PREPARATION AND PERFORMANCE ANALYSIS OF ECO-FRIENDLY COMPOSITE SMOKE SUPPRESSION ASPHALT
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摘要: 为了降低沥青烟雾对环境的污染,通过在沥青中添加外加剂,开发出一种环境友好型复合抑烟沥青,并对其性能、作用机理、经济及环境效益进行分析。首先,通过热重实验,分析Sasobit和氢氧化铝(ATH)在单掺及复配时的抑烟效果,结合基本物理性能测试优选出外加剂的最佳比例,并对该比例外加剂下的沥青进行了性能分析。然后,通过红外光谱和热重实验,分别研究沥青及外加剂的官能团变化及外加剂的抑烟规律,从而进一步分析复合抑烟沥青的作用机理,并对其经济及环境效益进行评价。结果表明:外加剂最佳的复配比例为3%Sasobit和20%ATH,沥青烟雾产生率降低约10.93%,并且沥青的布氏旋转黏度有所提高,高温抗车辙能力提高2倍左右,但低温性能也有所下降。Sasobit和ATH对沥青的改性机制分别以化学和物理改性为主。与单掺Sasobit和ATH相比,复合改性沥青的成本分别降低约53%和9%,同时复合抑烟沥青具有良好的环境效益。Abstract: In order to reduce the emission of asphalt smoke to the environment, a kind of eco-friendly composite smoke suppression asphalt was developed by adding admixtures to asphalt, and its performance, mechanism, economic and environmental benefits were analyzed. Firstly, through thermogravimetric experiment, the smoke suppression effect of Sasobit and aluminum trihydrate(ATH) in single blending and compounding were analyzed, combined with the basic physical performance test, the optimal proportion of smoke suppression agent was selected, and the performance with the proportion of the admixtures was analyzed. Then, through infrared spectroscopy and thermogravimetric experiment, the functional group changes of the asphalt and admixtures and the smoke suppression laws of the admixtures were studied respectively, so as to further analyze the mechanism of the composite smoke suppression asphalt. Finally, the economic and environmental benefits were evaluated. The results showed that the optimal mixture ratio of additives was 3% of Sasobit and 20% of ATH, and the asphalt smoke production rate decreased by about 10.93%. The Brookfield rotational viscosity of the asphalt was increased, the high temperature rutting resistance was increased by about 2 times, but the low temperature performance was somewhat declined. Sasobit and ATH mainly modified asphalt through chemical modification and physical modification, respectively. Compared with adding Sasobit and ATH separately, the cost of composite modified asphalt was reduced by about 53% and 9%, respectively. At the same time, the compound smoke suppression asphalt had good environmental benefits.
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Key words:
- road engineering /
- smoke suppression asphalt /
- performance analysis /
- mechanism /
- environmental benefits
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[1] 马万斌,牛昌昌,王迎丹,等.沥青烟浓度及成分检测技术研究进展[J].公路交通科技(应用技术版),2020,16(9):155-157. [2] 吴晓颖,刘树华,李志军,等.沥青烟气测定方法国内外研究现状[J].齐鲁石油化工,2021,49(1):76-80. [3] NEGHAB M,DERISI F Z,HASSANZADEH J,et al.Toxic responses of different organs following occupational exposure to sub-threshold limit value levels of paving asphalt fumes[J].Toxicological and Environmental Chemistry,2017,99(2):331-339. [4] 王春,郝培文,张庆,等.温拌沥青混合料环境与经济效益分析[J].环境工程,2012,30(增刊2):452-455. [5] 张丽宏.温拌沥青混合料性能研究[J].环境工程,2014,32(增刊1):480-482,487. [6] 吴乃明.温拌剂种类对沥青混合料性能影响的研究[D].哈尔滨:东北林业大学,2013. [7] BUTZ T.Warm asphalt mix-technologies,researches and experience[C]//Proceedings of the Polish Road Congress,Ⅰ Kongres Drogowy-1 st Polish Congress,Poland.2004. [8] 郭寅川,王涵,申爱琴,等.ATH/OMMT复合改性沥青阻燃抑烟性能与机理分析[J].硅酸盐通报,2020,39(6):1989-1997. [9] 万赈民.改性氢氧化铝粉体制备及其阻燃温拌沥青的性能[D].郑州:郑州航空工业管理学院,2020. [10] 申爱琴,苏宇轩,杨小龙,等.ATH/MMT阻燃剂对沥青混合料性能的影响[J].长安大学学报(自然科学版),2020,40(2):1-9. [11] 王鲁静,肖学文,段金凤,等.氢氧化铝填料的合成及在复合材料中的阻燃应用研究[J].山西化工,2021,41(1):18-20. [12] CHUAN Y L,WU S,CHIU Y C.Thermal stability of epoxy resins containing flame retardant components:an evaluation with thermogravimetric analysis[J].Polymer Degradation and Stability,2002,78(1):41-48. [13] 刘细军,任艳.氢氧化铝阻燃剂对沥青及沥青混合料性能的影响[J].北方交通,2013(6):9-11. [14] 交通运输部.公路工程沥青及沥青混合料试验规程:JTG E20—2011[S].北京:人民交通出版社,2011. [15] 刘静.高温条件下沥青烟尘评价系统与抑制技术研究[D].重庆:重庆交通大学,2012. [16] 张红华.抑烟沥青的性能及抑烟效果评价研究[D].武汉:武汉理工大学,2014. [17] 叶伟.隧道抑烟沥青的研制与抑烟沥青混合料路用性能研究[D].重庆:重庆交通大学,2014. [18] 季节,罗晓辉,徐世法.Sasobit改性沥青的结构与性能研究[J].中国公路学报,2011,24(5):18-25. [19] 熊剑平,彭文举,陈宇,等.基于热分析的阻燃沥青阻燃机理[J].长安大学学报(自然科学版),2019,39(2):47-56.
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