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新型纳滤膜在水处理与水回用中的研究进展

杨哲 戴若彬 文越 王立 王志伟 汤初阳

杨哲, 戴若彬, 文越, 王立, 王志伟, 汤初阳. 新型纳滤膜在水处理与水回用中的研究进展[J]. 环境工程, 2021, 39(7): 1-12. doi: 10.13205/j.hjgc.202107001
引用本文: 杨哲, 戴若彬, 文越, 王立, 王志伟, 汤初阳. 新型纳滤膜在水处理与水回用中的研究进展[J]. 环境工程, 2021, 39(7): 1-12. doi: 10.13205/j.hjgc.202107001
YANG Zhe, DAI Ruo-bin, WEN Yue, WANG Li, WANG Zhi-wei, TANG Chu-yang. RECENT PROGRESS OF NANOFILTRATION MEMBRANE IN WATER TREATMENT AND WATER REUSE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 1-12. doi: 10.13205/j.hjgc.202107001
Citation: YANG Zhe, DAI Ruo-bin, WEN Yue, WANG Li, WANG Zhi-wei, TANG Chu-yang. RECENT PROGRESS OF NANOFILTRATION MEMBRANE IN WATER TREATMENT AND WATER REUSE[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(7): 1-12. doi: 10.13205/j.hjgc.202107001

新型纳滤膜在水处理与水回用中的研究进展

doi: 10.13205/j.hjgc.202107001
基金项目: 

国家重点研发计划项目(2019YFC0408200);香港资研局优配研究金(17204220)

详细信息
    作者简介:

    杨哲(1991-),男,博士后,主要研究方向为膜过滤和膜分离。zheyang@connect.hku.hk

    通讯作者:

    王志伟(1980-),男,教授,主要研究方向为膜法污水处理与资源化技术等。zwwang@tongji.edu.cn

    汤初阳(1976-),男,教授,主要研究方向为膜分离技术、海水淡化、水回用、清洁能源等。tangc@hku.hk

RECENT PROGRESS OF NANOFILTRATION MEMBRANE IN WATER TREATMENT AND WATER REUSE

  • 摘要: 近年来,纳滤膜(NF)以其较高水渗透性能、良好水/盐选择性和相较于反渗透膜(RO)低工作压力等优势被广泛应用于水处理和水回用中。然而传统的商品NF的分离性能具有局限性,例如对人体有益的矿物质去除率过高、对污染物去除率偏低,而且渗透性能-选择性能的制衡等问题严重制约了NF的发展及潜在的应用。详细介绍了NF膜在水处理和水回用中的应用及NF结构优化和改性的最新进展;回顾了通过对NF膜除盐层的孔隙率、亲水性、表面官能团及表面带电性等改性方式来提高NF的渗透性、选择性、抗污染、抗菌和耐氯能力等取得的研究成果;最后展望了新型NF膜在水处理和水回用领域的发展。
  • [1] ELIMELECH M,PHILLIP W A.The future of seawater desalination:energy,technology,and the environment[J].Science,2011,333(6043):712-717.
    [2] TANG C Y,YANG Z,GUO H,et al.Potable water reuse through advanced membrane technology[J].Environmental Science & Technology,2018,52(18):10215-10223.
    [3] DAI R,GUO H,TANG C Y,et al.Hydrophilic selective nanochannels created by metal organic frameworks in nanofiltration membranes enhance rejection of hydrophobic endocrine-disrupting compounds[J].Environmental Science & Technology,2019,53(23):13776-13783.
    [4] YANG Z,GUO H,TANG C Y.The upper bound of thin-film composite (TFC) polyamide membranes for desalination[J].Journal of Membrane Science,2019,590:117297.
    [5] 曲久辉.生命之源[J].求是,2012(8):39-40.
    [6] DAI R B,HAN H Y,WANG T L,et al.Fouling is the beginning:upcycling biopolymer-fouled substrates for fabricating high-Permeance thin-film composite polyamide membranes[J].Green Chemistry,2021,23:1013-1025.
    [7] YANG Z,ZHOU Z W,GUO H,et al.Tannic acid/Fe nanoscaffold for interfacial polymerization:toward enhanced nanofiltration performance[J].Environmental Science & Technology,2018,52(16):9341-9349.
    [8] YANG Z,WU Y,GUO H,et al.A novel thin-film nano-templated composite membrane with in situ silver nanoparticles loading:separation performance enhancement and implications[J].Journal of Membrane Science,2017,544:351-358.
    [9] GUO H,DENG Y,TAO Z J,et al.Does hydrophilic polydopamine coating enhance membrane rejection of hydrophobic endocrine-disrupting compounds?[J].Environmental Science & Technology Letters,2016,3(9):332-338.
    [10] 李昆,王健行,魏源送.纳滤在水处理与回用中的应用现状与展望[J].环境科学学报,2016,36(8):2714-2729.
    [11] YANG Z,GUO H,YAO Z K,et al.Hydrophilic silver nanoparticles induce selective nanochannels in thin film nanocomposite polyamide membranes[J].Environmental Science & Technology,2019,53(9):5301-5308.
    [12] STOLOV M,FREGER V.Degradation of polyamide membranes exposed to chlorine:an impedance spectroscopy study[J].Environmental Science & Technology,2019,53(5):2618-2625.
    [13] YANG Z,MA X H,TANG C Y.Recent development of novel membranes for desalination[J].Desalination,2018,434:37-59.
    [14] YANG Z,SUN P F,LI X,et al.A critical review on thin-film nanocomposite membranes with interlayered structure:mechanisms,recent developments,and environmental applications[J].Environmental Science & Technology,2020,54(24):15563-15583.
    [15] DAI R B,LI J Y,WANG Z W.Constructing interlayer to tailor structure and performance of thin-film composite polyamide membranes:a review[J].Advances in Colloid and Interface Science,2020,282:102204.
    [16] DAI R B,WANG X,TANG C Y,et al.Dually charged mof-based thin-film nanocomposite nanofiltration membrane for enhanced removal of charged pharmaceutically active compounds[J].Environmental Science & Technology,2020,54(12):7619-7628.
    [17] CADOTTE J,KING R,MAJERLE R,et al.Interfacial synthesis in the preparation of reverse osmosis membranes[J].Journal of Macromolecular Science-Chemistry,1981,15(5):727-755.
    [18] 时雅滨,张学彬,田明,等.纳滤膜的制备及其应用现状[J].化工时刊,2018,32(10):35-38.
    [19] 王祯宜.薄膜复合纳滤膜结构设计及脱盐性能研究[D].合肥:中国科学技术大学,2020.
    [20] 田家宇,常海霖,高珊珊,等.基于界面聚合技术的复合纳滤膜研究进展[J].净水技术,2020,39(10):86-93

    ,180.
    [21] RAMON G Z,WONG M C,HOEK E M.Transport through composite membrane,part 1:is there an optimal support membrane?[J].Journal of Membrane Science,2012,415:298-305.
    [22] 栾仁杰,马骁轩,刘爱菊,等.高效纳滤膜的制备研究进展[J].山东理工大学学报(自然科学版),2020,34(3):17-22.
    [23] 李新冬,代武川,袁佳彬,等.纳滤膜分离技术处理饮用水研究进展[J].应用化工,2018,47(8):1767-1771.
    [24] 刘四华.聚哌嗪酰胺纳滤膜微结构原位调控及氯化机理研究[D].天津:天津工业大学,2020.
    [25] ZAIDI S J,FADHILLAH F,KHAN Z,et al.Salt and water transport in reverse osmosis thin film composite seawater desalination membranes[J].Desalination,2015,368:202-213.
    [26] MOHAMMAD A W,TEOW Y H,ANG W L,et al.Nanofiltration membranes review:recent advances and future prospects[J].Desalination,2015,356:226-254.
    [27] DEEN W M.Hindered transport of large molecules in liquid-filled pores[J].AIChE Journal,1987,33(9):1409-1425.
    [28] TSURU T,NAKAO S I,KIMURA S.Calculation of ion rejection by extended Nernst-Planck equation with charged reverse osmosis membranes for single and mixed electrolyte solutions[J].Journal of Chemical Engineering of Japan,1991,24(4):511-517.
    [29] YAROSHCHUK A E.Rejection mechanisms of NF membranes[J].Membrane Technology,1998,1998(100):9-12.
    [30] BOWEN W R,WELFOOT J S.Modelling the performance of membrane nanofiltration-critical assessment and model development[J].Chemical Engineering Science,2002,57(7):1121-1137.
    [31] 于水利.基于纳滤膜分离的健康饮用水处理工艺[J].给水排水,2019,45(4):12-14

    ,23.
    [32] 张正磊,张俸志,周伟伟,等.纳滤工艺深度净化微污染水源水厂出水中试研究[J].中国给水排水,2019,35(15):37-42.
    [33] KHANZADA N K,FARID M U,KHARRAZ J A,et al.Removal of organic micropollutants using advanced membrane-based water and wastewater treatment:a review[J].Journal of Membrane Science,2020,598:117672.
    [34] LICONA K,GEAQUINTO L D O,NICOLINI J,et al.Assessing potential of nanofiltration and reverse osmosis for removal of toxic pharmaceuticals from water[J].Journal of Water Process Engineering,2018,25:195-204.
    [35] GUO H,DENG Y,YAO Z K,et al.A highly selective surface coating for enhanced membrane rejection of endocrine disrupting compounds:mechanistic insights and implications[J].Water Research,2017,121:197-203.
    [36] GUO H,PENG L E,YAO Z K,et al.Non-polyamide based nanofiltration membranes using green metal-organic coordination complexes:implications for the removal of trace organic contaminants[J].Environmental Science & Technology,2019,53(5):2688-2694.
    [37] LIU C,SHI L,WANG R.Crosslinked layer-by-layer polyelectrolyte nanofiltration hollow fiber membrane for low-pressure water softening with the presence of SO24- in feed water[J].Journal of Membrane Science,2015,486:169-176.
    [38] KOSUTIC K,DOLAR D,ASPERGER D,et al.Removal of antibiotics from a model wastewater by RO/NF membranes[J].Separation and Purification Technology,2007,53(3):244-249.
    [39] FUJIOKA T,NGHIEM L D,KHAN S J,et al.Effects of feed solution characteristics on the rejection of N-nitrosamines by reverse osmosis membranes[J].Journal of Membrane Science,2012,409/410:66-74.
    [40] YOON Y,WESTERHOFF P,SNYDER S A,et al.Removal of endocrine disrupting compounds and pharmaceuticals by nanofiltration and ultrafiltration membranes[J].Desalination,2007,202(1/2/3):16-23.
    [41] YANG L Y,ZHOU J,SHE Q H,et al.Role of calcium ions on the removal of haloacetic acids from swimming pool water by nanofiltration:mechanisms and implications[J].Water Research,2017,110:332-341.
    [42] COMERTON A M,ANDREWS R C,BAGLEY D M,et al.The rejection of endocrine disrupting and pharmaceutically active compounds by NF and RO membranes as a function of compound and water matrix properties[J].Journal of Membrane Science,2008,313(1/2):323-335.
    [43] HASSAN A M,AL-SOFI M A K,AL-AMODI A S,et al.A nanofiltration (NF) membrane pretratment of SWRO feed and MSF make-up[C]//IDA Conference,1997.
    [44] 周栋,傅寅翼,朱丽静,等.纳滤预处理反渗透海水淡化研究进展[J].膜科学与技术,2015,35(3):106-112.
    [45] 周栋,傅寅翼,薛立新,等.采用高效纳滤-低压反渗透集成膜工艺的海水淡化研究[J].膜科学与技术,2016,36(3):62-69.
    [46] QIN J J,KEKRE K A,TAO G,et al.New option of MBR-RO process for production of NEWater from domestic sewage[J].Journal of Membrane Science,2006,272(1/2):70-77.
    [47] CÔTÉ P,SIVERNS S,MONTI S.Comparison of membrane-based solutions for water reclamation and desalination[J].Desalination,2005,182(1/2/3):251-257.
    [48] 薛涛,张朋川,张彩云,等.水资源全回收的MBR-NF新水源工艺中试研究[J].中国给水排水,2018,34(9):11-14.
    [49] 俞开昌.MBR-NF双膜法高品质再生水制备技术与工程应用[D].北京:清华大学,2017.
    [50] 张芸,王晓静,代文臣,等.组合膜分离技术资源化处理印染废水工艺的研究[J].水资源与水工程学报,2015,26(4):29-34.
    [51] 刘威.混凝-纳滤组合工艺处理印染整理废水的研究[D].北京:中国科学院大学(中国科学院过程工程研究所),2018.
    [52] LI K,WANG J X,LIU J B,et al.Advanced treatment of municipal wastewater by nanofiltration:operational optimization and membrane fouling analysis[J].Journal of Environmental Sciences,2016,43:106-117.
    [53] CINPERI N C,OZTURK E,YIGIT N O,et al.Treatment of woolen textile wastewater using membrane bioreactor,nanofiltration and reverse osmosis for reuse in production processes[J].Journal of Cleaner Production,2019,223:837-848.
    [54] 靳云辉,秦川,郝静,等.中温厌氧-MBR-NF/RO工艺处理垃圾渗滤液设计[J].给水排水,2018,44(9):46-48.
    [55] 金正鑫,林振琳,黄功洛,等.垃圾渗滤液MBR+NF浓缩液资源化技术研究进展[J].能源与环境,2018(3):11-13.
    [56] 艾恒雨,孟棒棒,李娜,等.我国垃圾渗滤液膜浓缩液处理现状与污染控制建议[J].环境工程技术学报,2016,6(6):553-558.
    [57] 赵庆.两级A/O-MBR+NF/RO处理垃圾渗滤液[J].能源研究与管理,2020(2):32-34,41.
    [58] BOO C,WANG Y,ZUCKER I,et al.High performance nanofiltration membrane for effective removal of perfluoroalkyl substances at high water recovery[J].Environmental Science & Technology,2018,52(13):7279-7288.
    [59] BI F,ZHAO H,ZHANG L,et al.Discussion on calculation of maximum water recovery in nanofiltration system[J].Desalination,2014,332(1):142-146.
    [60] 谢锦灯,李晨冉.垃圾渗滤液MBR+NF浓缩液全量处理技术应用研究[J].能源与环境,2020(4):74-76.
    [61] 杨姝君,张辰,贺骏,等.垃圾渗滤液"纳滤+纳滤浓缩液3级减量"技术的工程应用[J].环境工程,2020,38(6):81-87.
    [62] CHEN Z W,LUO J Q,CHEN X R,et al.Fully recycling dairy wastewater by an integrated isoelectric precipitation-nanofiltration-anaerobic fermentation process[J].Chemical Engineering Journal,2016,283:476-485.
    [63] ANDRADE L,MENDES F,ESPINDOLA J,et al.Nanofiltration as tertiary treatment for the reuse of dairy wastewater treated by membrane bioreactor[J].Separation and Purification Technology,2014,126:21-29.
    [64] FERNÁNDEZ P,RIERA F A,ÁLVAREZ R,et al.Nanofiltration regeneration of contaminated single-phase detergents used in the dairy industry[J].Journal of Food Engineering,2010,97(3):319-328.
    [65] GALANAKIS C M,TORNBERG E,GEKAS V.Clarification of high-added value products from olive mill wastewater[J].Journal of Food Engineering,2010,99(2):190-197.
    [66] 王健行,郑靖凡,魏源送,等.纳滤膜深度处理抗生素制药废水的运行条件优化[J].中国给水排水,2018,34(19):85-89.
    [67] WANG J X,LI K,YU D W,et al.Comparison of NF membrane fouling and cleaning by two pretreatment strategies for the advanced treatment of antibiotic production wastewater[J].Water Science and Technology,2016,73(9):2260-2267.
    [68] WANG J X,LI K,WEI Y S,et al.Performance and fate of organics in a pilot MBR-NF for treating antibiotic production wastewater with recycling NF concentrate[J].Chemosphere,2015,121:92-100.
    [69] WANG J,LI K,YU D W,et al.Fouling characteristics and cleaning strategies of NF membranes for the advanced treatment of antibiotic production wastewater[J].Environmental Science and Pollution Research,2017,24(10):8967-8977.
    [70] LIU C H,LEE J,MA J,et al.Antifouling thin-film composite membranes by controlled architecture of zwitterionic polymer brush layer[J].Environmental Science & Technology,2017,51(4):2161-2169.
    [71] JEONG B H,HOEK E M,YAN Y,et al.Interfacial polymerization of thin film nanocomposites:a new concept for reverse osmosis membranes[J].Journal of Membrane Science,2007,294(1):1-7.
    [72] ZHOU Z Y,HU Y X,BOO C,et al.High-performance thin-film composite membrane with an ultrathin spray-coated carbon nanotube interlayer[J].Environmental Science & Technology Letters,2018,5(5):243-248.
    [73] KARAN S,JIANG Z,LIVINGSTON A G.Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation[J].Science,2015,348(6241):1347-1351.
    [74] JIANG Z,KARAN S,LIVINGSTON A G.Water transport through ultrathin polyamide nanofilms used for reverse osmosis[J].Advanced Materials,2018,30(15):1705973.
    [75] PARK S J,CHOI W,NAM S E,et al.Fabrication of polyamide thin film composite reverse osmosis membranes via support-free interfacial polymerization[J].Journal of Membrane Science,2017,526:52-59.
    [76] LI Y F,YOU X D,LI Y,et al.Graphene quantum dot engineered ultrathin loose polyamide nanofilms for high-performance nanofiltration[J].Journal of Materials Chemistry A,2020,45(8):23930-23938.
    [77] ZHU J Y,HOU J W,ZHANG R J,et al.Rapid water transport through controllable,ultrathin polyamide nanofilms for high-performance nanofiltration[J].Journal of Materials Chemistry A,2018,6(32):15701-15709.
    [78] PENG L E,YAO Z K,YANG Z,et al.Dissecting the role of substrate on the morphology and separation properties of thin film composite polyamide membranes:seeing is believing[J].Environmental Science & Technology,2020,54(11):6978-6986.
    [79] TRIVEDI J S,BHALANI D V,BHADU G R,et al.Multifunctional amines enable the formation of polyamide nanofilm composite ultrafiltration and nanofiltration membranes with modulated charge and performance[J].Journal of Materials Chemistry A,2018,6(41):20242-20253.
    [80] PARK S J,AHN W G,CHOI W,et al.A facile and scalable fabrication method for thin film composite reverse osmosis membranes:dual-layer slot coating[J].Journal of Materials Chemistry A,2017,5(14):6648-6655.
    [81] LEE J H,CHUNG J Y,CHAN E P,et al.Correlating chlorine-induced changes in mechanical properties to performance in polyamide-based thin film composite membranes[J].Journal of Membrane Science,2013,433:72-79.
    [82] WEI J,LIU X,QIU C Q,et al.Influence of monomer concentrations on the performance of polyamide-based thin film composite forward osmosis membranes[J].Journal of Membrane Science,2011,381(1/2):110-117.
    [83] CUI Y,LIU X Y,CHUNG T S.Ultrathin polyamide membranes fabricated from free-standing interfacial polymerization:synthesis,modifications,and post-treatment[J].Industrial & Engineering Chemistry Research,2017,56(2):513-523.
    [84] YANG Z,WANG F,GUO H,et al.Mechanistic insights into the role of polydopamine interlayer towards improved separation performance of polyamide nanofiltration membranes[J].Environmental Science & Technology,2020,54(18):11611-11621.
    [85] WEN Y,ZHANG X,LI X,et al.Metal-organic framework nanosheets for thin-film composite membranes with enhanced permeability and selectivity[J].ACS Applied Nano Materials,2020,3(9):9238-9248.
    [86] MA X H,YAO Z,YANG Z,et al.Nanofoaming of polyamide desalination membranes to tune permeability and selectivity[J].Environmental Science & Technology Letters,2018,5(2):123-130.
    [87] LU X,ARIAS Chavez L H,ROMERO-VARGAS Castrillón S,et al.Influence of active layer and support layer surface structures on organic fouling propensity of thin-film composite forward osmosis membranes[J].Environmental Science & Technology,2015,49(3):1436-1444.
    [88] GLATER J,ZACHARIAH M R.A mechanistic study of halogen interaction with polyamide reverse-osmosis membranes[M].Reverse Osmosis and Ultrafiltration.American Chemical Society,1985:345-358.
    [89] YAO Y,ZHANG P,JIANG C,et al.High performance polyester reverse osmosis desalination membrane with chlorine resistance[J].Nature Sustainability,2021,4:138-146.
    [90] ZHENG J F,LIU Y L,ZHU J Y,et al.Sugar-based membranes for nanofiltration[J].Journal of Membrane Science,2021,619:118786.
    [91] CHENG J,ZHANG Z Q,SHI W X,et al.A novel polyester composite nanofiltration membrane prepared by interfacial polymerization catalysed by 4-dimethylaminopyridine:enhanced the water permeability and anti-fouling ability[J].Polymer,2018,153:24-32.
    [92] JIN P R,ZHU J Y,YUAN S S,et al.Erythritol-based polyester loose nanofiltration membrane with fast water transport for efficient dye/salt separation[J].Chemical Engineering Journal,2020,406:126796.
    [93] XUE J,JIAO Z W,BI R,et al.Chlorine-resistant polyester thin film composite nanofiltration membranes prepared with Β-cyclodextrin[J].Journal of Membrane Science,2019,584:282-289.
    [94] GUI L,DONG J,FANG W,et al.Ultrafast ion sieving from honeycomb-like polyamide membranes formed using porous protein assemblies[J].Nano Letters,2020,20(8):5821-5829.
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