活性黑KN-B在石墨烯表面的吸附行为

孙兆楠; 潘玉瑾; 冷杰雯; 王明秀; 杨薇; 张南

doi:10.13205/j.hjgc.202112017

活性黑KN-B在石墨烯表面的吸附行为

doi: 10.13205/j.hjgc.202112017

1. 辽宁省化学助剂合成与分离重点实验室营口理工学院, 辽宁营口 115014;
2. 营口市环境工程开发有限公司, 辽宁营口 115014

基金项目:

2019年营口理工学院优秀科技人才支持计划(RC201905)。

辽宁省化学助剂合成与分离重点实验室资助项目(ZJNK2014)

详细信息

作者简介:
孙兆楠(1986-),女,副教授,主要研究方向为有机废水处理。280728183@qq.com

通讯作者:
杨薇(1981-),女,讲师,博士后,主要研究方向为染料废水处理、微生物。316011917@qq.com

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- 文章访问数: 135
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- 被引次数: 0
出版历程
- 收稿日期: 2021-08-06
- 网络出版日期: 2022-03-30
- 刊出日期: 2022-03-30

ADSORPTION BEHAVIOR OF REACTIVE BLACK KN-B ON GRAPHENE SURFACE

1. Liaoning Key Laboratory of Chemical Additive Synthesis and Separation, Yingkou Institute of Technology, Yingkou 115014, China;
2. Yingkou Environment Project Development Co., Ltd, Yingkou 115014, China

摘要

摘要: 采用石墨烯作为吸附剂,以活性黑KN-B为目标污染物模拟染料废水,考察吸附法处理活性黑KN-B模拟染料废水的影响因素及活性黑KN-B在石墨烯表面的吸附行为。结果表明:在投加2 g/L石墨烯,pH值为5.0,振荡速率为100 r/min, 40 ℃恒温下振荡60 min,吸附处理50 mg/L活性黑KN-B染料废水50 mL,对活性黑KN-B的去除率可达到94%,且稳定可行。研究发现,可利用Langmuir吸附等温线和准二级动力学描述活性黑KN-B在石墨烯表面的吸附行为,即单分子层化学吸附。
- 吸附法 /
- 石墨烯 /
- 活性黑KN-B /
- 动力学 /
- 吸附机理
Abstract: Using graphene as the adsorbent, and reactive black KN-B as the target pollutant to simulate dye wastewater, the influencing factors of adsorption treatment of reactive black KN-B simulated dye wastewater and the adsorption behavior of reactive black KN-B on graphene surface were investigated. The results showed that under the optimum reaction condition of adding 2 g/L of graphene in 50 mL solution, pH value was 5.0, oscillating rate was 100 r/min, oscillating at 40 ℃ for 60 min, the removal rate of absorption 50 mg/L reactive black KN-B dye wastewater could reach 94%. It was found that Langmuir adsorption isotherm and quasi-second-order kinetics could be used to describe the adsorption behavior of reactive black KN-B on graphene surface, and then this course could be defined as monolayer chemisorption.
- adsorption method /
- graphene /
- reactive black KN-B /
- dynamics /
- adsorption mechanism

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参考文献(14)

[1]	何雪梅,冒海燕,蔡露.壳聚糖基杂化气凝胶对活性染料的吸附性能[J].纺织学报,2021,42(2):148-155.
[2]	曲艳萍,刘洪娇,于雯靖,等.氧化石墨烯/贝壳粉复合材料的制备及其对刚果红吸附性能的研究[J].化工新型材料,2020,48(8):281-285.
[3]	NGUYEN T T,CHEN H H,TO Thi Hien,et al.Development of biochars derived from water bamboo (Zizania latifolia) shoot husks using pyrolysis and ultrasound-assisted pyrolysis for the treatment of Reactive Black 5 (RB5) in wastewater[J].Water,2021,13(12):1615.
[4]	JÓZ'WIAK T,FILIPKOWSKA U.The use of air-lift adsorber with a floating filling from a cross-linked chitosan hydrogels for Reactive Black 5 removal[J].Scientific Reports,2021,11(1):13382.
[5]	涂盛辉,熊超华,林立,等.Cu/Mn/La/MCM-41分子筛降解染料废水的性能研究[J].功能材料,2021,52(7):7064-7071.
[6]	赵芳玉,胡筱敏,郭鹏瑶.焙烧条件对热聚合法制备石墨相氮化碳光催化性能的影响及其机理[J].环境工程,2021,39(5):55-60.
[7]	李丹丹,姚广铮,梁桂琰,等.氧化石墨烯复合二氧化钛光催化剂的制备及模拟染料废水处理[J].材料工程,2019,47(12):104-110.
[8]	GEIM A K,NOVOSELOV K S.The rise of graphene[J].Nature Materials,2007,6:183-191.
[9]	DREYER D R,RUOFF R S,BIELAWSKI C W.From conception to realization:an historial account of graphene and some perspectives for its future[J].Angewandte Chemie International Ed.in English,2010,49(49):9336-9344.
[10]	WANG C,LI H,LIAO S H,et al.Coadsorption,desorption hysteresis and sorption thermodynamics of sulfamethoxazole and carbamazepine on graphene oxide and graphite[J].Carbon,2013,65:243-251.
[11]	UPADHYAY R K,SOIN N,ROY S S.Role of graphene/metal oxide composites as photocatalysts,adsorbents and disinfectants in water treatment:a review[J].RSC Advances,2014,4:3823-3851.
[12]	KONICKI W,ALEKSANDRZAK M,MOSZYN'SKI D,et al.Adsorption of anionic Azo-Dyes from aqueous solutions onto graphene oxide:equilibrium,kinetic and thermodynamic studies[J].Journal of Colloid and Interface Science,2017,496:188-200.
[13]	ROBATI D,MIRZA B,RAJABI M,et al.Removal of hazardous dyes-BR12 and methyl orange using graphene oxide as an adsorbent from aqueous phase[J].Chemical Engineering Journal,2016,284:687-697.
[14]	王永娟,龙雨,郑怀礼,等.磁性石墨烯基纳米材料吸附水中污染物的研究进展[J].水处理技术,2021,47(5):11-17.