvolatility organic compounds in initial particle growth in the atmosphere[J].Nature,2016,533(7604):527-531.
    [5] BAROJA O,RODRIGUEZ E,DE BALUGERA Z G,et al.Speciation of volatile aromatic and chlorinated hydrocarbons in an urban atmosphere using TCT-GC/MS[J].Journal of Environmental Science and Health Part a-Toxic/Hazardous Substances&Environmental Engineering,2005,40(2):343-367.
    [6] HUANG R J,ZHANG Y L,BOZZETTI C,et al.High secondary aerosol contribution to particulate pollution during haze events in China[J].Nature,2014,514(7521):218-222.
    [7] MA P K,ZHAO Y L,ROBINSON A L,et al.Evaluating the impact of new observational constraints on P-S/IVOC emissions,multi-generation oxidation,and chamber wall losses on SOAmodeling for Los Angeles,CA[J].Atmospheric Chemistry and Physics,2017,17(15):9237-9259.
    [8] MCDONALD B C,DE GOUW J A,GILMAN J B,et al.Volatile chemical products emerging as largest petrochemical source of urban organic emissions[J].Science,2018,359(6377):760-764.
    [9] 梁小明.我国人为源挥发性有机物反应性排放清单与臭氧控制对策研究[D].广州:华南理工大学,2017.
    [10] CHIANG Y C,CHAING P C,HUANG C P.Effects of pore structure and temperature on VOC adsorption on activated carbon[J].Carbon,2001,39(4):523-534.
    [11] 田静,史兆臣,万亚萌,等.挥发性有机物组合末端治理技术的研究进展[J].应用化工,2019,48(6):1433-1439.
    [12] SHIM W G,LEE J W,RHEE H K,et al.Adsorption dynamics for the capillary condensation of trichloroethylene vapor on mesoporous material[J].Korean Journal of Chemical Engineering,2004,21(2):469-476.
    [13] HU Q,LI J J,HAO Z P,et al.Dynamic adsorption of volatile organic compounds on organofunctionalized SBA-15 materials[J].Chemical Engineering Journal,2009,149(1/2/3):281-288.
    [14] 郑亮巍.改性13X沸石蜂窝转轮对甲苯的吸附性能研究[D].杭州:浙江工业大学,2013.
    [15] 张秉建.烟气中二噁英类物质脱除的实验研究[D].保定:华北电力大学,2009.
    [16] YE J J,YE F,DAI W,et al.Formaldehyde capture with fingercitron-residue-based activated carbon[J].Separation Science and Technology,2015,50(2):253-259.
    [17] RONG H Q,LIU Z Y,WU Q L,et al.Formaldehyde removal by Rayon-based activated carbon fibers modified by P-aminobenzoic acid[J].Cellulose,2009,17(1):205-214.
    [18] WEN Q B,LI C T,CAI Z H,et al.Study on activated carbon derived from sewage sludge for adsorption of gaseous formaldehyde[J].Bioresource Technology,2011,102(2):942-947.
    [19] LI L Q,SONG J F,YAO X L,et al.Adsorption of volatile organic compounds on three activated carbon samples:effect of pore structure[J].Journal of Central South University,2012,19(12):3530-3539.
    [20] DELAGE F,PRÉP,LE CLOIREC P.Mass transfer and warming during adsorption of high concentrations of VOCs on an activated carbon bed:experimental and theoretical analysis[J].Environmental Science&Technology,2000,34(22):4816-4821.
    [21] GREVILLOT G,YU F D,LUO L A.Adsorption isotherms of VOCs onto an activated carbon monolith:experimental measurement and correlation with different models[J].Journal of Chemical and Engineering Data:the ACS Journal for Data,2002,47(3):467-473.
    [22] WANG C M,CHUNG T W,HUANG C M,et al.Adsorption equilibria of acetate compounds on activated carbon,silica gel,and13X zeolite[J].Journal of Chemical Engineering Data,2005,50(3):527-531.
    [23] OH K J,PARK D W,KIM S S,et al.Breakthrough data analysis of adsorption of volatile organic compounds on granular activated carbon[J].Korean Journal of Chemical Engineering,2010,27(2):632-638.
    [24] ROMERO-ANAYA A J,LILLO-RODENAS M A,LINARES-SOLANO A.Activation of a spherical carbon for toluene adsorption at low concentration[J].Carbon,2014,77:616-626.
    [25] PEI J,ZHANG J S.Determination of adsorption isotherm and diffusion coefficient of toluene on activated carbon at low concentrations[J].Building and Environment,2012,48:66-76.
    [26] YU F D,LUO L A,GREVILLOT G.Adsorption isotherms of VOCs onto an activated carbon monolith:experimental measurement and correlation with different models[J].Journal of Chemical Engineering Data,2004,47(3):467-473.
    [27] LILLO-RODENAS M A,CAZORLA-AMOROS D,LINARES-SOLANO A.Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations[J].Carbon,2005,43(8):1758-1767.
    [28] WIBOWO N,SETYADHI L,WIBOWO D,et al.Adsorption of benzene and toluene from aqueous solutions onto activated carbon and its acid and heat treated forms:influence of surface chemistry on adsorption[J].Journal of Hazardous Materials,2007,146(1/2):237-242.
    [29] LILLO-RODENAS M A,CAZORLA-AMOROS D,LINARES-SOLANO A.Benzene and toluene adsorption at low concentration on activated carbon fibres[J].Adsorption-Journal of the International Adsorption Society,2010,17(3):473-481.
    [30] MARCO-LOZAR J P,KUNOWSKY M,SUAREZ-GARCIA F,et al.Activated carbon monoliths for gas storage at room temperature[J].Energy&Environmental Science,2012,5(12):9833-9842.
    [31] MOHAMMED J,NASRI N S,AHMAD ZAINI M A,et al.Adsorption of benzene and toluene onto KOH activated coconut shell based carbon treated with NH3[J].International Biodeterioration&Biodegradation,2015,102:245-255.
    [32] LIU H B,YANG B,XUE N D.Enhanced adsorption of benzene vapor on granular activated carbon under humid conditions due to shifts in hydrophobicity and total micropore volume[J].Journal of Hazardous Materials,2016,318:425-432.
    [33] MADANI S H,HU C,SILVESTRE-ALBERO A,et al.Pore size distributions derived from adsorption isotherms,immersion calorimetry,and isosteric heats:a comparative study[J].Carbon,2016,96:1106-1113.
    [34] ZHAO X Y,LI X,ZHU T L,et al.Adsorption behavior of chloroform,carbon disulfide,and acetone on coconut shell-derived carbon:experimental investigation,simulation,and model study[J].Environmental Science and Pollution Research,2018,25(31):31219-31229.
    [35] FOSTER K L,FUERMAN R G,ECONOMY J,et al.Adsorption characteristics of trace volatile organic-compounds in gas streams onto activated carbon-fibers[J].Chemistry of Materials,1992,4(5):1068-1073.
    [36] LE CLOIREC P.Adsorption onto activated carbon fiber cloth and electrothermal desorption of volatile organic compound (VOCs):a specific review[J].Chinese Journal of Chemical Engineering,2012,20(3):461-468.
    [37] LIN C L,CHENG Y H,LIU Z S,et al.Adsorption and oxidation of high concentration toluene with activated carbon fibers[J].Journal of Porous Materials,2012,20(4):883-889.
    [38] ZHANG X Y,GAO B,CREAMER A E,et al.Adsorption of VOCs onto engineered carbon materials:a review[J].Journal of Hazardous Materials,2017,338:102-123.
    [39] BAI Y,HUANG Z H,KANG F Y.Synthesis of reduced graphene oxide/phenolic resin-based carbon composite ultrafine fibers and their adsorption performance for volatile organic compounds and water[J].Journal of Materials Chemistry A,2013,1(33):9536-9543.
    [40] SHEN Y,FANG Q L,CHEN B L.Environmental applications of three-dimensional graphene-based macrostructures:adsorption,transformation,and detection[J].Environmental Science Technology,2015,49(1):67-84.
    [41] GAO H C,SUN Y M,ZHOU J J,et al.Mussel-inspired synthesis of polydopamine-functionalized graphene hydrogel as reusable adsorbents for water purification[J].ACS Applied Materials Interfaces,2013,5(2):425-432.
    [42] MAUTER M S,ELIMELECH M.Environmental applications of carbon-based nanomaterials[J].Environmental Science Technology,2008,42(16):5843-5859.
    [43] TAO Y,KONG D B,ZHANG C,et al.Monolithic carbons with spheroidal and hierarchical pores produced by the linkage of functionalized graphene sheets[J].Carbon,2014,69:169-177.
    [44] ZHANG L,SHI G.Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability[J].Journal of Physical Chemistry C,2011,115(34):17206-17212.
    [45] HE Y Q,ZHANG N N,WU F,et al.Graphene oxide foams and their excellent adsorption ability for acetone gas[J].Materials Research Bulletin,2013,48(9):3553-3558.
    [46] WANG J H,WANG W Q,HAO Z P,et al.A superhydrophobic hyper-cross-linked polymer synthesized at room temperature used as an efficient adsorbent for volatile organic compounds[J].RSCAdvances,2016,6(99):97048-97054.
    [47] WANG J H,WANG G,WANG W Q,et al.Hydrophobic conjugated microporous polymer as a novel adsorbent for removal of volatile organic compounds[J].Journal of Materials Chemistry A,2014,2(34):14028-14037.
    [48] WANG W Q,WANG J,CHEN J G,et al.Synthesis of novel hyper-cross-linked polymers as adsorbent for removing organic pollutants from humid streams[J].Chemical Engineering Journal,2015,281:34-41.
    [49] TOZAWA T,JONES J T,SWAMY S I,et al.Porous organic cages[J].Nature Materials,2009,8(12):973-978.
    [50] COTE A P,BENIN A I,OCKWIG N W,et al.Porous,crystalline,covalent organic frameworks[J].Science,2005,310(5751):1166-1170.
    [51] EL-KADERI H M,HUNT J R,MENDOZA-CORTES J L,et al.Designed synthesis of 3D covalent organic frameworks[J].Science,2007,316(5822):268-272.
    [52] HYLA A S,FANG H,BOULFELFEL S E,et al.Significant temperature dependence of the isosteric heats of adsorption of gases in zeolites demonstrated by experiments and molecular simulations[J].Journal of Physical Chemistry C,2019,123(33):20405-20412.
    [53] KP VEERAPANDIAN S,DE GEYTER N,GIRAUDON J M,et al.The use of zeolites for VOCs abatement by combining nonthermal plasma,adsorption,and/or catalysis:a review[J].Catalysts,2019,9(1):98.
    [54] KIM J J,LIM S J,AHN H,et al.Adsorption equilibria and kinetics of propane and propylene on zeolite 13X pellets[J].Microporous and Mesoporous Materials,2019,274:286-298.
    [55] JIANG N,SHANG R,HEIJMAN S G,et al.High-silica zeolites for adsorption of organic micro-pollutants in water treatment:a review[J].Water Research,2018,144:145-161.
    [56] KAUSAR A,IQBAL M,JAVED A,et al.Dyes adsorption using clay and modified clay:a review[J].Journal of Molecular Liquids,2018,256:395-407.
    [57] UDDIN M K.A review on the adsorption of heavy metals by clay minerals,with special focus on the past decade[J].Chemical Engineering Journal,2017,308:438-462.
    [58] ALSHAMERI A,HE H,ZHU J,et al.Adsorption of ammonium by different natural clay minerals:characterization,kinetics and adsorption isotherms[J].Applied Clay Science,2018,159:83-93.
    [59] AGUIAR J,CECILIA J,TAVARES P,et al.Adsorption study of reactive dyes onto porous clay heterostructures[J].Applied Clay Science,2017,135:35-44.
    [60] BROSILLON S,MANERO M H,FOUSSARD J N.Mass transfer in VOC adsorption on zeolite:experimental and theoretical breakthrough curves[J].Environmental Science Technology,2001,35(17):3571-3575.
    [61] KIM K J,AHN H G.The effect of pore structure of zeolite on the adsorption of VOCs and their desorption properties by microwave heating[J].Microporous and Mesoporous Materials,2012,152:78-83.
    [62] PIRES J,CARVALHO A,DE CARVALHO M B.Adsorption of volatile organic compounds in Y zeolites and pillared clays[J].Microporous and Mesoporous Materials,2001,43(3):277-287.
    [63] AUERBACH S M,CARRADO K A,DUTTA P K.Handbook of zeolite science and technology[M].New York:CRC Press,2003.
    [64] FLANIGEN E M,BENNETT J,GROSE R,et al.Silicalite,a new hydrophobic crystalline silica molecular sieve[J].Nature,1978,271(5645):512-516.
    [65] RUNGSIRISAKUN R,NANOK T,PROBST M,et al.Adsorption and diffusion of benzene in the nanoporous catalysts FAU,ZSM-5and MCM-22:a molecular dynamics study[J].Journal of Molecular Graphics&Modelling,2006,24(5):373-382.
    [66] CUI X L,CHEN K J,XING H B,et al.Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene[J].Science,2016,353(6295):141-144.
    [67] PARK K S,NI Z,COTE A P,et al.Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J].Proceedings of the National Academy of Sciences,2006,103(27):10186-10191.
    [68] CADIAU A,ADIL K,BHATT P,et al.A metal-organic framework-based splitter for separating propylene from propane[J].Science,2016,353(6295):137-140.
    [69] KISHIDA K,OKUMURA Y,WATANABE Y,et al.Recognition of 1,3-butadiene by a porous coordination polymer[J].Angewandte Chemie International Edition,2016,55(44):13784-13788.
    [70] ADIL K,BELMABKHOUT Y,PILLAI R S,et al.Gas/vapour separation using ultra-microporous metal-organic frameworks:insights into the structure/separation relationship[J].Chemical Society Reviews,2017,46(11):3402-3430.
    [71] LIAO P Q,HUANG N Y,ZHANG W X,et al.Controlling guest conformation for efficient purification of butadiene[J].Science,2017,356(6343):1193-1196.
    [72] LAI Z,BONILLA G,DIAZ I,et al.Microstructural optimization of a zeolite membrane for organic vapor separation[J].Science,2003,300(5618):456-460.
    [73] BLOCH E D,QUEEN W L,KRISHNA R,et al.Hydrocarbon separations in a metal-organic framework with open iron (Ⅱ)coordination sites[J].Science,2012,335(6076):1606-1610.
    [74] CADIAU A,ADIL K,BHATT P M,et al.A metal-organic framework-based splitter for separating propylene from propane[J].Science,2016,353(6295):137-140.
    [75] ZHANG C,LIVELY R P,ZHANG K,et al.Unexpected molecular sieving properties of zeolitic imidazolate framework-8[J].Journal of Physical Chemistry Letters,2012,3(16):2130-2134.
    [76] LIU D F,MA X L,XI H X,et al.Gas transport properties and propylene/propane separation characteristics of ZIF-8 membranes[J].Journal of Membrane Science,2014,451:85-93.
    [77] ZHAO X S,LU G Q.Modification of MCM-41 by surface silylation with trimethylchlorosilane and adsorption study[J].Journal of Physical Chemistry B,1998,102(9):1556-1561.
    [78] WANG X,GUO Q J,KONG T T.Tetraethylenepentaminemodified MCM-41/silica gel with hierarchical mesoporous structure for CO2capture[J].Chemical Engineering Journal,2015,273:472-480.
    [79] LIU Y S,LI Z Y,YANG X,et al.Performance of mesoporous silicas (MCM-41 and SBA-15) and carbon (CMK-3) in the removal of gas-phase naphthalene:adsorption capacity,rate and regenerability[J].RSC Advances,2016,6(25):21193-21203.
    [80] HU X J,QIAO S Z,ZHAO X S,et al.Adsorption study of benzene in ink-bottle-like MCM-41[J].Industrial Engineering Chemistry Research,2001,40(3):862-867.
    [81] SERNA-GUERRERO R,SAYARI A.Applications of poreexpanded mesoporous silica.7.Adsorption of volatile organic compounds[J].Environmental Science Technology,2007,41(13):4761-4766.
    [82] ZHAO X S,LU G Q,HU X.Organophilicity of MCM-41adsorbents studied by adsorption and temperature-programmed desorption[J].Colloids Surfaces A:Physicochemical Engineering Aspects,2001,179(2/3):261-269.
    [83] LIU X W,ZHOU L,FU X,et al.Adsorption and regeneration study of the mesoporous adsorbent SBA-15 adapted to the capture/separation of CO2and CH4[J].Chemical Engineering Science,2007,62(4):1101-1110.
    [84] DOU B J,HU Q,LI J J,et al.Adsorption performance of VOCs in ordered mesoporous silicas with different pore structures and surface chemistry[J].Journal of Hazardous Materials,2011,186(2/3):1615-1624.
    [85] ZHOU L Y,FAN J,CUI G K,et al.Highly efficient and reversible CO2adsorption by amine-grafted platelet SBA-15 with expanded pore diameters and short mesochannels[J].Green Chemistry,2014,16(8):4009-4016.
    [86] MIRJI S,HALLIGUDI S,MATHEW N,et al.Adsorption of methanol on mesoporous SBA-15[J].Materials Letters,2007,61(1):88-92.
    [87] MIRJI S,HALLIGUDI S,MATHEW N,et al.Adsorption of methanol on Si (100)/Si O2and mesoporous SBA-15[J].Colloids Surfaces A:Physicochemical Engineering Aspects,2006,287(1/2/3):51-58.
    [88] LIU Y S,LI Z Y,YANG X,et al.Performance of mesoporous silicas (MCM-41 and SBA-15) and carbon (CMK-3) in the removal of gas-phase naphthalene:adsorption capacity,rate and regenerability[J].RSC Advances,2016,6(25):21193-21203.
    [89] JANUS R,NATKAN'SKI P,WACH A,et al.Thermal transformation of polyacrylonitrile deposited on SBA-15 type silica:effect on adsorption capacity of methyl-ethyl ketone vapor[J].Journal of Thermal Analysis Calorimetry,2012,110(1):119-125.
    [90] KORANYI T I,PFEIFER E,MIHALY J,et al.Infrared spectroscopic investigation of CO adsorption on SBA-15-and KIT-6-supported nickel phosphide hydrotreating catalysts[J].Journal of Physical Chemistry A,2008,112(23):5126-5130.
    [91] LIU Y M,SHI J J,CHEN J,et al.Dynamic performance of CO2adsorption with tetraethylenepentamine-loaded KIT-6[J].Microporous and Mesoporous Materials,2010,134(1/2/3):16-21.
    [92] KISHOR R,GHOSHAL A K.APTES grafted ordered mesoporous silica KIT-6 for CO2adsorption[J].Chemical Engineering Journal,2015,262:882-890.
    [93] BENSACIA N,FECHETE I,MOULAY S,et al.Kinetic and equilibrium studies of lead (Ⅱ) adsorption from aqueous media by KIT-6 mesoporous silica functionalized with-COOH[J].Comptes Rendus Chimie,2014,17(7/8):869-880.
    [94] ZHU L,SHI X C,SONG L J,et al.Mesoporous silica (KIT-6)derivatized with hydroxyquinoline functionalities as a selective adsorbent of uranium (Ⅵ)[J].Journal of Radioanalytical and Nuclear Chemistry,2016,308(2):381-392.
    [95] QIN Y,WANG Y,WANG H Q,et al.Effect of morphology and pore structure of SBA-15 on toluene dynamic adsorption/desorption performance[J].Procedia Environmental Science,2013,18:366-371.
    [96] KOSUGE K,KUBO S,KIKUKAWA N,et al.Effect of pore structure in mesoporous silicas on VOC dynamic adsorption/desorption performance[J].Langmuir,2007,23(6):3095-3102.
    [97] HOFFMANN F,CORNELIUS M,MORELL J,et al.Silica-based mesoporous organic-inorganic hybrid materials[J].Angewandte Chemie-International Edition,2006,45(20):3216-3251.
    [98] BURKETT S L,SIMS S D,MANN S.Synthesis of hybrid inorganic-organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors[J].Chemical Communications,1996,11:1367-1368.
    [99] MACQUARRIE D J.Direct preparation of organically modified MCM-type materials.Preparation and characterisation of aminopropyl-MCM and 2-cyanoethyl-MCM[J].Chemical Communications,1996,16:1961-1962.
    [100] LIM M H,BLANFORD C F,STEIN A.Synthesis and characterization of a reactive vinyl-functionalized MCM-41:probing the internal pore structure by a bromination reaction[J].Journal of the American Chemical Society,1997,119(17):4090-4091.
    [101] MERCIER L,PINNAVAIA T J.Direct synthesis of hybrid organicinorganic nanoporous silica by a neutral amine assembly route:structure-function control by stoichiometric incorporation of organosiloxane molecules[J].Chemistry of Materials,2000,12(1):188-196.
    [102] CHE S,GARCIA-BENNETT A E,YOKOI T,et al.A novel anionic surfactant templating route for synthesizing mesoporous silica with unique structure[J].Nature Materials,2003,2(12):801-805.
    [103] HUH S,WIENCH J W,YOO J C,et al.Organic functionalization and morphology control of mesoporous silicas via a co-condensation synthesis method[J].Chemistry of Materials,2003,15(22):4247-4256.
    [104] LIU N G,ASSINK R A,SMARSLY B,et al.Synthesis and characterization of highly ordered functional mesoporous silica thin films with positively chargeable-NH2groups[J].Chemical Communications,2003,(10):1146-1147.
    [105] YOKOI T,YOSHITAKE H,TATSUMI T.Synthesis of anionicsurfactant-templated mesoporous silica using organoalkoxysilanecontaining amino groups[J].Chemistry of Materials,2003,15(24):4536-4538.
    [106] CAGNOL F,GROSSO D,SANCHEZ C.A general one-pot process leading to highly functionalised ordered mesoporous silica films[J].Chemical Communications,2004,15:1742-1743.
    [107] FOWLER C E,BURKETT S L,MANN S.Synthesis and characterization of ordered organo-silica-surfactant mesophases withfunctionalized MCM-41-type architecture[J].Chemical Communications,1997,18:1769-1770.
    [108] HALL S,FOWLER C.Template-directed synthesis of bifunctionalized organo-MCM-41 and phenyl-MCM-48 silica mesophases[J].Chemical Communications,1999,(2):201-202.
    [109] LIM M H,STEIN A.Comparative studies of grafting and direct syntheses of inorganic-organic hybrid mesoporous materials[J].Chemistry of Materials,1999,11:3285-3295.
    [110] WANG Y,ZIBROWIUS B,YANG C M,et al.Synthesis and characterization of large-pore vinyl-functionalized mesoporous silica SBA-15[J].Chemical Communications,2004,1:46-47.
    [111] BAMBROUGH C M,SLADE R C,WILLIAMS R T.Synthesis of a large pore phenyl-modified mesoporous silica and its characterization by nitrogen and benzene sorption[J].Journal of Materials Chemistry,1998,8(3):569-571.
    [112] SLADE R C,BAMBROUGH C M,WILLIAMS R T.An incoherent inelastic neutron scattering investigation of the vibrational spectrum of phenyl-modified (-C6H5) mesoporous silica and its variations in the presence of sorbed benzene (C6H6) and of sorbed deuteriobenzene (C6D6)[J].Physical Chemistry Chemical Physics,2002,4(21):5394-5399.
    [113] LIU S,CHEN J J,PENG Y,et al.Studies on toluene adsorption performance and hydrophobic property in phenyl functionalized KIT-6[J].Chemical Engineering Journal,2018,334:191-197.
    [114] LIU A M,HIDAJAT K,KAWI S,et al.A new class of hybrid mesoporous materials with functionalized organic monolayers for selective adsorption of heavy metal ions[J].Chemical Communications,2000,13:1145-1146.
    [115] LEI C H,SHIN Y,LIU J,et al.Entrapping enzyme in a functionalized nanoporous support[J].Journal of the American Chemical Society,2002,124(38):11242-11243.
    [116] MATSUMOTO A,TSUTSUMI K,SCHUMACHER K,et al.Surface functionalization and stabilization of mesoporous silica spheres by silanization and their adsorption characteristics[J].Langmuir,2002,18(10):4014-4019.
    [117] HO K Y,MCKAY G,YEUNG K L.Selective adsorbents from ordered mesoporous silica[J].Langmuir,2003,19(7):3019-3024.
    [118] HUANG H,YANG R,CHINN D,et al.Aminopropylfunctionalised silicas as high capacity carbon dioxide adsorbents[J].Industrial Engineering Chemistry Research,2003,42(12):2427-2433.
    [119] WALCARIUS A,ETIENNE M,LEBEAU B.Rate of access to the binding sites in organically modified silicates.2.Ordered mesoporous silicas grafted with amine or thiol groups[J].Chemistry of Materials,2003,15(11):2161-2173.
    [120] YOKOI T,YOSHITAKE H,TATSUMI T.Synthesis of aminofunctionalized MCM-41 via direct co-condensation and postsynthesis grafting methods using mono-,di-and tri-aminoorganoalkoxysilanes[J].Journal of Materials Chemistry,2004,14(6):951-957.
    [121] KHATRI R A,CHUANG S S,SOONG Y,et al.Carbon dioxide capture by diamine-grafted SBA-15:a combined Fourier transform infrared and mass spectrometry study[J].Industrial Engineering Chemistry Research,2005,44(10):3702-3708.
    [122] ZHENG F,TRAN D,BUSCHE B,et al.Carbon dioxide capture via mesoporous silica particles[J].Industrial Engineering Chemistry Research,2005,44(9):3099-3105.
    [123] MERCIER L,PINNAVAIA T J.Heavy metal ion adsorbents formed by the grafting of a thiol functionality to mesoporous silica molecular sieves:factors affecting Hg (Ⅱ) uptake[J].Environmental Science Technology,1998,32(18):2749-2754.
    [124] ANTOCHSHUK V,JARONIEC M.1-Allyl-3-propylthiourea modified mesoporous silica for mercury removal[J].Chemical Communications,2002(3):258-259.
    [125] ARMATAS G,SALMAS C,LOULOUDI M,et al.Relationships among pore size,connectivity,dimensionality of capillary condensation,and pore structure tortuosity of functionalized mesoporous silica[J].Langmuir,2003,19(8):3128-3136.
    [126] KANG T,PARK Y,CHOI K,et al.Ordered mesoporous silica(SBA-15) derivatized with imidazole-containing functionalities as a selective adsorbent of precious metal ions[J].Journal of Materials Chemistry,2004,14(6):1043-1049.
    [127] KANG T,PARK Y,YI J.Highly selective adsorption of Pt2+ and Pd2+using thiol-functionalized mesoporous silica[J].Industrial Engineering Chemistry Research,2004,43(6):1478-1484.
    [128] RODRÍGUEZ-LÓPEZ G,MARCOS M D,MARTÍNEZ-MÁÑEZR,et al.Efficient boron removal by using mesoporous matrices grafted with saccharides[J].Chemical Communications,2004,19:2198-2199.
    [129] ANWANDER R,NAGL I,WIDENMEYER M,et al.Surface characterization and functionalization of MCM-41 silicas via silazane silylation[J].Journal of Physical Chemistry B,2000,104(15):3532-3544.
    [130] INUMARU K,INOUE Y,KAKII S,et al.Molecular selective adsorption of dilute alkylphenols and alkylanilines from water by alkyl-grafted MCM-41:tunability of the cooperative organicinorganic function in the nanostructure[J].Physical Chemistry Chemical Physics,2004,6(12):3133-3139.
    [131] INUMARU K,MURASHIMA M,KASAHARA T,et al.Enhanced photocatalytic decomposition of 4-nonylphenol by surfaceorganografted Ti O2:a combination of molecular selective adsorption and photocatalysis[J].Applied Catalysis B:Environmental,2004,52(4):275-280.
    [132] MARTIN T,GALARNEAU A,DI RENZO F,et al.Great improvement of chromatographic performance using MCM-41spheres as stationary phase in HPLC[J].Chemistry of Materials,2004,16(9):1725-1731.
    [133] YANG H Q,ZHANG G Y,HONG X L,et al.Silylation of mesoporous silica MCM-41 with the mixture of Cl (CH2)3Si Cl3and CH3Si Cl3:combination of adjustable grafting density and improved hydrothermal stability[J].Microporous and Mesoporous Materials,2004,68(1/2/3):119-125.
    [134] LIU S,PENG Y,CHEN J,et al.Engineering surface functional groups on mesoporous silica:towards a humidity-resistant hydrophobic adsorbent[J].Journal of Materials Chemistry A,2018.
    [135] EGAN P J,MULLIN M.Recent improvement and projected worsening of weather in the United States[J].Nature,2016,532(7599):357.
    [136] LIU S,PENG Y,YAN T,et al.modified silica adsorbents for toluene adsorption under dry and humid conditions:impacts of pore size and surface chemistry[J].Langmuir,2019,35(27):8927-8934.
    [137] TANG Y,LANDSKRON K.CO2-sorption properties of organosilicas with bridging amine functionalities inside the framework[J].Journal of Physical Chemistry C,2010,114(6):2494-2498.
    [138] LIN D R,HU L J,YOU H,et al.Initial screening studies on potential of high phenolic-linked plant clonal systems for nitrate removal in cold latitudes[J].Journal of Soils and Sediments,2010,10(5):923-932.
    [139] LIN D R,HU L J,YOU H,et al.Synthesis and characterization of a nanostructured photoluminescent silsesquioxane containing urea and dodecyl groups that can be patterned on carbon films[J].European Polymer Journal,2011,47(8):1526-1533.
    [140] LIN D R,HU L J,LI Z,et al.Influence of alkylene-bridging group length on mesostructure and porosity in cubic (Pm3n)periodic mesoporous bridged polysilsesquioxanes[J].Journal of Porous Materials,2014,21(1):39-44.
    [141] LIN D R,ZHAO Q,HU L J,et al.Synthesis and characterization of cubic mesoporous bridged polysilsesquioxane for removing organic pollutants from water[J].Chemosphere,2014,103:188-196.
  • 加载中
计量
  • 文章访问数:  1313
  • HTML全文浏览量:  149
  • PDF下载量:  45
  • 被引次数: 0
出版历程
  • 收稿日期:  2020-11-05
  • 网络出版日期:  2022-01-18

目录

    /

    返回文章
    返回