电驱动选择性膜分离技术研究进展

吴悠; 高舒嘉; 王天玉; 孙境求; 胡承志

doi:10.13205/j.hjgc.202107003

电驱动选择性膜分离技术研究进展

doi: 10.13205/j.hjgc.202107003

吴悠^1,2,
高舒嘉^1,3,
王天玉¹,
孙境求^1,2,
胡承志^1,2,3, ,

1. 中国科学院生态环境研究中心环境水质学国家重点实验室, 北京 100085;
2. 中国科学院大学, 北京 100049;
3. 桂林理工大学广西环境污染控制理论与技术重点实验室, 广西桂林 541004

基金项目:

国家自然科学基金（51978646）；中国科学院前沿科学研究项目（ZDBS-LY-DQC014）

详细信息

作者简介:
吴悠(1996-),男,硕士研究生,主要研究方向为电控膜分离技术。youwu_st@rcees.ac.cn

通讯作者:
胡承志(1976-),男,研究员,主要研究方向为水质净化和资源回收技术原理与应用。czhu@rcees.ac.cn

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出版历程
- 收稿日期: 2021-02-20
- 网络出版日期: 2022-01-18

RESEARCH PROGRESS OF ELECTRO-DRIVEN SELECTIVE MEMBRANE SEPARATION TECHNOLOGY

WU You^1,2,
GAO Shu-jia^1,3,
WANG Tian-yu¹,
SUN Jing-qiu^1,2,
HU Cheng-zhi^{1,2,3
, ,}

1. Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China;
3. Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin 541004, China

摘要

摘要: 电驱动膜分离将电化学与膜分离技术有机结合，通过调控电场或电极电位强化膜分离效果，有望突破膜污染、选择性分离弱及“trade-off”效应等技术瓶颈，是实现污/废水资源化的有效途径。提出电驱动膜分离概念，将电驱动膜分离分为电控膜分离、电渗析和膜电容去离子等技术类型，重点关注选择性膜分离回收废水中有价物质进而实现废水资源化。首先介绍了电驱动膜分离技术的基础研究进展，然后从膜/电极材料创新和工艺优化等角度对电控膜分离、电渗析和膜电容去离子的研究进展进行回顾和总结，最后从基础研究、材料创新和反应器开发3个方面对该技术未来的发展方向做出展望。
- 电驱动膜分离 /
- 电化学水处理 /
- 导电膜 /
- 膜污染 /
- 废水资源化
Abstract: The recovery of resource and energy in sewage and wastewater is an important part of building a low-carbon society. Electro-driven membrane separation is an effective way to realize the resource utilization of sewage and wastewater, which combines electrochemistry with membrane separation technology, and enhances membrane separation effect by adjusting electric field or electrode potential. And it is expected to break through the technical bottlenecks of membrane fouling, weak selective separation and trade-off effect. The concept of electro-driven membrane separation was proposed for the first time, and the electro-driven membrane separation was divided into electrical control membrane separation, electrodialysis and membrane capacitance deionization. This paper focused on the recovery of valuable substances in wastewater via selective membrane separation, so as to realize the recycling of wastewater. Firstly, the basic research progress of electro-driven membrane separation technology was introduced. Then, the research progress of electro-controlled membrane separation, electrodialysis and membrane capacitor deionization was reviewed and summarized from the perspectives of membrane/electrode material innovation and process optimization. Finally, the future development direction of the technology was prospected from three aspects:basic research, material innovation and reactor development.
- electro-driven membrane separation /
- electrochemical water treatment /
- conductive membrane /
- membrane fouling /
- wastewater utilization

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参考文献(65)

[1]	USEPA.Wastewater Management Fact Sheet:Energy Conservation[S].EPA 832-F-06-024,2006.
[2]	XIE M,SHON H K,GRAY S R,et al.Membrane-based processes for wastewater nutrient recovery:technology,challenges,and future direction[J].Water Research,2016,89:210-221.
[3]	MCCARTY P L,BAE J,KIM J.Domestic wastewater treatment as a net energy producer-can this be achieved?[J].Environmental Science & Technology,2011,45(17):7100-7106.
[4]	隋冰.膜分离技术在环境工程中的应用现状及发展前景[J].中国战略新兴产业,2018(12):161.
[5]	胡承志,刘会娟,曲久辉.电化学水处理技术研究进展[J].环境工程学报,2018,12(3):677-696.
[6]	TANG W W,HE D,ZHANG C Y,et al.Optimization of sulfate removal from brackish water by membrane capacitive deionization (MCDI)[J].Water Research,2017,121:302-310.
[7]	WEIDLICH C,MANGOLD K M.Electrochemically switchable polypyrrole coated membranes[J].Electrochimica Acta,2011,56(10):3481-3484.
[8]	DUDCHENKO A V,ROLF J,RUSSELL K,et al.Organic fouling inhibition on electrically conducting carbon nanotube-polyvinyl alcohol composite ultrafiltration membranes[J].Journal of Membrane Science,2014,468:1-10.
[9]	AL-AMSHAWEE S,YUNUS M Y B M,AZODDEIN A A M,et al.Electrodialysis desalination for water and wastewater:a review[J].Chemical Engineering Journal,2020,380:122231.
[10]	FOLARANMI G,BECHELANY M,SISTAT P,et al.Towards electrochemical water desalination techniques:a review on capacitive deionization,membrane capacitive deionization and flow capacitive deionization[J].Membranes (Basel),2020,10(5):96.
[11]	SUN P Z,ZHENG F,WANG K L,et al.Electro-and magneto-modulated ion transport through graphene oxide membranes[J].Scientific Reports,2014,4:6798.
[12]	LI D,JING W H,LI S Q,et al.Electric field-controlled ion transport in TiO₂ nanochannel[J].Acs Applied Materials & Interfaces,2015,7(21):11294-11300.
[13]	OJHA K,ARULMOZHI N,ARANZALES D,et al.Double layer of Pt(111)-aqueous electrolyte interface:potential of Zero charge and anomalous gouy-chapman screening[J].Angewandte Chemie-International Edition,2020,59(2):711-715.
[14]	CHENG C,JIANG G P,SIMON G P,et al.Low-voltage electrostatic modulation of ion diffusion through layered graphene-based nanoporous membranes[J].Nature Nanotechnology,2018,13(8):685-690.
[15]	DONNAN F G.The Theory of Membrane Equilibria[J].Chemical Reviews,1924,1(1):73-90.
[16]	PETROPOULOS J H,TSIMBOUKIS D G,KOUZELI K.Non-equipotential volume membrane models-relation between the glueckauf and equipotential surface models[J].Journal of Membrane Science,1983,16:379-389.
[17]	KAMCEV J,PAUL D R,FREEMAN B D.Ion activity coefficients in ion exchange polymers:applicability of manning's counterion condensation theory[J].Macromolecules,2015,48(21):8011-8024.
[18]	KAMCEV J,GALIZIA M,BENEDETTI F M,et al.Partitioning of mobile ions between ion exchange polymers and aqueous salt solutions:importance of counter-ion condensation[J].Phys Chem Chem Phys,2016,18(8):6021-6031.
[19]	HU C Z,LI M Q,SUN J Q,et al.NOM fouling resistance in response to electric field during electro-ultrafiltration:significance of molecular polarity and weight[J].Journal of Colloid and Interface Science,2019,539:11-18.
[20]	SUN J Q,HU C Z,WU B C,et al.Improving ion rejection of graphene oxide conductive membranes by applying electric field[J].Journal of Membrane Science,2020,604:118077.
[21]	SUN J Q,HU C Z,TONG T Z,et al.Performance and mechanisms of ultrafiltration membrane fouling mitigation by coupling coagulation and applied electric field in a novel electrocoagulation membrane reactor[J].Environmental Science & Technology,2017,51(15):8544-8551.
[22]	SUN J Q,HU C Z,ZHAO K,et al.Enhanced membrane fouling mitigation by modulating cake layer porosity and hydrophilicity in an electro-coagulation/oxidation membrane reactor (ECOMR)[J].Journal of Membrane Science,2018,550:72-79.
[23]	FAN X F,ZHAO H M,QUAN X,et al.Nanocarbon-based membrane filtration integrated with electric field driving for effective membrane fouling mitigation[J].Water Research,2016,88:285-292.
[24]	SUN J Q,WANG G G,ZHANG H,et al.Facile fabrication of a conductive polypyrrole membrane for anti-fouling enhancement by electrical repulsion and in situ oxidation[J].Chemosphere,2020,270:129416.
[25]	SUBTIL E L,GONÇALVES J,LEMOS H G,et al.Preparation and characterization of a new composite conductive polyethersulfone membrane using polyaniline (PANI) and reduced graphene oxide (rGO)[J].Chemical Engineering Journal,2020,390:124612.
[26]	WANG X Y,WANG Z W,CHEN H Q,et al.Removal of Cu(Ⅱ) ions from contaminated waters using a conducting microfiltration membrane[J].Jounral of Hazardous Materials,2017,339:182-190.
[27]	TAN X,HU C Z,ZHU Z Q,et al.Electrically pore-size-tunable polypyrrole membrane for antifouling and selective separation[J].Advanced Functional Materials,2019,29(35):1903081.
[28]	YI G,CHEN S,QUAN X,et al.Enhanced separation performance of carbon nanotube-polyvinyl alcohol composite membranes for emulsified oily wastewater treatment under electrical assistance[J].Separation and Purification Technology,2018,197:107-115.
[29]	SUN J Q,HU C Z,LIU Z T,et al.Surface charge and hydrophilicity improvement of graphene membranes via modification of pore surface oxygen-containing groups to enhance permeability and selectivity[J].Carbon,2019,145:140-148.
[30]	ZHANG H G,QUAN X,FAN X F,et al.Improving ion rejection of conductive nanofiltration membrane through electrically enhanced surface charge density[J].Environmental Science & Technology,2019,53(2):868-877.
[31]	HU C Z,LIU Z T,LU X L,et al.Enhancement of the Donnan effect through capacitive ion increase using an electroconductive rGO-CNT nanofiltration membrane[J].Journal of Materials Chemistry A,2018,6(11):4737-4745.
[32]	GUO L,JING Y,CHAPLIN B P.Development and characterization of ultrafiltration TiO₂ magneli phase reactive electrochemical membranes[J].Environmental Science & Technology,2016,50(3):1428-1436.
[33]	张桐,仝胜录,王晓雷,等.电渗析技术对煤气化灰水的处理[J].环境工程,2016,34(增刊1):278-281,290.
[34]	LEMAY N,MIKHAYLIN S,MAREEV S,et al.How demineralization duration by electrodialysis under high frequency pulsed electric field can be the same as in continuous current condition and that for better performances?[J].Journal of Membrane Science,2020,603:117878.
[35]	SOSA-FERNANDEZ P A,POST J W,RAMDLAN M S,et al.Improving the performance of polymer-flooding produced water electrodialysis through the application of pulsed electric field[J].Desalination,2020,484:114424.
[36]	DUFTON G,MIKHAYLIN S,GAALOUL S,et al.Systematic study of the impact of pulsed electric field parameters (pulse/pause duration and frequency) on ED performances during acid whey treatment[J].Membranes,2020,10(1):14.
[37]	WU D S,CHEN G Q,HU B S,et al.Feasibility and energy consumption analysis of phenol removal from salty wastewater by electro-electrodialysis[J].Separation and Purification Technology,2019,215:44-50.
[38]	ZHANG Z Y,LIBA D,ALVARADO L,et al.Separation and recovery of Cr(Ⅲ) and Cr(Ⅵ) using electrodeionization as an efficient approach[J].Separation and Purification Technology,2014,137:86-93.
[39]	ZHOU Y,HU C Z,LIU H J,et al.Potassium-Ion recovery with a polypyrrole membrane electrode in novel redox transistor electrodialysis[J].Environmental Science & Technology,2020,54(7):4592-4600.
[40]	REIG M,VECINO X,VALDERRAMA C,et al.Application of selectrodialysis for the removal of As from metallurgical process waters:recovery of Cu and Zn[J].Separation and Purification Technology,2018,195:404-412.
[41]	BUNANI S,YOSHIZUKA K,NISHIHAMA S,et al.Application of bipolar membrane electrodialysis (BMED) for simultaneous separation and recovery of boron and lithium from aqueous solutions[J].Desalination,2017,424:37-44.
[42]	DURAND R,PELLERIN G,THIBODEAU J,et al.Screening for metabolic syndrome application of a herring by-product hydrolysate after its separation by electrodialysis with ultrafiltration membrane and identification of novel anti-inflammatory peptides[J].Separation and Purification Technology,2020,235:116205.
[43]	DURAND R,FRABOULET E,MARETTE A,et al.Simultaneous double cationic and anionic molecule separation from herring milt hydrolysate and impact on resulting fraction bioactivities[J].Separation and Purification Technology,2019,210:431-441.
[44]	BAZINET L AND MOALIC M.Coupling of porous filtration and ion-exchange membranes in an electrodialysis stack and impact on cation selectivity:a novel approach for sea water demineralization and the production of physiological water[J].Desalination,2011,277(1/3):356-363.
[45]	GE L,WU B,LI Q H,et al.Electrodialysis with nanofiltration membrane (EDNF) for high-efficiency cations fractionation[J].Journal of Membrane Science,2016,498:192-200.
[46]	SUSS M E,PORADA S,SUN X,et al.Water desalination via capacitive deionization:what is it and what can we expect from it?[J].Energy & Environmental Science,2015,8(8):2296-2319.
[47]	BIAN Y H,YANG X F,LIANG P,et al.Enhanced desalination performance of membrane capacitive deionization cells by packing the flow chamber with granular activated carbon[J].Water Research,2015,85:371-376.
[48]	PAN J F,ZHENG Y,DING J C,et al.Fluoride removal from water by membrane capacitive deionization with a monovalent anion selective membrane[J].Industrial & Engineering Chemistry Research,2018,57(20):7048-7053.
[49]	KIM Y J,KIM J H,CHOI J H.Selective removal of nitrate ions by controlling the applied current in membrane capacitive deionization (MCDI)[J].Journal of Membrane Science,2013,429:52-57.
[50]	SAKAR H,CELIK I,BALCIK CANBOLAT C,et al.Electro-sorption of ammonium by a modified membrane capacitive deionization unit[J].Separation Science and Technology,2017,52(16):2591-2599.
[51]	GAO F,WANG L,WANG J,et al.Nutrient recovery from treated wastewater by a hybrid electrochemical sequence integrating bipolar membrane electrodialysis and membrane capacitive deionization[J].Environmental Science:Water Research & Technology,2020,6(2):383-391.
[52]	WANG Z J,GONG H,ZHANG Y,et al.Nitrogen recovery from low-strength wastewater by combined membrane capacitive deionization (MCDI) and ion exchange (IE) process[J].Chemical Engineering Journal,2017,316:1-6.
[53]	KIM D I,GWAK G,DORJI P,et al.Palladium recovery through membrane capacitive deionization from metal plating wastewater[J].ACS Sustainable Chemistry & Engineering,2017,6(2):1692-1701.
[54]	JEON S I,PARK H R,YEO J G,et al.Desalination via a new membrane capacitive deionization process utilizing flow-electrodes[J].Energy & Environmental Science,2013,6(5):1471-1475.
[55]	LIANG P,SUN X L,BIAN Y H,et al.Optimized desalination performance of high voltage flow-electrode capacitive deionization by adding carbon black in flow-electrode[J].Desalination,2017,420:63-69.
[56]	ZHANG X D,YANG F,MA J J,et al.Effective removal and selective capture of copper from salty solution in flow electrode capacitive deionization[J].Environmental Science:Water Research & Technology,2020,6(2):341-350.
[57]	FANG K,GONG H,HE W Y,et al.Recovering ammonia from municipal wastewater by flow-electrode capacitive deionization[J].Chemical Engineering Journal,2018,348:301-309.
[58]	ZHANG J,TANG L,TANG W W,et al.Removal and recovery of phosphorus from low-strength wastewaters by flow-electrode capacitive deionization[J].Separation and Purification Technology,2020,237:116322.
[59]	LIN L,HU J,LIU J,et al.Selective ammonium removal from synthetic wastewater by flow-electrode capacitive deionization using a novel K₂Ti₂O₅-activated carbon mixture electrode[J].Environmental Science & Technology,2020,54(19):12723-12731.
[60]	ZHANG C J,MA J X,WAITE T D.Ammonia-rich solution production from wastewaters using chemical-free flow-electrode capacitive deionization[J].ACS Sustainable Chemistry & Engineering,2019,7(7):6480-6485.
[61]	XU L Q,YU C,TIAN S Y,et al.Selective recovery of phosphorus from synthetic urine using flow-electrode capacitive deionization (FCDI)-based technology[J].ACS ES&T Water,2020,1(1):175-184.
[62]	EPSHTEIN A,NIR O,MONAT L,et al.Treatment of acidic wastewater via fluoride ions removal by SiO₂ particles followed by phosphate ions recovery using flow-electrode capacitive deionization[J].Chemical Engineering Journal,2020,400:125892.
[63]	ZHANG C Y,WANG M,XIAO W,et al.Phosphate selective recovery by magnetic iron oxide impregnated carbon flow-electrode capacitive deionization (FCDI)[J].Water Research,2020,189:116653.
[64]	BIAN Y H,CHEN X,LU L,et al.Concurrent nitrogen and phosphorus recovery using flow-electrode capacitive deionization[J].ACS Sustainable Chemistry & Engineering,2019,7(8):7844-7850.
[65]	黄宽,唐浩,刘丹阳,等.电容去离子技术综述(一):理论基础[J].环境工程,2016,34(增刊1):82-88.