REMEDIATION OF Cd CONTAMINATED SOIL BY ARTIFICIAL STRUVITE COMBINED WITH RYEGRASS
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摘要: 以MgCl2为添加剂,调节含N、P废水中n(Mg2+)∶n(NH4+)∶n(PO43-)比例为1.15∶1∶1,pH为8.5~9,反应时间30 min,经SEM、FT-IR、XRD表征后发现,所得产物以鸟粪石为主。将人工鸟粪石联合黑麦草修复Cd污染土壤,研究表明:人工鸟粪石可有效提升土壤pH、速效磷含量以及酶活性,同时可以降低土壤中交换态Cd含量,增加黑麦草叶片谷胱甘肽GSH含量来降低叶片内丙二醛MDA含量,减少膜脂过氧化程度。与对照相比,人工鸟粪石使黑麦草生物量提升81.7%~148.5%,Cd总提取量提升25.41%~44.27%,且当添加剂量为5%时修复效率最佳。Abstract: With magnesium chloride as the additive, the artificial struvite was prepared when the ratio of n(Mg2+):n(NH4+):n(PO43-) in N and P wastewater was adjusted to be 1.15:1:1, pH was between 8.5 and 9, and the reaction time was 30 min. The product was characterized by SEM, FT-IR and XRD, indicating that struvite was the main content. Artificial struvite combined with ryegrass was used to remediation soil contaminated by Cd. Studies showed that artificial struvite could effectively improve the soil pH, available phosphorus content and enzyme activity to increase soil environmental quality. At the same time, it could reduce the exchangable Cd content in the soil and increase the GSH content in the ryegrass leaves to reduce the MDA content in the leaves and reduce the degree of membrane lipid peroxidation. Compared with the control, the biomass of ryegrass was increased by 81.7%~148.5%, and the total extraction of Cd was increased by 25.41%~44.27%. The remediation efficiency was the best when the additive dosage was 5%.
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Key words:
- artificial struvite /
- Cd /
- soil /
- ryegrass /
- remediation
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