淋土式介质阻挡放电等离子体修复阿特拉津污染土壤

于政; 李杰; 姜楠; 刘政妍; 彭邦发; 吴彦

doi:10.13205/j.hjgc.202112032

淋土式介质阻挡放电等离子体修复阿特拉津污染土壤

doi: 10.13205/j.hjgc.202112032

于政¹,
李杰^2, ,,
姜楠²,
刘政妍¹,
彭邦发²,
吴彦²

1. 大连理工大学环境学院, 大连 116024;
2. 大连理工大学电气工程学院, 大连 116024

基金项目:

中央高校基本科研业务费资助(DUT20ZD202)。

详细信息

作者简介:
于政(1995-),男,硕士研究生。研究方向为低温等离子体土壤修复。978213877@qq.com

通讯作者:
李杰。lijie@dlut.edu.cn

计量
- 文章访问数: 114
- HTML全文浏览量: 21
- PDF下载量: 1
- 被引次数: 0
出版历程
- 收稿日期: 2020-08-18
- 网络出版日期: 2022-03-30
- 刊出日期: 2022-03-30

REMEDIATION OF ATRAZINE CONTAMINATED SOIL BY DIELECTRIC BARRIER DISCHARGE PLASMA WITH SOIL SPRINKLE MODE

1. School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China;
2. Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian 116024, China

摘要

摘要: 介绍了淋土式介质阻挡放电等离子体修复阿特拉津污染土壤的方法,探究了土壤特性及等离子体发生参数对阿特拉津降解效果的影响并对中间产物进行检测与分析。结果表明:增加电压和频率有利于提高阿特拉津降解率,降低能量效率;增加初始浓度会导致降解率下降,能量效率上升;而增加土壤粒径或降低pH则导致降解率和能量效率下降;含水率增加使得降解率和能量效率先增后减。在峰-峰值36 kV,电源频率为200 Hz, pH=7.03条件下,60~80目的10 mg/kg阿特拉津污染干土经过50 s放电后阿特拉津降解率为70.95%,能量效率为0.014 mg/kJ。利用液相色谱质谱联用对中间产物进行测定,发现产物主要为脱烷基、脱氯和酮或醛等类阿特拉津产物,未检测到低聚物的生成。由于低温等离子体在土壤颗粒周围产生,使得臭氧和·OH等短寿命活性物种共同参与污染物降解过程,使得反应器降解效果得到增强。
- 低温等离子体 /
- 介质阻挡放电 /
- 土壤修复 /
- 淋土式 /
- 阿特拉津
Abstract: A method that the pouring soil into the plasma of dielectric barrier discharge(DBD) to efficiently degrade atrazine in the soil was studied. The effects of soil characteristics and plasma generation parameters on atrazine degradation were investigated and the degradation intermediates were detected and analyzed. The experiment results showed that increasing voltage and frequency could improve the degradation efficiency of atrazine and reduce the energy efficiency. The increase of initial concentration would lead to the decrease of degradation efficiency and the increase of energy efficiency. The degradation efficiency and energy efficiency were decreased when soil particle size increased or pH decreased. As water content increased, degradation efficiency and energy efficiency first increased and then decreased. Under the conditions of peak-peak 36 kV, 200 Hz, and pH of 7.03, the degradation efficiency and energy efficiency of 10 mg/kg polluted dry soil with particle size of 60~80 were 70.95% and 0.014 mg/kJ after discharge treatment for 50 s. Through liquid chromatography-mass spectrometry, the intermediate products were tested to be atrazine-like substances such as dealkylation, dechlorination and ketone or aldehyde without any oligomer. As non-thermal plasma was generated around the soil particles, ozone and the short-lived active species, such as ·OH, jointly participated in the pollutant degradation process, resulting in enhanced reactor degradation effect.
- non-thermal plasma /
- dielectric barrier discharge /
- soil remediation /
- sprinkle mode /
- atrazine

HTML全文

参考文献(35)

[1]	YUE L,GE C J,FENG D,et al.Adsorption-desorption behavior of atrazine on agricultural soils in China[J].Journal of Environmental Science,2017,57:180-189.
[2]	UDIKOVIC-KOLIC N,SCOTT C,MARTIN-LAURENT F.Evolution of atrazine-degrading capabilities in the environment[J].Applied Microbiology and Biotechnology,2012,96(5):1175-1189.
[3]	MUELLER T C,PARKER E T,STECKEL L,et al.Enhanced atrazine degradation is widespread across the United States[J].Pest Management Science,2017,73(9):1953-1961.
[4]	ALMBERG K S,TURYK M E,JONES R M,et al.Atrazine contamination of drinking water and adverse birth outcomes in community water systems with elevated atrazine in ohio,2006—2008[J].Internation Journal of Environmental Research and Public Health,2018,15(9).
[5]	曹梦华,涂书新,张娥,等.抗坏血酸还原降解土壤中的阿特拉津[J].环境工程,2019,37(12):207-211.
[6]	SUN J,MA X L,WANG W,et al.The adsorption behavior of atrazine in common soils in northeast china[J].Bulletin of Environmental Contamination and Toxicology,2019,103(2):316-322.
[7]	BONTEMPO A F,CARNEIRO G D,GUIMARAES F A,et al.Residual tembotrione and atrazine in carrot[J].Journal of Environmental Science and Health.Part.B,2016,51(7):465-468.
[8]	HAYES T B,COLLINS A,LEE M,et al.Hermaphroditic,demasculinized frogs after exposure to the herbicide atrazine at low ecologically relevant doses[J].Proceedings of the National Academy of Sciences of the United States of America,2002,99(8):5476-5480.
[9]	张馨元.可溶性有机质(DOM)对黑土吸附阿特拉津行为影响与机理分析[J].哈尔滨:东北农业大学,2019.
[10]	CHENG M,ZENG G M,HUANG D L,et al.Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds:a review[J].Chemical Engineering Journal,2016,284:582-598.
[11]	WANG T C,QU G Z,LI J,et al.Remediation of p-nitrophenol and pentachlorophenol mixtures contaminated soil using pulsed corona discharge plasma[J].Separation and Purification Technology,2014,122:17-23.
[12]	WANG T C,LU N,LI J,et al.Degradation of pentachlorophenol in soil by pulsed corona discharge plasma[J].Journal of Hazardous Materials,2010,180(1/2/3):436-441.
[13]	WANG T C,LU N,LI J,et al.Evaluation of the potential of pentachlorophenol degradation in soil by pulsed corona discharge plasma from soil characteristics[J].Environmental Science & Technology,2010,44(8):3105-3110.
[14]	WANG C H,ZHANG X,WANG T C,et al.Role of energy input model on the remediation of the p-Nitrophenol contaminated over-wet soil by pulsed corona discharge plasma[J].Journal of Physics Conference Series,2013:418.
[15]	ZHAN J X,LIU Y N,CHENG W Y,et al.Remediation of soil contaminated by fluorene using needle-plate pulsed corona discharge plasma[J].Chemical Engineering Journal,2018,334:2124-2133.
[16]	LOU J,LU N,LI J,et al.Remediation of chloramphenicol-contaminated soil by atmospheric pressure dielectric barrier discharge[J].Chemical Engineering Journal,2012,180:99-105.
[17]	AGGELOPOULOS C A,TSAKIROGLOU C D,OGNIER S,et al.Non-aqueous phase liquid-contaminated soil remediation by ex situ dielectric barrier discharge plasma[J].International Journal of Environmental Science and Technology,2015,12(3):1011-1020.
[18]	ZHANG H,MA D Y,QIU R L,et al.Non-thermal plasma technology for organic contaminated soil remediation:a review[J].Chemical Engineering Journal,2017,313:157-170.
[19]	牟睿文.介质阻挡放电与脉冲电晕放电等离子体修复多环芳烃污染土壤的研究[D].上海:东华大学,2016.
[20]	ZHAN J X,ZHANG A,HÉROUX P,et al.Gasoline degradation and nitrogen fixation in soil by pulsed corona discharge plasma[J].Science of the Total Environment,2019,661:266-275.
[21]	ZHAN J X,ZHANG A,HÉROUX P,et al.Remediation of perfluorooctanoic acid (PFOA) polluted soil using pulsed corona discharge plasma[J].Journal of Hazardous Materials,2020,387:121688.
[22]	WANG T C,QU G Z,LI J,et al.Depth dependence of pnitrophenol removal in soil by pulsed discharge plasma[J].Chemical Engineering Journal,2014,239:178-184.
[23]	WANG T C,QU G Z,LI J,et al.Evaluation and optimization of multi-channel pulsed discharge plasma system for soil remediation[J].Vacuum,2014,103:72-77.
[24]	DAYFIELD D,FIORIDO C,LAMBERT K,et al.Development and validation of a method using QuEChERS and liquid chromatography-mass spectrometry for atrazine determination[J].Abstracts of Papers of the American Chemical Society,2018,255.
[25]	王铁成.场地有机物污染土壤的脉冲放电等离子体修复方法和机理研究[D].大连:大连理工大学,2013.
[26]	ELIASSON B,KOGELSCHATZ U.Modeling and applications of silent discharge plasmas[J].IEEE Transactions on Plasma Science,1991,19(2):309-323.
[27]	ELIASION B,EGLI W,KOGELSCHATZ U.Modelling of dielectric barrier discharge chemistry[J].Pure and Applied Chemistry,2013,66(6):1275-1286.
[28]	ACERO J.L,STEMMLER K,VON GUNTEN U.Degradation kinetics of atrazine and its degradation products with ozone and OH radicals:a predictive tool for drinking water treatment[J].Environmental Science & Technology,2000,34(4):591-597.
[29]	MU R W,LIU Y N,LI R,et al.Remediation of pyrenecontaminated soil by active species generated from flat-plate dielectric barrier discharge[J].Chemical Engineering Journal,2016,296:356-365.
[30]	李蕊.有机污染土壤的低温等离子体修复方法及机理研究[D].上海:东华大学,2017.
[31]	WANG Z H,SHEN D K,SHEN F,et al.Phosphate adsorption on lanthanum loaded biochar[J].Chemosphere,2016,150:1-7.
[32]	WANG T C,QU G Z,SUN Q H,et al.Formation and roles of hydrogen peroxide during soil remediation by direct multi-channel pulsed corona discharge in soil[J].Separation and Purification Technology,2015,147:17-23.
[33]	SOLOMON K R,GIESY J P,LAPOINT T W,et al.Ecological risk assessment of atrazine in North American surface waters[J].Environmental Toxicology and Chemistry,2013,32(1):10-11.
[34]	黄凤莲,邹璇,陈灿,等.亚铁活化次氯酸钠降解土壤中阿特拉津的研究[J].环境工程,2021,39(2):160-165 ,172.
[35]	AGGELOPOULOS C A,TATARAKI D,RASSIAS G.Degradation of atrazine in soil by dielectric barrier discharge plasma-Potential singlet oxygen mediation[J].Chemical Engineering Journal,2018,347:682-694.