制革行业土壤铬污染特征及其影响因素

金晓丹; 田永强; 吴昊; 陈何潇; 王兴润; 程金平

doi:10.13205/j.hjgc.202112031

制革行业土壤铬污染特征及其影响因素

doi: 10.13205/j.hjgc.202112031

金晓丹^1,2,3,
田永强⁴,
吴昊²,
陈何潇²,
王兴润⁵,
程金平^1, ,

1. 上海交通大学中国城市治理研究院, 上海 200030;
2. 广西壮族自治区环境保护科学研究院, 南宁 530022;
3. 上海交通大学国际与公共管理学院, 上海 200030;
4. 四川大学, 成都 610065;
5. 中国环境科学研究院, 北京 100012

基金项目:

上海交通大学中国城市治理研究院“城市治理与大数据”专项重点课题资助(SJTU-2019UGBD-01)。

科技计划项目“场地土壤污染成因与治理技术”(2018YFC1802201-01)

详细信息

作者简介:
金晓丹(1983-),女,博士,高级工程师,主要研究方向为土壤重金属污染治理。jinxiaodan0773@163.com

通讯作者:
程金平,男,教授,主要研究方向为环境化学。jpcheng@sjtu.edu.cn

计量
- 文章访问数: 249
- HTML全文浏览量: 65
- PDF下载量: 2
- 被引次数: 0
出版历程
- 收稿日期: 2020-02-19
- 网络出版日期: 2022-03-30
- 刊出日期: 2022-03-30

CHARACTERISTICS OF CHROMIUM POLLUTION AND ITS INFLUENCING FACTORS IN LEATHER INDUSTRY

1. China Institute for Urban Governance, Shanghai Jiaotong University, Shanghai 200030, China;
2. Environmental Protection Research Institute of Guangxi, Nanning 530022, China;
3. School of International and Public Affairs, Shanghai Jiaotong University, Shanghai 200030, China;
4. Sichuan University, Chengdu 610065, China;
5. Chinese Research Academy of Environmental Sciences, Beijing 100012,China

摘要

摘要: 为了解制革场地土壤Cr(Ⅵ)污染情况和分布特征,选取我国3种典型制革企业用地的土壤和污泥样品,分析了制革行业土壤铬污染特征。结果表明:调查的Ⅰ型制革企业场地土壤Cr(Ⅵ)含量最高为48 mg/kg,超过GB 36600—2018《土壤环境质量建设用地土壤污染风险管控标准(试行)》筛选值,存在环境风险。调查的Ⅱ型制革企业环保设施完善,场地土壤Cr(Ⅵ)含量低于GB 36600—2018筛选值,土壤Cr(Ⅵ)环境风险低。Ⅱ型制革企业危险废物暂存间污泥总铬含量高达85377 mg/kg, Cr(Ⅵ)含量最高为1455 mg/kg。调查的Ⅲ型制革企业场地泥土混合物总铬含量为1564~28000 mg/kg, Cr(Ⅵ)含量最高为250 mg/kg,相较于Ⅰ型和Ⅱ型制革企业场地,受到严重污染。总体上,制革企业用地土壤铬污染物以Cr(Ⅲ)形态为主,Cr(Ⅵ)形态占比少,不足1%。
- 制革行业场地 /
- 土壤 /
- 污泥 /
- 六价铬 /
- 管理
Abstract: In order to understand the soil Cr(Ⅵ) pollution and distribution characteristics in the sludge and soil of tanning site, soil and sludge samples of three typical site in China were selected to analyze the soil Cr(Ⅵ) pollution characteristics of tanning industry. The results showed that the highest content of soil Cr(Ⅵ) in the investigated type Ⅰ tanning enterprise's site was 48 mg/kg, which exceeded the screening value of the standard of soil pollution risk control for construction land(GB 36600—2018). There was pollution and environmental risk in Cr(Ⅵ). The investigated type Ⅱ tanning enterprise's site had complete environmental protection facilities, and the content of soil Cr(Ⅵ) was generally low, lower than the screening value of GB 36600—2018, with a lower environmental risk. The total chromium content of sludge in the temporary storage room of hazardous waste in type Ⅱ tanning enterprises' s site was as high as 85377 mg/kg, and the highest Cr(Ⅵ) content was 1455 mg/kg. The total chromium content of soil mixture in type Ⅲ tanning enterprise's site investigated ranged from 1564 to 28000 mg/kg, and the highest Cr(Ⅵ) content was 250 mg/kg. Compared with type Ⅰ and type Ⅱ tanning sites, it was seriously polluted. In general, Cr(Ⅲ) was the main form of soil chromium in tanning sites, and Cr(Ⅵ) accounted for less than 1%.
- tanning site /
- soil /
- sludge /
- Cr(Ⅵ) /
- management

HTML全文

参考文献(28)

[1]	周林艳,曾丽璇,李晨.皮革行业实施清洁生产途径的可持续发展研究[J].生态经济,2012(4):122-126.
[2]	RELIGA P,KOWALIK A,GIERYCZ P.Application of nanofiltration for chromium concentration in the tannery wastewater[J].Journal of Hazardous Materials,2011,186(1):288-292.
[3]	BRINDHA K,ELANGO L.SHINWARI.Impact of tanning industries on groundwater quality near a metropolitan city in india[J].Water Resour Manage,2012(26):1747-1761.
[4]	王宇峰,刘磊,汪俊玉,等.典型制革企业退役场地污染特征研究[J].中国资源综合利用,2019,37(6):153-155.
[5]	CHEN H,AROCENA J M,LI J,et al.Mobility and storage sinks for chromium and other metals in soils impacted by leather tannery wastes[J].Journal of Environmental Monitoring,2012,14(12):3240-3248.
[6]	孔祥科,黄国鑫,韩占涛,等.制革污泥堆存场地典型土壤剖面中污染物的垂向分布特征[J].南水北调与水利科技,2017,15(6):96-100.
[7]	BINI C,MALECI L,ROMANIN A.The chromium issue in soils of the leather tannery district in Italy[J].Journal of Geochemical Exploration,2008,96(2/3):194-202.
[8]	GOWD S S,REDDY M R,GOVIL P K.Assessment of heavy metal contamination in soils at Jajmau (Kanpur) and Unnao industrial areas of the Ganga Plain,Uttar Pradesh,India[J].Journal of Hazardous Materials,2010,174(1/2/3):113-121.
[9]	ALI Z,MALIK R N,SHINWARI Z K,et al.Enrichment,risk assessment,and statistical apportionment of heavy metals in tannery-affected areas[J].International Journal of Environmental Science and Technology,2015,12 (2):537-550.
[10]	SAADIA R T,MUNIR H S,SHAHEEN N,et al.Multivariate analysis of trace metal levels in tannery effluents in relation to soil and water:a case study from Peshawar,Pakistan[J].Journal of Environmental Management,2006,79 (1):20-29.
[11]	MAKDISI R S.Tannery wastes definition,risk assessment and cleanup options,Berkeley,California[J].Journal of Hazardous Materials,1991,29 (1):79-96.
[12]	TARCAN G,AKINCI G,DANIŞMAN M A.Assessment of the pollution from tannery effluents upon waters and soils in and around Kula vicinity,Turkey[J].Water,Air,& Soil Pollution,2010,213(1/2/3/4):199-210.
[13]	BINI C,MALECI L,ROMANIN A.The chromium issue in soils of the leather tannery district in Italy[J].Journal of Geochemical Exploration,2008,96 (2/3):194-202.
[14]	SHI J J,CHEN H L,JOSELITO M,et al.Elemental sulfur amendment decreases bio-available Cr-Ⅵ in soils impacted by leather tanneries[J].Environmental Pollution,2016,212:57-64.
[15]	李健康.江门市制革行业固体废物处理处置出路探讨[J].资源节约与环保,2019(5):87-88.
[16]	MEGHARAJ M,AVUDAINAYAGAM S,NAIDU R.Toxicity of hexavalent chromium and its reduction by bacteria isolated from soil contaminated with tannery waste[J].Current Microbiology,2003,47(1):51-54.
[17]	SINGH R,MISRA V,SINGH R P.Removal of Cr(Ⅵ) by nanoscale zero-valent iron (nZVI) from soil contaminated with tannery wastes[J].Bulletin of Environmental Contamination and Toxicology,2012,88(2):210-214.
[18]	ZEESHANUR R,VED P S.Cr(Ⅵ) reduction by Enterobacter sp.DU17 isolated from the tannery waste dump site and characterization of the bacterium and the Cr(Ⅵ) reductase[J].International Biodeterioration & Biodegradation,2014,91:97-103.
[19]	SCOTT E.Fendorf.Surface reactions of chromium in soils and waters[J].Geoderma,1995,67(1):55-71.
[20]	AJOUYED O,HUREL C,AMMARI M,et al.Sorption of Cr(Ⅵ) onto natural iron and aluminum (oxy)hydroxides:effects of pH,ionic strength and initial concentration[J].Journal of Hazardous Materials,2010,174(1/2/3):616-622.
[21]	JOHNSTON C P,CHRYSOCHOOU M.Mechanisms of chromate adsorption on boehmite[J].Journal of Hazardous Materials,2015,281:56-63.
[22]	APTE A D,VERMA S,TARE V,et al.Oxidation of Cr(Ⅲ) in tannery sludge to Cr(Ⅵ):field observations and theoretical assessment[J].Journal of Hazardous Materials,2005,121(1/2/3):215-222.
[23]	MARIA C DIMITRIS D,DENNIS G G,et al.Importance of mineralogy in the geoenvironmental characterization and treatment of chromite ore processing residue,2010,136(3):510-521.
[24]	CHEN H L,AROCENA J M,LI J B,et al.Mobility and storage sinks for chromium and other metals in soils impacted by leather tannery wastes[J].Journal of Environmental Monitoring:JEM,2012,14(12):3240-3248.
[25]	杨斌,张刚,李欲如,等.浙江省制革和电镀行业铬污染现状调研及治理对策[J].中国给水排水,2016,32(8):22-28.
[26]	XU T,NAN F,JIANG X F,et al.Effect of soil pH on the transport,fractionation,and oxidation of chromium (Ⅲ)[J].Ecotoxicology and Environmental Safety,2020,195:110459.
[27]	MONDAL N C,SINGH V P.Hydrochemical analysis of salinization for a tannery belt in Southern India[J].Journal of Hydrology,2014,5:235-247.
[28]	ANDREA E,ANNA M,MAURIZIO B.Chromium in Agricultural Soils and Crops:A Review[J].Water Air Soil Pollut,2017,228:190.