地下水源膜法给水厂长期运行过程中膜性能演变

常嘉雨; 于水利; 刘华发; 高乐; 刘贵彩

doi:10.13205/j.hjgc.202107008

地下水源膜法给水厂长期运行过程中膜性能演变

doi: 10.13205/j.hjgc.202107008

常嘉雨^1,2,
于水利^1,2, ,,
刘华发^1,2,
高乐^1,2,
刘贵彩³

1. 同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室, 上海 200092;
2. 上海污染控制与生态安全研究院, 上海 200092;
3. 济南大学土木建筑学院, 济南 250022

基金项目:

国家自然科学基金（51778443）；国家自然科学基金（51808257）；水体污染控制与治理科技重大专项（2017ZX0710100204）

详细信息

作者简介:
常嘉雨(1997-),女,硕士研究生,主要研究方向为超滤膜污染。changjiayu97@126.com

通讯作者:
于水利(1962-),男,教授,主要研究方向为饮用水与水的膜分离技术与理论研究。ysl@tongji.edu.cn

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出版历程
- 收稿日期: 2021-01-29
- 网络出版日期: 2022-01-18

EVOLUTION IN MEMBRANE PERFORMANCE OF GROUNDWATER SOURCED WATERWORKS DURING LONG-TERM OPERATION

CHANG Jia-yu^1,2,
YU Shui-li^{1,2
, ,},
LIU Hua-fa^1,2,
GAO Le^1,2,
LIU Gui-cai³

1. State Key Laboratory of Pollution Control and Resource Utilization, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China;
2. Shanghai Institute of Pollution Control and Ecology Safety, Shanghai 200092, China;
3. School of Civil Engineering and Architecture, Jinan University, Jinan 250022, China

摘要

摘要: 大庆油田水务公司西水源水厂以地下水作为主要水源，采用臭氧/活性炭+超滤膜（UF）处理工艺；自2014年投产至2019年底已经运行5年，水厂出水浊度、有机物（COD_Mn）和菌落总数等水质指标均稳定达标，但超滤膜污染导致膜性能变化。为了探究5年运行过程中超滤膜处理性能演变情况，对膜出水水质、膜通量、跨膜压差和膜污染层等进行分析。结果表明：超滤膜对浊度和微生物的去除率保持在90%以上，对COD_Mn平均去除率维持在9%。运行5年过程中，超滤膜的比通量每年下降2.1%~4.6%，恢复性化学清洗（CIP）对超滤膜的通量与比通量恢复率分别维持在73%~91%和85%~92%。污染层分析结果表明，超滤膜的有机污染物主要是腐植酸和蛋白质等；无机污染物包括锰、铁、硅、钙和铝等。高价金属元素与有机物形成络合污染物，在污染层中起到支配作用；另外，钙和硅的无机盐垢也不可忽视。
- 饮用水 /
- 超滤膜 /
- 长期运行 /
- 处理效能 /
- 膜性能
Abstract: Daqing Oilfield Xishuiyuan Water Plant took groundwater as the main water source, used conventional-ozone/activated carbon-ultrafiltration(UF) membrane treatment technology, and had been in operation for 5 years from its commissioning in 2014 to the end of 2019. The turbidity of the effluent from the water plant, organic matter(COD_Mn) and total number of colonies reached the standard stably. However, ultrafiltration membrane fouling led to changes in membrane performance. In order to explore the evolution of ultrafiltration membrane water treatment and membrane performance during the five years operation, the water quality of membrane effluent, membrane flux, transmembrane pressure and membrane fouling layer were analyzed. The results showed that the removal rate of turbidity and microorganism maintained above 90%, while the average removal rate of organic matter was only 9%. The specific flux of the ultrafiltration membrane decreased by 2.1%~4.6% per year. Clean in place(CIP) in the flux and specific flux recovery rate of the ultrafiltration membrane were maintained in the range of 73%~91% and 85%~92%, respectively. The analysis results of the fouling layer showed that the organic pollutants of the ultrafiltration membrane were mainly humic acid and protein; the inorganic pollutants were manganese, calcium, iron, silicon and aluminium. Complex pollutants formed by high-valent metal elements and organic matter played a dominant role in the pollution layer; at the same time, inorganic salt scales with silicon and calcium shouldn't be ignored.
- drinking water /
- ultrafiltration membrane /
- long-term operation /
- processing efficiency /
- membrane performance

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参考文献(18)

[1]	范小江,张锡辉,苏子杰,等.超滤技术在我国饮用水厂中的应用进展[J].中国给水排水,2013,29(22):64-70.
[2]	GERE A R.Microfiltration operating costs[J].Journal American Water Works Association,1997,89(10):39-49.
[3]	姜立君,张永强,柏章明.超滤膜技术在我国城市净水厂中的应用现状[J].供水技术,2014,8(4):3-7.
[4]	HONG S,ELIMELECH M.Chemical and physical aspects of natural organic matter fouling of nanofiltration membranes[J].Abstracts of Papers of the American Chemical Society,1996,212:2-ENVR.
[5]	刘华发,于水利,高乐,等.超滤膜在水厂运行中分离性能变化及膜寿命评价[J].给水排水,2020,56(7):47-53.
[6]	NOROUZI M,SHARIFNEZHAD H,HOSSEINI S G.Preparation and modification of polyethersulphone MF/UF membrane by TiO₂ nanoparticles for pre-treatment of Pink water[J].International Journal of Environmental Analytical Chemistry,2019,100(2):175-188.
[7]	SONG Y F,HU Q H,SUN Y K,et al.The feasibility of UF-RO integrated membrane system combined with coagulation/flocculation for hairwork dyeing effluent reclamation[J].Science of the Total Environment,2019,691:45-54.
[8]	YU H R,QU F S,WU Z J,et al.Front-face fluorescence excitation-emission matrix (FF-EEM) for direct analysis of flocculated suspension without sample preparation in coagulation-ultrafiltration for wastewater reclamation[J].Water Research,2020,187:116452.
[9]	ALRESHEEDI M T,BASU O D.Effects of feed water temperature on irreversible fouling of ceramic ultrafiltration membranes[J].Journal of Water Process Engineering,2019,31:100883.
[10]	A F,DE WILDE W,GAERTNER M,et al.Elaborating the membrane life concept in a full scale hollow-fibers MBR[J].Journal of Membrane Science,2012,421/422:349-354.
[11]	HAO Y,MORIYA A,MARUYAMA T,et al.Effect of metal ions on humic acid fouling of hollow fiber ultrafiltration membrane[J].Journal of Membrane Science,2011,376(1/2):247-253.
[12]	WANG L F,HE D Q,CHEN W,et al.Probing the roles of Ca²⁺ and Mg²⁺ in humic acids-induced ultrafitltration membrane fouling using an integrated approach[J].Water Research,2015,81:325-332.
[13]	王晓娜,杨艳玲,陈志和,等.地下水除铁除锰-超滤组合工艺的膜污染特性[J].水处理技术,2016,42(8):115-119.
[14]	GUO W,NGO H H,LI J.A mini-review on membrane fouling[J].Bioresource Technology,2012,122:27-34.
[15]	DENG L J,NGO H H,GUO W S,et al.Pre-coagulation coupled with sponge-membrane filtration for organic matter removal and membrane fouling control during drinking water treatment[J].Water Research,2019,157:155-166.
[16]	XIE W M,NI B J,SEVIOUR T,et al.Characterization of autotrophic and heterotrophic soluble microbial product (SMP) fractions from activated sludge[J].Water Research,2012,46(19):6210-6217.
[17]	陈亮,陶辉,陈连生,等.锰离子在超滤膜有机物污染中的作用与机理研究[J].中国给水排水,2013,29(7):33-36.
[18]	乔铁军,张锡辉,张金松,等.活性炭-超滤组合工艺处理南方微污染原水的研究[J].给水排水,2011,47(4):15-18.