电渗析技术在水泥厂废水零排放处理中的应用

施小林; 王大新; 楼书怿; 陈富强; 李玉友

doi:10.13205/j.hjgc.202107025

电渗析技术在水泥厂废水零排放处理中的应用

doi: 10.13205/j.hjgc.202107025

1. 日本东北大学环境科学研究科, 日本宫城仙台 980-8579;
2. 杭州匠容道环境科技有限公司, 杭州 310018;
3. 日本东北大学工学研究科环境保全工学研究室, 日本宫城仙台 980-8579

详细信息

作者简介:
施小林(1979-),男,在读博士,主要研究方向为废水零排放。sekyouku909@yahoo.co.jp

通讯作者:
李玉友(1961-),男,博士,教授,主要研究方向为污水与市政有机废物资源化利用。gyokuyu.ri.a5@tohoku.ac.jp

计量
- 文章访问数: 151
- HTML全文浏览量: 26
- PDF下载量: 8
- 被引次数: 0
出版历程
- 收稿日期: 2021-02-28
- 网络出版日期: 2022-01-18

APPLICATION OF ELECTRODIALYSIS TECHNOLOGY IN ZERO LIQUID DISCHARGE TREATMENT FOR WASTERWATER OF A CEMENT PLANT

1. Graduate School of Environmental Studies, Tohoku University, Miyagi 980-8579, Japan;
2. Hangzhou Jiangrongdao Environment Technology Co., Ltd, Hangzhou 310018, China;
3. Laboratory of Environmental Protection Engineering, Department of Civil and Environmental Engineering, Graduate School of Engineering, Tohoku University, Miyagi 980-8579, Japan

摘要

摘要: 在国家污废水资源化战略政策驱动下，工业废水零排放已成为必然趋势。作为重工业的水泥厂主要产生的循环冷却排污废水具有含盐量高、浓缩倍率大、Ca²⁺、Mg²⁺浓度高等特点，排放和回用前须进行科学有效的脱盐处理，以减少环境污染及负担。传统处理工艺存在加药量大、运行不稳定、易造成二次污染的剩余化学污泥量大等诸多的问题。采用混凝沉淀+反渗透+电渗析工艺深度处理水泥厂排污水的技术思路，探讨了电渗析单元在高盐废水处理中极致浓缩作用及特点并考察了其长期运行效果。在陕西省某水泥厂2个月以上的运行结果表明，电渗析系统脱盐率为24.7%，浓缩倍率为14.6倍，浓缩液平均电导率和产水量分别为147.7 mS/cm和0.07 m³/h。
- 电渗析 /
- 零排放 /
- 浓缩 /
- 高盐废水
Abstract: Driven by the strategy and policy of national sewage and wastewater resource, zero liquid discharge of industrial wastewater has become an inevitable trend. As a heavy industry, the circulating cooling wastewater from cement plants is characterized by high salt content, high condensate ratio and high concentration of calcium and magnesium ions. Scientific and effective desalination treatment must be carried out before discharge and reuse to reduce the environmental pollution. The traditional treatment process has many deficiencies, such as large dosage, unstable operation, and large amount of residual chemical sludge which is easy to cause the secondary pollution. In this study, the technical idea of advanced treatment of wastewater by coagulation sedimentation+reverse osmosis+electrodialysis process was proposed. The function and characteristics of electrodialysis unit in the treatment of high salt wastewater were discussed, and its operation effect was investigated. Through the operation of a cement plant in Shaanxi province for more than 2 months, the results showed that the desalination rate of electrodialysis system was 24.7%, the concentration ratio of electrodialysis system was 14.6 times, the average conductivity and water yield of the concentrate liquid were 147.7 mS/cm and 0.07 m³/h, respectively.
- electrodialysis /
- zero liquid discharge /
- concentrated /
- high-salt wastewater

HTML全文

参考文献(21)

[1]	李勇.水泥厂循环水处理技术探讨[J].水泥技术,2012(5):44-45.
[2]	杨凤民,邹安华,邢奕,等.热电厂循环冷却排污水旁流过滤脱盐处理工艺[J].环境工程,2008,26(6):26-28 ,3.
[3]	苏金坡,檀素丽,尹连庆,等.膜法处理电厂循环冷却系统排污水的工艺研究[J].工业水处理,2005,25(12):50-53.
[4]	颜海洋,汪耀明,蒋晨啸,等.离子膜电渗析在高盐废水"零排放"中的应用、机遇与挑战[J].化工进展,2019,38(1):672-681.
[5]	陈明燕,蓝大蔚,刘宇程.高含盐废水脱盐处理技术研究进展[J].化工环保,2018,38(1):19-24.
[6]	马双忱,马岚,刘畅,等.电厂循环冷却水处理技术研究与应用进展[J].化学工业与工程,2019,36(1):38-47.
[7]	黄河雨,牛犇.循环冷却排污水深度处理回用研究进展[J].应用化工,2017,46(11):2223-2226.
[8]	MAHMOOD A E,SANTANU K B,ANDREW G L.On the influence of salt concentration on the transport properties of reverse osmosis membranes in high pressure and high recovery desalination[J].Journal of Membrane Science,2020,594:117339.
[9]	JAOUAD E,SOUAD A,SÉBASTIEN V,et al.Water desalination by forward osmosis:dynamic performance assessment and experimental validation using MgCl₂ and NaCl as draw solutes[J].Computers & Chemical Engineering,2021,149:107313.
[10]	EWAOCHE J O,NNAMDI N.Optimisation of renewable energy powered reverse osmosis desalination systems:a state-of-the-art review[J].Renewable and Sustainable Energy Reviews,2021,140:110712.
[11]	QIU Y B,RUAN H M,TANG C,et al.Study on recovering high-concentration lithium salt from lithium-containing wastewater using a hybrid reverse osmosis (RO)-electrodialysis (ED) process[J].ACS Sustainable Chemistry & Engineering,2019,7(15):13481-13490.
[12]	陈富强,池勇志,田秉晖,等.高盐工业废水零排放技术研究进展[J].工业水处理,2018,38(8):1-5.
[13]	陈晓丹,李正浩,张淦,等.均相膜电渗析在电镀废水零排放中的应用[C]//中国环境科学学会.2017科学与技术年会论文集(第二卷).厦门:中国环境科学学会,2017:2996-2999.
[14]	樊惠娜,郭琳琳.电渗析技术(EDR)在废纸造纸行业废水脱盐中的应用试验[J].环境与可持续发展,2019,44(3):147-151.
[15]	王凤侠,卫新来,刘俊生.电渗析技术在废水处理中的应用进展[J].赤峰学院学报(自然科学版),2019,35(12):36-41.
[16]	巴忠磊.电渗析工艺在火力发电厂水处理中应用的探讨[J].科技与企业,2014(16):410.
[17]	LE H,SYLVAIN G,HÉLÈNE R B.Transfer of neutral organic solutes during desalination by electrodialysis:influence of the salt composition,Journal of Membrane Science,2016,511:207-218.
[18]	CHEN F Q,CHI Y Z,ZHANG M Y,et al.Removal of heat stable salts from N-methyldiethanolamine wastewater using electrodialysis:a pilot-scale study[J].Desalination and Water Treatment,2020,196:48-57.
[19]	ALIASKARI M.SCHAFER A I.Nitrate,arsenic and fluoride removal by electrodialysis from brackish groundwater[J].Water Research,2021,190:116683.
[20]	WANG Y M,LI W,YAN H Y.et al.Removal of heat stable salts (HSS) from spent alkanolamine wastewater using electrodialysis[J].Journal of Industrial and Engineering Chemistry,2018,57(25):356-362.
[21]	TONG T Z,ELIMELECH M.The Global rise of zero liquid discharge for wastewater management:drivers,technologies,and future directions[J].Environmental Science & Technology,2016,50(13):6846-6855.