新型有机污染物污染现状及其深度处理工艺研究进展

李文刚; 孙耀胜; 么强; 陈芳; 刘竞依

doi:10.13205/j.hjgc.202108010

新型有机污染物污染现状及其深度处理工艺研究进展

doi: 10.13205/j.hjgc.202108010

李文刚¹,
孙耀胜¹,
么强³,
陈芳^1,2, ,,
刘竞依¹

1. 东北大学资源与土木工程学院, 沈阳 110819;
2. 东北大学秦皇岛分校资源与材料学院, 河北秦皇岛 066004;
3. 河北农业大学海洋学院, 河北秦皇岛 066003

基金项目:

国家自然科学基金（41501514）；河北省自然科学基金（D2019501004）；河北省科学技术厅重点研发计划项目（19224204D）。

详细信息

作者简介:
李文刚(1994-),男,硕士研究生,主要研究方向为新型污染物治理。lwg497635932@163.com

通讯作者:
陈芳(1978-),女,博士,副教授,主要从事污染生态环境修复。chenfangyq@163.com

计量
- 文章访问数: 535
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- 被引次数: 0
出版历程
- 收稿日期: 2020-06-29
- 网络出版日期: 2022-01-18

REVIEW ON POLLUTION STATUS AND ADVANCED TREATMENT TECHNOLOGIES OF EMERGING ORGANIC POLLUTANTS

1. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China;
2. School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, China;
3. Ocean College of Hebei Agriculture University, Qinhuangdao 066003, China

摘要

摘要: 新型有机污染物的污染现状及其去除技术近年来受到学界的广泛关注。由于传统污水处理厂不能有效去除新型有机污染物，导致其随污水处理厂出水、污泥等进入生态环境，产生危害。因此，为有效去除该类污染物，近年来新型有机污染物的去除技术逐渐成为研究热点。通过总结新型有机污染物的污染现状及其危害，对目前新型处理技术，包括活化过硫酸盐、光催化耦合微生物同步降解、臭氧微气泡法、金属-有机框架材料、固定化微生物和漆酶降解等技术进行了综述，并分析了各种技术的优势和缺点。结果表明：目前对这些新型工艺降解新型有机污染物的研究大多处于实验室研究阶段，且多为单一工艺研究，部分工艺存在有毒有害产物。建议通过建立数学模型，使其在预测工艺降解能力、评估污染物毒性及其环境风险、污染程度等方面更加简便、经济。同时应进一步筛选高效菌株，研发安全可靠的新型处理材料，通过清洁生产，从根源上消除新型污染物污染。
- 污水处理厂 /
- 新型有机污染物 /
- 新型高级氧化技术 /
- 金属-有机框架材料
Abstract: In recent years, the pollution status and removal technology of emerging organic pollutants received widespread attention. As the emerging organic pollutants cannot be effectively removed by traditional sewage treatment plants, they will enter the ecological environment together with the sewage treatment plant effluent, sludge, etc., and cause harm. Therefore, in order to effectively remove such pollutants, new treatment technologies gradually become a research hotspot in recent years. By summarizing the treatment status and harms of emerging organic pollutants in sewage treatment plants, new treatment technologies were reviewed including activated persulfate, intimate coupling of photocatalysis and biodegradation technology, ozone microbubble method, metal-organic framework materials, immobilized microorganisms, immobilized laccase degradation technology, etc. And the advantages and disadvantages of various technologies were analyzed. The results showed that the current new treatment technologies for emerging organic pollutants were mainly in the laboratory research stage, and most of them were single technology studies, Some treatment processes even produced toxic and harmful products. It was suggested that mathematical model should be established to make it more convenient and economical to predict the degradation ability of the treatment process, assess the toxicity and environmental risk of pollutants, further screen the high-efficiency strains, and develope safe and reliable new treatment materials. Emerging pollutants were then eliminated from the root, through cleaner production.
- sewage treatment plant /
- emerging organic pollutants /
- new advanced oxidation technology /
- metal-organic framework materials

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参考文献(105)

[1]	TRAN N H,REINHARD M,GIN K Y,et al.Occurrence and fate of emerging contaminants in municipal wastewater treatment plants from different geographical regions-a review[J].Water Research,2018,133:182-207.
[2]	李婷睿.基于海绵城市理念的智慧水务应用研究[J].给水排水,2017,53(7):129-135.
[3]	KOSMA C I,LAMBROPOULOU D A,ALBANIS T A,et al.Investigation of PPCPs in wastewater treatment plants in Greece:occurrence,removal and environmental risk assessment[J].Science of the Total Environment,2014,466/467:421-438.
[4]	BEN W W,ZHU B,YUAN X J,et al.Occurrence,removal and risk of organic micropollutants in wastewater treatment plants across China:comparison of wastewater treatment processes[J].Water Research,2018,130:38-46.
[5]	PABLO G,GROS M,AHRENS L,et al.Impact of on-site,small and large scale wastewater treatment facilities on levels and fate of pharmaceuticals,personal care products,artificial sweeteners,pesticides,and perfluoroalkyl substances in recipient waters[J].Science of the Total Environment,2017,601/602:1289-1297.
[6]	CZEKALSKI N,SIGDEL R,BIRTEL J,et al.Does human activity impact the natural antibiotic resistance background?abundance of antibiotic resistance genes in 21 Swiss lakes[J].Environment International,2015,81:45-55.
[7]	KUMAR A,PAL D.Antibiotic resistance and wastewater:correlation,impact and critical human health challenges[J].Journal of Environmental Chemical Engineering,2018,6(1):52-58.
[8]	MARTI E,JOFRE J,BALCAZAR J L,et al.Prevalence of antibiotic resistance genes and bacterial community composition in a river influenced by a wastewater treatment plant[J].PLOS ONE,2013,8(10):e78906.
[9]	SHARMA V K,JOHNSON N,CIZMAS L,et al.A review of the influence of treatment strategies on antibiotic resistant bacteria and antibiotic resistance genes[J].Chemosphere,2016,150:702-714.
[10]	SHEYLA A O,PINTO PINTO G,GARCIA-ENCINA P A,et al.Ecotoxicity and environmental risk assessment of pharmaceuticals and personal care products in aquatic environments and wastewater treatment plants[J].Ecotoxicology,2014,23(8):1517-1533.
[11]	CHRISTINA R,HAPESHI E,et al.Long-term wastewater irrigation of vegetables in real agricultural systems:concentration of pharmaceuticals in soil,uptake and bioaccumulation in tomato fruits and human health risk assessment[J].Water Research,2017,109:24-34.
[12]	RIEMENSCHNEIDER C,AL-RAGGAD M,MOEDER M,et al.Pharmaceuticals,their metabolites,and other polar pollutants in field-grown vegetables irrigated with treated municipal wastewater[J].J Agric Food Chem.,2016,64(29):5784-5792.
[13]	WANG M,PENG C,CHEN W,et al.Ecological risks of polycyclic musk in soils irrigated with reclaimed municipal wastewater[J].Ecotoxicology and Environmental Safety,2013,97:242-247.
[14]	JING X,YAO G,LIU D,et al.Effects of wastewater irrigation and sewage sludge application on soil residues of chiral fungicide benalaxyl[J].Environmental Pollution,2017,224:1-6.
[15]	MARANO R B M,ZOLTI A,JURKEVITCH E,et al.Antibiotic resistance and class 1 integron gene dynamics along effluent,reclaimed wastewater irrigated soil,crop continua:elucidating potential risks and ecological constraints[J].Water Research,2019,164:114906.
[16]	ABDEL-SHAFY H I,MANSOUR M S M.A review on polycyclic aromatic hydrocarbons:source,environmental impact,effect on human health and remediation[J].Egyptian Journal of Petroleum,2016,25(1):107-123.
[17]	MEZZANOTTE V,ANZANO M,COLLINA E,et al.Distribution and removal of polycyclic aromatic hydrocarbons in two Italian municipal wastewater treatment plants in 2011-2013[J].Polycyclic Aromatic Compounds,2016,36(3):213-228.
[18]	LIU L Y,KUKUCKA P,VENIER M,et al.Differences in spatiotemporal variations of atmospheric PAH levels between North America and Europe:data from two air monitoring projects[J].Environment International,2014,64:48-55.
[19]	ABD MANAN T S B,KHAN T,SIVAPALAN S,et al.Application of response surface methodology for the optimization of polycyclic aromatic hydrocarbons degradation from potable water using photo-Fenton oxidation process[J].The Science of the Total Environment,2019,665:196-212.
[20]	李博.污水处理厂中PACs的迁移转化规律和归趋模型研究[D].哈尔滨:哈尔滨工业大学,2016.
[21]	DENG Y,BONILLA M,REN H,et al.Health risk assessment of reclaimed wastewater:A case study of a conventional water reclamation plant in Nanjing,China[J].Environment international,2017,112:235-242.
[22]	SUBEDI B,KANNAN K.Fate of artificial sweeteners in wastewater treatment plants in New York State,U.S.A.[J].Environmental Science & Technology,2014,48(23):13668-13674.
[23]	HAMANN E,STUYFZAND P J,GRESKOWIAK J,et al.The fate of organic micropollutants during long-term/long-distance river bank filtration[J].Science of the Total Environment,2016,545/546:629-640.
[24]	STEPIEN D K,DIEHL P,HELM J,et al.Fate of 1,4-dioxane in the aquatic environment:from sewage to drinking water[J].Water Research,2014,48:406-419.
[25]	DOURSON M L,HIGGINBOTHAM J,CRUM J,et al.Update:Mode of action (MOA) for liver tumors induced by oral exposure to 1,4-dioxane[J].Regulatory Toxicology and Pharmacology,2017,88:45-55.
[26]	MARGOT J,ROSSI L,BARRY D A,et al.A review of the fate of micropollutants in wastewater treatment plants[J].Wiley Interdisciplinary Reviews:Water Homepage,2015,2(5):457-487.
[27]	耿存珍,段玉双,王艺璇,等.有机磷系阻燃剂的全球污染现状[J].生态毒理学报,2016,11(2):124-133.
[28]	李素珍,付卫强,冯承莲,等.有机磷酸酯阻燃剂的环境暴露、环境行为和毒性效应研究进展[J].环境工程,2018,36(9):35,180 -184.
[29]	WEI G L,LI D Q,ZHUO M N,et al.Organophosphorus flame retardants and plasticizers:sources,occurrence,toxicity and human exposure[J].Environmental Pollution,2015,196:29-46.
[30]	高立红.北京市城市环境有机磷酸酯污染水平和分布特征研究[D].北京:北京科技大学,2016.
[31]	LEHNER A F,SAMSING F,RUMBEIHA W K,et al.Organophosphate ester flame retardant-induced acute intoxications in dogs[J].Journal of Medical Toxicology,2010,6(4):448.
[32]	JORGE E,RICE C P,TORRENTS A.Fate of octyl- and nonylphenol ethoxylates and some carboxylated derivatives in three American wastewater treatment plants[J].Environmental Science & Technology,2007,41(19):6815-6821.
[33]	BARBER L B,LOYO-ROSALES J E,RICE C P,et al.Endocrine disrupting alkylphenolic chemicals and other contaminants in wastewater treatment plant effluents,urban streams,and fish in the Great Lakes and Upper Mississippi River Regions[J].Science of the Total Environment,2015,517:195-206.
[34]	CHANG H S,CHOO K H,LEE B,et al.The methods of identification,analysis,and removal of endocrine disrupting compounds (EDCs) in water[J].Journal of Hazardous Materials,2009,172(1):1-12.
[35]	徐文冰,干志伟.人工甜味剂污染及其在环境中的行为[J].四川农业科技,2016,(9):65-67.
[36]	LUO J,ZHANG Q,CAO M,et al.Ecotoxicity and environmental fates of newly recognized contaminants-artificial sweeteners:a review[J].Science of the Total Environment,2019,653:1149-1160.
[37]	UEBANSO T,OHNISHI A,KITAYAMA R,et al.Effects of low-dose non-caloric sweetener consumption on gut microbiota in mice[J].Nutrients,2017,9(6):560.
[38]	ARDALAN M R,TABIBI H,EBRAHIMZADEH A V,et al.Nephrotoxic effect of aspartame as an artificial sweetener:a brief review[J].Iranian Journal of Kidney Diseases,2017,11(5):339-343.
[39]	CHI L,BIAN X,GAO B,et al.Effects of the artificial sweetener neotame on the gut microbiome and fecal metabolites in mice[J].Molecules,2018,23(2):367.
[40]	DING G,PEIJNENBURG W J G M,et al.Physicochemical properties and aquatic toxicity of poly- and perfluorinated compounds[J].Critical Reviews in Environmental Science and Technology,2013,43(6):598-678.
[41]	周珍,胡宇宁,史亚利,等.武汉地区水环境中全氟化合物污染水平及其分布特征[J].生态毒理学报,2017,12(3):425-433.
[42]	MA R,SHIH K.Perfluorochemicals in wastewater treatment plants and sediments in Hong Kong[J].Environmental Pollution,2010,158(5):1354-1362.
[43]	KWON H O,KIM H Y,PARK Y M,et al.Updated national emission of perfluoroalkyl substances (PFASs) from wastewater treatment plants in South Korea[J].Environmental Pollution,2017,220:298-306.
[44]	KATARZYNA S,SURMA M,CIESLIK E,et al.The perfluoroalkyl substances (PFASs) contamination of fruits and vegetables[J].Food Additives & Contaminants:Part A,2018,35(9):1776-1786.
[45]	BURCU Ü,BAKIR E,BAKIR E,et al.Assessment of perfluoroalkyl substances levels in tap and bottled water samples from Turkey[J].Chemosphere,2019,235:1162-1171.
[46]	JIAN J M,GUO Y,ZENG L,et al.Global distribution of perfluorochemicals (PFCs) in potential human exposure source-a review[J].Environment International,2017,108:51-62.
[47]	DOMINGO J L,NADAL M.Human exposure to per- and polyfluoroalkyl substances (PFAS) through drinking water:a review of the recent scientific literature[J].Environmental Research,2019,177:108648.
[48]	CLARA M,SCHEFFKNECHT C,SCHARF S,et al.Emissions of perfluorinated alkylated substances (PFAS) from point sources-identification of relevant branches[J].Water Science & Technology,2008,58(1):59-66.
[49]	AHRENS L,BUNDSCHUH M.Fate and effects of poly- and perfluoroalkyl substances in the aquatic environment:a review[J].Environmental Toxicology and Chemistry,2014,33(9):1921-1929.
[50]	CASTIGLIONI S,VALSECCHI S,POLESELLO S,et al.Sources and fate of perfluorinated compounds in the aqueous environment and in drinking water of a highly urbanized and industrialized area in Italy[J].Journal of Hazardous Materials,2015,282:51-60.
[51]	宋彦敏,周连宁,郝文龙,等.全氟化合物的污染现状及国内外研究进展[J].环境工程,2017,35(10):82-86.
[52]	王士运.全氟化合物PFOA对雄性黑斑蛙的生殖毒效应及机理研究[D].杭州:杭州师范大学,2017.
[53]	蒲生彦,吕雪,张颖,等.基于文献计量的全球活化过硫酸盐氧化技术研究趋势分析[J].环境工程学报,http://kns.cnki.net/kcms/detail/11.5591.X.20200415.1826.002.html.
[54]	LI A,WU Z,WANG T,et al.Kinetics and mechanisms of the degradation of PPCPs by zero-valent iron (Fe⁰) activated peroxydisulfate (PDS) system in groundwater[J].J Hazard Mater.,2018,357:207-216.
[55]	KANG Y G,YOON H,LEE W,et al.Comparative study of peroxide oxidants activated by nZVI:Removal of 1,4-dioxane and arsenic (Ⅲ) in contaminated waters[J].Chemical Engineering Journal,2018,334:2511-2519.
[56]	WU S H,HE H J,LI X,et al.Insights into atrazine degradation by persulfate activation using composite of nanoscale zero-valent iron and graphene performances and mechanisms[J].Chemical Engineering Journal,2018,341:126-136.
[57]	GU M,FAROOQ U,LU S,et al.Degradation of trichloroethylene in aqueous solution by rGO supported nZVI catalyst under several oxic environments[J].Journal of Hazardous Materials,2018,349:35-44.
[58]	DENG J,DONG H,ZHANG C,et al.Nanoscale zero-valent iron/biochar composite as an activator for Fenton-like removal of sulfamethazine[J].Separation and Purification Technology,2018,202:130-137.
[59]	GAO J,HAN D,XU Y,et al.Persulfate activation by sulfide-modified nanoscale iron supported by biochar (S-nZVI BC) for degradation of ciprofloxacin[J].Separation and Purification Technology,2020,235:116202.
[60]	LI H,ZHU F,HE S,et al.The degradation of decabromodiphenyl ether in the e-waste site by biochar supported nanoscale zero-valent iron/persulfate[J].Ecotoxicology and Environmental Safety,2019,183:109540.
[61]	LUO S,DUAN L,SUN B,et al.Manganese oxide octahedral molecular sieve (OMS-2) as an effective catalyst for degradation of organic dyes in aqueous solutions in the presence of peroxymonosulfate[J].Applied Catalysis B:Environmental,2015,164:92-99.
[62]	DU J,BAO J,LIU Y,et al.Efficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A[J].Journal of Hazardous Materials,2016,320:150-159.
[63]	REN Y M,LIN L Q,MA J,et al.Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe₂O₄ (M=Co,Cu,Mn,and Zn) as heterogeneous catalysts in the water[J].Applied Catalysis B:Environmental,2015,165:572-578.
[64]	YANG S,WU P,LIU J,et al.Efficient removal of bisphenol A by superoxide radical and singlet oxygen generated from peroxymonosulfate activated with Fe0-montmorillonite[J].Chemical Engineering Journal,2018,350:484-495.
[65]	HUANG G,WANG C,YANG C,et al.Degradation of bisphenol A by peroxymonosulfate catalytically activated with Mn1.8Fe1.2O4 nanospheres:synergism between Mn and Fe[J].Environmental Science & Technology,2017,51(21):12611-12618.
[66]	NAM S N,CHO H,HAN J,et al.Photocatalytic degradation of acesulfame K:optimization using the Box-Behnken design (BBD)[J].Process Safety and Environmental Protection,2018,113:10-21.
[67]	FU Y,WU G,GENG J,et al.Kinetics and modeling of artificial sweeteners degradation in wastewater by the UV persulfate process[J].Water Research,2018,150:12-15.
[68]	WANG Y,ZHAO X,CAO D,et al.Peroxymonosulfate enhanced visible light photocatalytic degradation bisphenol A by single-atom dispersed Ag mesoporous g-C₃N₄ hybrid[J].Applied Catalysis B,2017,211:79-88.
[69]	余韵,陆金鑫,吕贞,等.紫外活化过硫酸盐降解水中三氯蔗糖动力学和机制[J].https://doi.org/10.13227/j.hjkx.202001046.
[70]	丁蕊,赵峰.光催化耦合微生物同步降解污染物[J].化学进展,2017,29(9):1154-1158.
[71]	熊厚锋.可见光催化氧化-生物降解直接耦合技术降解四环素废水的效能与作用机制[D].长春:吉林大学,2017.
[72]	MICHAEL D M,TORRES C I,HAUSNER M,et al.Intimate coupling of photocatalysis and biodegradation in a photocatalytic circulating-bed biofilm reactor[J].Biotechnology and Bioengineering,2008,101(1):83-92.
[73]	CAI H Y,SUN L,WANG Y M,et al.Unprecedented efficient degradation of phenanthrene in water by intimately coupling novel ternary composite Mn₃O₄ MnO₂-Ag₃PO₄ and functional bacteria under visible light irradiation[J].Chemical Engineering Journal,2019,369:1078-1092.
[74]	马艳,张鑫,韩小蒙,等.臭氧微纳米气泡技术在水处理中的应用进展[J].净水技术,2019,38(8):64-67.
[75]	郑天龙.微气泡/臭氧-三维电极反应器深度处理腈纶废水的研究[D].北京:北京科技大学,2016.
[76]	SUN Z,CHEN X,YANG K,et al.The progressive steps for TPH stripping and the decomposition of oil refinery sludge using microbubble ozonation[J].Science of the Total Environment,2020,712:135631.
[77]	熊永磊,杨小丽,宋海亮,等.微纳米气泡在水处理中的应用及其发生装置研究[J].环境工程,2016,34(6):23-27.
[78]	NAM G,MOHAMED M M,JUNG J,et al.Enhanced degradation of benzo[a]pyrene and toxicity reduction by microbubble ozonation[J].Environmental Technology,2019,https://doi.org/10.1080/09593330.2019.1683077.
[79]	TAKASHI A,OTOMO K,KUNITOU M,et al.Removal of pharmaceuticals in water by introduction of ozonated microbubbles[J].Separation and Purification Technology,2018,212:483-489.
[80]	施佳泽,张磊,张静,等.微气泡催化臭氧化-生化耦合工程装置运行性能[J].工业水处理,http://kns.cnki.net/kcms/detail/12.1087.X.20200421.1456.002.html.
[81]	KHENG S T,MADEHI N.Ozonation of ofloxacin in water:By-products,degradation pathway and ecotoxicity assessment[J].Science of The Total Environment,2015,520:23-31.
[82]	HU Z,WEN X,SI X,et al.Pre-ultrafiltration or pre-ozonation for EDCs removal in a combined ultrafiltration and ozonation process[J].Journal of Chemical Technology and Biotechnology,2016,91(12):2929-2934.
[83]	谢莎莎.多孔碳材料的制备及其去除水体中卡马西平的研究[D].南昌:南昌航空大学,2018.
[84]	JOSEPH L,JUN B,JANG M,et al.Removal of contaminants of emerging concern by metal-organic framework nanoadsorbents:A review[J].Chemical Engineering Journal,2019,369:928-946.
[85]	ZHUANG S,CHENG R,WANG J,et al.Adsorption of diclofenac from aqueous solution using UiO-66-type metal-organic frameworks[J].Chemical Engineering Journal,2019,359:354-362.
[86]	BISWA N B,JHUNG S H.Adsorptive removal of wide range of pharmaceuticals and personal care products from water using bio-MOF-1 derived porous carbon[J].Microporous and Mesoporous Materials,2018,270:102-108.
[87]	ZHAO R,MA T,LI S,et al.Porous aromatic framework modified electrospun fiber membrane as a highly efficient and reusable adsorbent for pharmaceuticals and personal care products removal[J].American Chemical Society,2019,11(18):16662-16673.
[88]	赵朝成,吴光锐.MOFs复合材料催化降解水中有机污染物的应用研究进展[J].化工进展,2019,38(4):1775-1784.
[89]	卓宁.金属有机框架/高分子复合吸附剂对新兴污染物的吸附研究[D].南京:南京师范大学,2017.
[90]	LI H,ZHANG J,YAO Y,et al.Nanoporous bimetallic metal-organic framework (FeCo-BDC) as a novel catalyst for efficient removal of organic contaminants[J].Environmental Pollution,2019,255:113337.
[91]	黄茜.生物质炭固定化微生物对水中壬基酚的去除效果研究[D].杭州:浙江大学,2018.
[92]	袁鑫.固定化微生物强化工业废水处理的研究[D].太原:太原理工大学,2019.
[93]	陈曦.多环芳烃降解菌包埋固定化及其降解特性研究[D].重庆:重庆大学,2018.
[94]	KAZUICHI I,UDAGAWA M,KIMURA Y,et al.Biological wastewater treatment of 1,4-dioxane using polyethylene glycol gel carriers entrapping Afipia sp.D1[J].Journal of Bioscience and Bioengineering,2016,121(2):203-208.
[95]	CHUNG J,LEE,G,CHUNG S,et al.Removal of 1,4-dioxane in water using specific microbe immobilization cells[J].Water,Air, & Soil Pollution,2019,230(6):114.
[96]	孙安琪.炭基材料固定化微生物及其对PAHs污染土壤的修复研究[D].华侨大学,2019.
[97]	DONG R,CHEN D,LI N,et al.Enhancement of organic pollutants bio-decontamination from aqueous solution using newly-designed Pseudomonas putida-Ga/MIl-100(Fe) bio-nanocomposites[J].Environmental Research,2019,173:237-245.
[98]	GARCÍA-DELGADO C,EYMAR E,CAMACHO-ARÉVALO R,et al.Degradation of tetracyclines and sulfonamides by stevensite- and biochar-immobilized laccase systems and impact on residual antibiotic activity[J].Journal of Chemical Technology & Biotechnology,2018,93(12):3394-3409.
[99]	宁甲练,陈志莉,汪楚依,等.固定化漆酶降解水中酚类污染物的研究进展[J].水处理技术,2019,45(2):13-17.
[100]	王小琴,张耿崚,李清荷,等.利用固定化技术与添加表面活性剂增强双酚A降解率的研究[J].环境科学学报,2017,37(9):3342-3348.
[101]	MOKHTAR A,NISHIOKA T,MATSUMOTO H,et al.Novel biodegradation system for bisphenol A using laccase-immobilized hollow fiber membranes[J].International Journal of Biological Macromolecules,2019,130:737-744.
[102]	李彦莹,李雪花,杨先海,等.有机污染物生物降解性预测模型[J].生态毒理学报,2012,7(5):549-555.
[103]	陆守昆.植物根系吸收疏水性有机污染物的数学模型构建[D].南京:南京农业大学,2016.
[104]	QI X,LI X,YAO H,et al.Predicting plant cuticle-water partition coefficients for organic pollutants using pp-LFER model[J].Science of the Total Environment,2020,725:138455.s
[105]	TOROPOVA A P,TOROPOV A A.Use of the index of ideality of correlation to improve models of eco-toxicity[J].Environmental Science and Pollution Research,2018,25(31):31771-31775.