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电催化臭氧技术降解啶虫脒

马永双,  展巨宏,  王会姣,  王玉珏

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文章导航 > 环境工程  > 2021 >  39(12): 107-113,187
马永双, 展巨宏, 王会姣, 王玉珏. 电催化臭氧技术降解啶虫脒[J]. 环境工程, 2021, 39(12): 107-113,187. doi: 10.13205/j.hjgc.202112016
引用本文: 马永双, 展巨宏, 王会姣, 王玉珏. 电催化臭氧技术降解啶虫脒[J]. 环境工程, 2021, 39(12): 107-113,187. doi: 10.13205/j.hjgc.202112016
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MA Yong-shuang, ZHAN Ju-hong, WANG Hui-jiao, WANG Yu-jue. STUDY ON ABATEMENT OF ACETAMIPRID BY ELECTRO-PEROXONE PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(12): 107-113,187. doi: 10.13205/j.hjgc.202112016
Citation: MA Yong-shuang, ZHAN Ju-hong, WANG Hui-jiao, WANG Yu-jue. STUDY ON ABATEMENT OF ACETAMIPRID BY ELECTRO-PEROXONE PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(12): 107-113,187. doi: 10.13205/j.hjgc.202112016
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电催化臭氧技术降解啶虫脒

doi: 10.13205/j.hjgc.202112016

  • 1. 清华大学 环境学院, 北京 100084;

  • 2. 苏州普滤得净化股份有限公司, 江苏 苏州 215129;

  • 3. 清华苏州环境创新研究院, 江苏 苏州 215163;

  • 4. 中国矿业大学(北京)化学与环境工程学院, 北京 100083

基金项目: 

国家水体污染控制与治理科技重大专项(2017ZX07202-001)。

详细信息
    作者简介:

    马永双(1996-),男,硕士,主要研究方向为电化学高级氧化技术。mys18@mails.tsinghua.edu.cn

    通讯作者:

    王玉珏(1975-),男,副教授,主要研究方向为水处理技术研究。wangyujue@tsinghua.edu.cn

STUDY ON ABATEMENT OF ACETAMIPRID BY ELECTRO-PEROXONE PROCESS

  • 1. School of Environment, Tsinghua University, Beijing 100084, China;

  • 2. Suzhou Purification Equipment Co., Ltd, Suzhou 215129, China;

  • 3. Research Institute for Environmental Innovation (Suzhou), Tsinghua University, Suzhou 215163, China;

  • 4. School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

摘要

    摘要
  • 摘要: 研究了臭氧氧化、紫外/臭氧(UV/O3)和电催化臭氧(electro-peroxone, EP)3种技术降解啶虫脒的机制,比较了3种技术降解地下水和地表水中啶虫脒的效率和能耗(使用EEO指标表征)。发现啶虫脒为臭氧难氧化物质,与臭氧(O3)和羟基自由基(·OH)的二级反应速率常数分别为(0.05±0.01) mol/(L·s)、(2.8±0.2)×109 mol/(L·s)。经6 min臭氧氧化后,地下水和地表水中的啶虫脒去除率仅为26%和64%。与之相比,UV/O3和EP技术可以完全去除地下水和地表水中的啶虫脒。臭氧氧化、UV/O3和EP技术降解啶虫脒的能耗分别为0.11~0.27,1.22~1.24,0.12~0.24 kW·h/m3。结果表明,EP技术是一种去除饮用水中啶虫脒的高效低耗技术。
    Abstract: The abatement kinetics and mechanism of acetamiprid were studied by ozonation, ultraviolet/ozone(UV/O3), and electro-peroxone(EP) in the groundwater and surface water. The electrical energy demands per order removal(EEO) of acetamiprid abatement by these processes were compared in two real water matrices. The second-order rate constants for the reaction of acetamiprid with ozone and hydroxyl radical(·OH) at pH of 7 were determined to be(0.05±0.01) mol/(L·s) and(2.8±0.2)×109 mol/(L·s), respectively. After 6 min ozone oxidation, the removal rates of acetamiprid in groundwater and surface water were only 26% and 64%. In contrast, UV/O3 and EP technology can completely remove acetamiprid from groundwater and surface water. The energy demands for 90% removal efficiency of acetamiprid were 0.11~0.27, 1.22~1.24, and 0.12~0.24 kW·h/m3 for ozonation, UV/O3, and EP processes, respectively. The results showed that the EP process was an energy-efficient alternative for the abatement of acetamiprid in water treatment.
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出版历程
  • 收稿日期:  2020-12-30
  • 网络出版日期:  2022-03-30
  • 刊出日期:  2022-03-30

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