派河清水廊道表层沉积物中磷的赋存形态特征及其环境指示意义

陈莹莹; 张浏; 尹浩; 王育来

doi:10.13205/j.hjgc.202112011

派河清水廊道表层沉积物中磷的赋存形态特征及其环境指示意义

doi: 10.13205/j.hjgc.202112011

陈莹莹¹,
张浏²,
尹浩³,
王育来^1, ,

1. 安徽工业大学能源与环境学院, 安徽马鞍山 243002;
2. 安徽省环境科学研究院, 合肥 230071;
3. 中国科学技术大学地球与空间科学学院壳幔物质与环境实验室, 合肥 230026

基金项目:

国家科技重大专项(2017ZX07603-004)。

详细信息

作者简介:
陈莹莹(1996-),女,硕士研究生,主要研究方向为流域污染控制。yingying_chen1996@163.com

通讯作者:
王育来(1982-),男,副教授,主要研究方向为重污染水体修复技术。yulai_wang@yahoo.com

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出版历程
- 收稿日期: 2020-11-10
- 网络出版日期: 2022-03-30
- 刊出日期: 2022-03-30

CHARACTERISTICS OF PHOSPHORUS FRACTIONS IN SURFACE SEDIMENT FROM A CLEAR WATER GALLERY IN PAIHE RIVER, AND ITS ENVIRONMENTAL IMPLICATIONS

1. School of Energy and Environment, Anhui University of Technology, Maanshan 243002, China;
2. Anhui Research Academy for Environmental Science, Hefei 230071, China;
3. CAS Key Laboratory of Crust-Mantle Materials and the Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China

摘要

摘要: 沉积物磷的赋存形态是河流内源释放的关键控制因素之一。以“引江济淮—江淮沟通”段清水廊道——派河为研究对象,分别测定了派河表层沉积物中总磷、无机磷和有机磷含量,并采用分级提取法分析了有机磷赋存形态,包括活性有机磷(labile organic phosphorus, LOP)、中活性有机磷(moderately labile organic phosphorus, MLOP)和非活性有机磷(nonlabile organic phosphorus, NOP),进一步探讨了不同磷形态的空间分布特征。结果表明:派河表层沉积物中总磷含量为471.17~1509.58 mg/kg,无机磷含量为421.83~1325.17 mg/kg,有机磷含量为103.29~221.79 mg/kg;派河沉积物各形态有机磷含量大小顺序总体上为NOP>LOP>MLOP,其中MLOP和NOP含量均表现为下游河段含量显著高于中上游河段(P<0.05)。同时,有机磷的赋存形态与沉积物的理化性质相关,NOP与阳离子交换量呈显著正相关(P<0.05);MLOP和NOP均与LOI(loss on ignition)呈显著正相关(P<0.05),表明沉积物中有机质含量和CEC可能会影响沉积物中有机磷的赋存形态。研究结果表明,“江淮沟通”工程的实施可能引起沉积物中磷的内源释放,建议工程实施后应在削减外源输入和内源控制的基础上加强流域生态监测,实施流域智慧管理等措施。
- 清水廊道 /
- 有机磷形态 /
- 引江济淮 /
- 内源释放
Abstract: The fractions distribution of sediment phosphorus is one of the important controlling factors of river endogenous release. In present study, the total phosphorus, inorganic phosphorus and organic phosphorus contents in surface sediments of Paihe River section, the clear water gallery of Yangtze-Huaihe Water Diversion, were determined. The organic phosphorus fractions were explored by the method of graded extraction, including labile organic phosphorus(LOP), moderately labile organic phosphorus(MLOP) and nonlabile organic phosphorus(NOP). And the spatial distribution characteristics of phosphorus fractions were further discussed. The results showed that the total phosphorus content in the surface sediments of Paihe River was 471.17~1509.58 mg/kg, among which the inorganic phosphorus content was 421.83~1325.17 mg/kg, and the organic phosphorus content was 103.29~221.79 mg/kg. Generally, the contents of organic phosphorus fractions followed the order of NOP>LOP>MLOP, and the content of MLOP and NOP were significantly higher in the downstream reach than in the middle and upper reach(P<0.05). The organic phosphorus fractions was related to the physical and chemical properties of sediments. NOP had significant positive correlation with cation exchange capacity(CEC)(P<0.05), MLOP and NOP had significant positive correlation with loss on ignition(LOI)(P<0.05), indicating that the variation of organic matter and CEC in sediments affected the distribution of organic phosphorus fractions. The results of this study indicated that the implementation of the Yangtze-Huaihe Water Diversion project may lead to the endogenous release of phosphorus in sediments. Therefore, after the project implemented, on the basis of reducing exogenous input and endogenous control, ecological monitoring should be strengthened and watershed intelligent management should be conducted.
- clear water gallery /
- organic phosphorus fractions /
- Yangtze-Huaihe water diversion project /
- endogenous release

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参考文献(36)

[1]	王海军,王洪铸.富营养化治理应放宽控氮、集中控磷[J].自然科学进展,2009,19(6):17-22.
[2]	PEI G F,WANG Q,LIU G X,et al.The role of periphyton in phosphorus retention in shallow lakes with different trophic status,China[J].Aquatic Botany,2015,125:17-22.
[3]	孔范龙,郗敏,徐丽华,等.富营养化水体的营养盐限制性研究综述[J].地球环境学报,2016,7(2):121-129.
[4]	LÜ C W,HE J,ZHOU B,et al.Distribution characteristics of organic phosphorus in sediments from Lake Hulun,China[J].Environmental Science: Processes and Impacts,2015,17(10):1851-1858.
[5]	WAN J,Yuan X Y,HAN L,et al. Characteristics and distribution of organic phosphorus fractions in the surface sediments of the inflow rivers around Hongze Lake,China[J].International Journal of Environmental Research and Public Health,2020,17(2):648-664.
[6]	金相灿,王圣瑞,庞燕.太湖沉积物磷形态及pH值对磷释放的影响[J].中国环境科学,2004,24(6):68-72.
[7]	WU P B,YIN A J,FAN M M,et al.Phosphorus dynamics influenced by anthropogenic calcium in an urban stream flowing along an increasing urbanization gradient[J].Landscape and Urban Planning,2018,177:1-9.
[8]	丁瑶,欧阳莉莉,石清,等.特大城市河流表层沉积物磷形态分布及有效性:以成都市为例[J]. 环境科学,2019,40(1):219-227.
[9]	王辉,焦振恒,刘春跃,等.辽河辽宁段干流表层沉积物中磷的含量及赋存形态研究[J].生态环境学报,2019,28(12):2409-2415.
[10]	江雪,文帅龙,姚书春,等.天津于桥水库沉积物磷赋存特征及其环境意义[J].湖泊科学,2018,30(3):50-61.
[11]	张文强,李洁,金鑫,等.基于31P-NMR与SMT方法的海河流域典型河流沉积物中磷形态特征研究[J].环境科学学报,2016,36(6):1891-1900.
[12]	IVANOFF D B,REDDY K R,ROBINSON S,Chemical fractionation of organic phosphorus in selected histosols[J].Soil Science,1998,163(1):36-45.
[13]	马双丽,倪兆奎,王圣瑞,等.鄱阳湖沉积物有机磷形态及对水位变化响应[J].环境科学学报,2016,36(10):3607-3614.
[14]	NORTON S A,COOLIDGE K,AMIRBAHMAN A,et al.Speciation of Al,Fe,and P in recent sediment from three lakes in Maine,USA[J].Science of the Total Environment,2008,404(2/3):276-283.
[15]	徐健,袁旭音,叶宏萌,等.闽江上游溪流沉积物有机磷空间分布及其环境意义分析[J].环境科学,2019,40(5):2186-2193.
[16]	GAO Y L,LIANG T,TIAN S H,et al.High-resolution imaging of labile phosphorus and its relationship with iron redox state in lake sediments[J].Environmental Pollution,2016,219:466-474.
[17]	严攀,徐栋,刘子森,等.杭州西湖沉积物磷分析及释放风险[J].环境化学,2019,38(7):1479-1487.
[18]	王玲玲,吴卫菊,张斌,等.梁子湖沉积物中重金属及营养盐分布特征研究[J].环境科学与技术,2015,38(6):197-203.
[19]	ASPILA K I,AGEMIAN H,CHAU A S Y. A semi-automated method for the determination of inorganic,organic and total phosphate in sediments[J].Analyst,1976,101:187-197.
[20]	ZHANG K,CHENG P D,ZHONG B C,et al.Total phosphorus release from bottom sediments in flowing water[J].Journal of Hydrodynamics,2012,24(4):589-594.
[21]	鲍林林,李叙勇.河流沉积物磷的吸附释放特征及其影响因素[J].生态环境学报,2017,26(2):350-356.
[22]	张瑞明.巢湖主要入湖河流沉积物磷赋存特征及其环境意义[D].南京:南京大学,2019.
[23]	张友,宋佳伟,吕迎春,等.荣成天鹅湖沉积物有机磷的生物有效性及其时空动态[J].环境科学学报,2017,37(12):4629-4635.
[24]	李强,尹俊华,席北斗,等.巢湖入湖河流沉积物中有机磷的形态分级研究[J].环境工程学报,2014,8(2):441-447.
[25]	董丹萍,章婷曦,张丁予,等.太湖湖泛易发区沉积物中有机磷形态分布特征[J].环境科学,2016,37(11):4194-4202.
[26]	霍守亮,李青芹,昝逢宇,等.我国不同营养状态湖泊沉积物有机磷形态分级特征研究[J].环境科学,2011,32(4):1000-1007.
[27]	孙静,王圣瑞,曾清如.洱海表层沉积物有机磷形态分布特征及其影响因素[J].环境科学研究,2011,24(11):1226-1232.
[28]	金相灿,孟凡德,姜霞,等.太湖东北部沉积物理化特征及磷赋存形态研究[J].长江流域资源与环境,2006,15(3):388-393.
[29]	ZHANG W Q,SHAN B Q,LI J,et al.Characteristics,distribution and ecological risk assessment of phosphorus in surface sediments from different ecosystems in Eastern China:a P-31-nuclear magnetic resonance study[J]. Ecological Engineering,2015,75:264-271.
[30]	高海鹰,刘韬,丁士明,等.滇池沉积物有机磷形态分级特征[J].生态环境,2008,17(6):2137-2140.
[31]	黄晓敏,杨盛昌,彭建,等.派河流域滨岸带植物群落物种多样性和群落相似性分析及滨岸缓冲带模型构建[J].环境工程,2019,37(12):55-59 ,70.
[32]	孙康茜,刘花台,曹文志,等.引江济淮工程对派河水环境的影响[J]. 环境工程,2019,37(12):49-54.
[33]	杜聪,冯胜,张毅敏,等.微生物菌剂对黑臭水体水质改善及生物多样性修复效果研究[J].环境工程,2018,36(8):6-12.
[34]	于翔霏,程宪伟,祝惠,等.长春西湖沉积物氮、磷营养盐释放通量及原位覆盖控释效果模拟研究[J]. 湿地科学,2017,15(4):595-600.
[35]	孙峰,黄振芳,杨忠山,等. 北京市水生态监测评价方法构建及应用[J].中国环境监测,2017,33(2):82-87.
[36]	王冠,孔宇.沙坪河河道流域智慧水务建设方案研究[J]. 给水排水,2020,56(3):148-15.