RESEARCH PROGRESS OF APPLICATION OF MATERIALS WITH PHOTOCATALYTIC MEMORY IN FIELD OF ENVIRONMENT
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摘要: 光催化技术作为一种新兴的高效可持续技术,在环境领域具有广泛的应用前景。然而,多数光催化材料在失去外界光源的能量供应后,短时间内不再产生电子空穴对,从而迅速丧失催化反应活性。但光催化记忆材料具有独特的催化记忆效应,即在黑暗条件下仍可表现出一定的催化活性,进而克服了以上难题。主要概述了光催化记忆材料的基本工作原理,将现有的光催化记忆材料归类,并总结了光催化记忆材料在环境领域的主要应用方向,包括新能源的生产、难降解有机污染物的氧化去除、重金属污染物的还原去除及病原微生物的灭活,最后展望了光催化记忆材料的发展前景。Abstract: Photocatalytic technology, as an emergingly efficient and sustainable technology, has broad application prospect in the environmental field. However, most photocatalytic materials will not generate electron-hole pairs in a short period of time without the energy supply of the external light source, and thus rapidly lose the catalytic activity. Photocatalytic memory materials have a unique ability, named as catalytic memory effect, to maintain catalytic performance under dark environments for overcoming the above challenges. This review article mainly outlined the basic principles of photocatalytic memory materials, classified the existing photocatalytic memory materials, summarized the application of photocatalytic memory materials in the environmental field, including the production of energy sources and the oxidation of refractory organics, the reduction of heavy metal and the inactivation of pathogenic microorganisms, and prospected for the future development of photocatalytic memory materials.
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[1] 卢晓兰.浅谈水污染及治理技术[J].技术与市场,2014,23(9):20-22. [2] 雷春生,朱晓锋,高雯,等.复配表面活性剂协同促进氨氮吹脱效能研究[J].中国给水排水,2016,32(5):77-80. [3] 吕伯宇,李思凡,商丽艳.生物法处理工业废水的研究进展[J].当代化工,2014,43(3):432-434. [4] LI Q,LI Y W,WU P G,et al.Palladium oxide nanoparticles on nitrogen-doped titanium oxide:accelerated photocatalytic disinfection and post-illumination catalytic “memory”[J].Advanced Materrials,2008,20(19):3717-3723. [5] LI Q,LI Y W,LIU Z Q,et al.Memory antibacterial effect from photoelectron transfer between nanoparticles and visible light photocatalyst[J].Material Chemistry,2010,20(6):1068-1072. [6] TATSUMA T,SAITOH S,OHKO Y,et al.TiO2-WO3 photoelectrochemical anticorrosion system with an energy storage ability[J].Chemical Materials,2001,13(9):2838-2842. [7] TATSUMA T,SAITOH S,NGAOTRAKANWIWAT P,et al.Energy storage of TiO2-WO3 photocatalysis systems in the gas phase[J].Langmuir,2002,18(21):7777-7779. [8] 朱红庆,杨兵,魏世强,等.微米SiC/石墨烯复合物光催化降解罗丹明B[J].环境科学,2020,41(2):756-762. [9] TAKAHASHI Y,TATSUMA T.Oxidative energy storage ability of a TiO2-Ni(OH)2 bilayer photocatalyst[J].Langmuir,2005,21(26):12357-12361. [10] HUANG H,JIANG L,ZHANG W K,et al.Photoelectrochromic properties and energy storage of TiO2-xNx/NiO bilayer thin films[J].Solar Energy Materials and Solar Cells,2010,94(2):355-359. [11] NG C,NG Y H,IWASE A,et al.Visible light-induced charge storage,on-demand release and self-photorechargeability of WO3 film[J].Physical Chemistry Chemical Physic,2011,13(29):13421-13426. [12] PARK H,BAK A,JEON T H,et al.Photo chargeable and dischargeable TiO2 and WO3 heterojunction electrodes[J].Applied Catalysis B:Environmental,2012,115/116:74-80. [13] LIU L M,YANG W Y,LI Q,et al.Synthesis of Cu2O nanospheres decorated with TiO2 nanoislands,their enhanced photoactivity and stability under visible light illumination,and their post-illumination catalytic memory[J].ACS Applied Materials & Interfaces,2014,6(8):5629-5639. [14] LIU L M,SUN W Z,YANG W Y,et al.Post-illumination activity of SnO2 nanoparticle-decorated Cu2O nanocubes by H2O2 production in dark from photocatalytic “memory”[J].Scientific Reports,2016,6(1):20878. [15] LIN H,DENG W H,ZHOU T H,et al.Iodine-modified nanocrystalline titania for photo-catalytic antibacterial application under visible light illumination[J].Applied Catalysis B:Environmental,2015,176/177:36-43. [16] 蒋悦,贾漫珂,邹彩琼,等.碘掺杂TiO2可见光光催化性能研究[J].环境工程学报,2013,7(3):975-980. [17] DONG F,XIONG T,SUN Y J,et al.A semimetal bismuth element as a direct plasmonic photocatalyst[J].Chemical Communications,2014,50(72):10386-10389. [18] CHIOU Y D,HSU Y J.Room-temperature synthesis of single-crystalline Se nanorods with remarkable photocatalytic properties[J].Applied Catalysis B:Environmental,2011,105(1/2):211-219. [19] LAU V W H,KLOSE D,KASAP H,et al.Dark photocatalysis:storage of solar energy in carbon nitride for time-delayed hydrogen generation[J].Angewandte Chemie International Edition,2017,56(2):510-514. [20] 张金水,王博,王心晨,等.氮化碳聚合物半导体光催化[J].化学进展,2016,26(1):19-29. [21] WANG C T,HUANG H H.Photo-chargeable titanium/vanadium oxide composites[J].Non-Crystalline Solids,2008,354(28):3336-3342. [22] YASOMANEE J P,BANDARA J.Multi-electron storage of photoenergy using Cu2O-TiO2 thin film photocatalyst[J].Solar Energy Materials and Solar Cells,2008,92(3):348-352. [23] NGUYEN C C,VU N O,DO T O.Efficient hollow double-shell photocatalysts for the degradation of organic pollutants under visible light and in darkness[J].Materials Chemistry A,2016,4(12):4413-4419. [24] ZHANG Q,WANG H,LI Z L,et al.Metal-free photocatalyst with visible-light-driven post-illumination catalytic memory[J].ACS Applied Materials & Interfaces,2017,9(26):21738-21746. [25] LI L N,LIU Z S,GUO L T,et al.NaBiO3/BiO2-x composite photocatalysts with post-illumination “memory” activity[J].Materials Letters,2018,234(1):30-34. [26] 李静,吉庆华,兰华春,等.ZnTiO3-TiO2复合光催化剂的制备及光催化降解有机污染物机制分析[J].环境科学,2019,40(2):693-700. [27] TAKAHASHI Y,TATSUMA T.Remote energy storage in Ni(OH)2 with TiO2 photocatalyst[J].Physical Chemistry Chemical Physics,2006,8(23):2716-2719. [28] LI J,LIU Y,ZHU Z J,et al.A full-sunlight-driven photocatalyst with super long-persistent energy storage ability[J].Scientific Reports,2013,3:2409. [29] LI Y T,ZHANG J M,LI H W,et al.Highly stable dispersibility in water induced by surface hydration force of TiO2 nanocrystalline mixtures during phase transformation[J].Dispersion Science and Technology,2010,31(2):260-263. [30] EL-SHESHTAWY H S,EL-HOSAINY H M,SHOUEIR K R,et al.Facile immobilization of Ag nanoparticles on g-C3N4/V2O5 surface for enhancement of post-illumination,catalytic,and photocatalytic activity removal of organic and inorganic pollutants[J].Applied Surface Science,2019,467/468:268-276. [31] ZHAO D,CHEN C C,YU C L,et al.Photoinduced electron storage in WO3/TiO2 nanohybrid material in the presence of oxygen and postirradiated reduction of heavy metal ions[J].Physical Chemistry C,2009,113(30):13160-13165. [32] XING Z,ZENG X K,DELETIC A,et al.Constructing ultrathin film with “memory” photocatalytic activity from monolayered tungstate nanodots[J].Chemical Communications,2016,52(43):6985-6988. [33] PARK S,KIM W,SELVARAJ R,et al.Spontaneous reduction of Cr(Ⅵ) using InSnS2 under dark condition[J].Chemical Engineering Journal,2017,321:97-104. [34] WANG G,XING Z,ZENG X K,et al.Ultrathin titanium oxide nanosheets films with memory bactericidal activity[J].Nanoscale,2016,8(42):18050-18056. [35] TATSUMA T,TAKEDA S,SAITOH S,et al.Bactericidal effect of an energy storage TiO2-WO3 photocatalyst in dark[J].Electrochemistry Communications,2003,5(9):793-796.
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