SPATIAL DISTRIBUTION CHARACTERISTICS AND POLLUTION ASSESSMENT OF NITROGEN, PHOSPHORUS AND HEAVY METAL IN SURFACE SEDIMENTS OF HEAVILY POLLUTED TRIBUTARIES OF SHAHE RIVER BASIN
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摘要: 为探明东江支流沙河流域重污染支流表层沉积物氮、磷及重金属风险分布规律,采用不同风险等级评价法进行分析。综合污染指数分析显示,TN风险等级分为重度污染、中度污染、轻度污染、清洁,占比分别为57.1%、14.3%、16.1%、12.5%,TP占比分别为62.5%、10.7%、21.4%、5.4%。重金属Cr、Ni、Cu、Zn、Cd、Pb、Hg平均浓度分别超对应广东省背景值的5.52,7.43,15.88,6.70,8.10,1.34,1.12倍,相关性分析与主成分分析法推测Cr、Ni、Cu、Zn、Cd、Pb主要来自造纸、电镀行业;Hg来自电池或金属制造业;As含量不超标,主要来自农药及化肥;地积累指数法显示Cu、Ni以及Cr污染严重,潜在生态危害指数法显示Cd与Cu是主要生态危害贡献因子。研究结果可为饮用水源型河流水质安全保障提供决策支持。Abstract: In order to find out the risk distribution of nitrogen, phosphorus and heavy metals in the surface sediments of the heavily polluted tributaries in Shahe basin, a tributary of Dongjiang River, different risk assessment methods were used. The comprehensive pollution index analysis showed that TN risk levels of heavy pollution, moderate pollution, light pollution and clean accounted for 57.1%, 14.3%, 16.1% and 12.5%, respectively, while the TP risk levels of heavy pollution, moderate pollution, light pollution and clean level accounted for 62.5%, 10.7%, 21.4% and 5.4%, respectively. The average concentrations of Cr, Ni, Cu, Zn, Cd, Pb and Hg were 5.52, 7.43, 15.88, 6.70, 8.10, 1.34 and 1.12 times higher than the background values of heavy metals in Guangdong Province, respectively. Correlation analysis and principal component analysis suggested that Cr, Ni, Cu, Zn, Cd and Pb mainly came from papermaking and electroplating industries; Hg mainly came from battery or metal manufacturing industries; As did not exceed the standard, mainly came from pesticides and fertilizers; the geoaccumulation index showed that Cu, Ni and Cr were seriously polluted; the potential ecological hazard index showed that Cd and Cu were the main ecological hazard contributing factors. The results could provide decision support for water quality security of rivers as drinking water sources.
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Key words:
- Shahe basin /
- sediments /
- nitrogen and phosphorus /
- heavy metals /
- risk assessment methods
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[1] 李照全,方平,黄博,等.洞庭湖区典型内湖表层沉积物中氮、磷和重金属空间分布与污染风险评价[J].环境科学研究,2020,33(6):1409-1420. [2] 熊春晖,张瑞雷,吴晓东,等.滆湖表层沉积物营养盐和重金属分布及污染评价[J].环境科学,2016,37(3):925-934. [3] 蒋豫,吴召仕,赵中华,等.阳澄湖表层沉积物中氮磷及重金属的空间分布特征及污染评价[J].环境科学研究,2016,29(11):1590-1599. [4] 郭掌珍,张渊,李维宏,等.汾河表层底泥中营养盐和重金属的含量、来源、生态风险[J].水土保持学报,2013,27(3):95-99. [5] MEMET V.Assessment of heavy metal contamination in sediments of the Tigris River(Turkey) using pollution indices and multivariate statistical techniques[J].Journal of Hazardous Materials,2011,195:355-364. [6] 国家环境保护总局.土壤环境监测技术规范:HJ/T166—2004[S]. [7] 国家林业局.森林土壤氮的测定:LY/T 1228—2015[S]. [8] 环境保护部.土壤总磷的测定碱熔-钼锑抗分光光度法:HJ 632—2011[S]. [9] 环境保护部.水质65种元素的测定电感耦合等离子体质谱法:HJ 700—2014[S]. [10] 国家标准化管理委员会,国家质量监督检验检疫总局.土壤质量总汞、总砷、总铅的测定原子荧光法第1部分:土壤中总汞的测定:GB/T 22105.1—2008[S]. [11] 王佩,卢少勇,王殿武,等.太湖湖滨带底泥氮、磷、有机质分布与污染评价[J].中国环境科学,2012,32(4):703-709. [12] LI W J,LIN S,WANG W C,et al.Assessment of nutrient and heavy metal contamination in surface sediments of the Xiashan stream,eastern Guangdong Province,China[J].Environmental Science and Pollution Research,2020,27:25908-25924. [13] 王丽,陈凡,马千里,等.东江淡水河流域地表水和沉积物重金属污染特征及风险评价[J].环境化学,2015,34(9):1671-1684. [14] 王贺年,张曼胤,郭子良,等.衡水湖底泥中7 种重金属元素含量的分布及其潜在生态风险评价[J].湿地科学,2020,18(2):191-199. [15] 许炼烽,邓绍龙,陈继鑫,等.河流底泥污染及其控制与修复[J].生态环境学报,2014,23(10):1708-1715. [16] 惠州市生态环境局博罗分局.沙河流域水环境精准治理与达标攻坚方案[R].惠州:惠州市生态环境局博罗分局,2019. [17] 王方园,洪华嫦,岑艳,等.东江流域底泥重金属分析及潜在环境生态风险[J].环境化学,2012,31(9):40-46. [18] 孙博,黄莹,李永霞,等.基于主成分分析的河流沉积物重金属污染评价[J].环境科学与技术,2016,39(10):175-184. [19] GRAY C W,MCLAREN R G,ROBERTS A H C,et al.The effect of long-term phosphatic fertilizer applications on the amounts and forms of cadmium in soils under pasture in New Zealand[J].Nutrient Cycling in Agroecosystems,1999,54(3):267-277. [20] HUDSON EDWARDS K A,HOUGHTON S L,OSBORNO A.Extraction and analysis of arsenic in soils and sediments[J].TrAC Trends in Analytical Chemistry,2004,23(10):745-752. [21] 胡国成,许振成,彭晓武,等.广东长潭水库表层沉积物重金属污染特征与潜在生态风险评价研究[J].农业环境科学学报,2011,30(6):1166-1171.
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