臭氧/陶瓷膜工艺在水处理中的研究进展

李思敏; 杨辉; 付玉洁; 肖峰; 郭建宁; 林创桂

doi:10.13205/j.hjgc.202203031

臭氧/陶瓷膜工艺在水处理中的研究进展

doi: 10.13205/j.hjgc.202203031

李思敏¹,
杨辉^1,2,
付玉洁^1,2,
肖峰³,
郭建宁^2, ,,
林创桂²

1. 河北工程大学能源与环境工程学院, 河北邯郸 056038;
2. 深圳信息职业技术学院, 广东深圳 518172;
3. 华北电力大学环境科学与工程学院, 北京 102206

基金项目:

深圳市科技计划项目(JCYJ20180307163205964)

广东高校省级重点平台和科研项目(2018GKTSCX065)

详细信息

作者简介:
李思敏(1968-),男,教授,主要研究方向为水及废水处理理论与技术。chyeli@126.com

通讯作者:
郭建宁(1981-),男,高级工程师,主要从事以膜为主的饮用水处理工艺研究。guojn08@163.com

计量
- 文章访问数: 283
- HTML全文浏览量: 41
- PDF下载量: 26
- 被引次数: 0
出版历程
- 收稿日期: 2021-01-21
- 网络出版日期: 2022-07-07

CURRENT KNOWLEDGE AND RESEARCHES ON OZONE/CERAMIC MEMBRANE PROCESS IN WATER TREATMENT FIELD

1. College of Energy and Environmental Engineering, Hebei University of Technology, Handan 056038, China;
2. Shenzhen Institute of Information Technology, Shenzhen 518172, China;
3. College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China

摘要

摘要: 臭氧/陶瓷膜组合工艺作为一种高效水处理技术,自2003年首次使用以来取得了快速发展。为进一步推动臭氧/陶瓷膜组合工艺在我国的深入研究与广泛应用,探讨了陶瓷膜对臭氧的催化机理及工艺效果。通过整理国内外近年来臭氧/陶瓷膜组合工艺在膜污染控治、污染物去除以及消毒副产物降解等方面的研究,并结合机理研究对工艺的发展方向进行了展望,指出陶瓷膜材料的制备与改性、膜孔"限域"空间的应用、臭氧曝气等将是臭氧/陶瓷膜技术的重要研究方向。
- 臭氧氧化 /
- 陶瓷膜 /
- 非均相催化 /
- 膜污染 /
- 消毒副产物
Abstract: As an efficient water and wastewater treatment technology, the combined ozone/ceramic membrane process has achieved rapid development since 2003. To promote the detailed research and extensive use of the prospective process in China, the mechanism of the catalytic ozonation on/in ceramic membrane is discussed and the performance of the hybrid process is also studied. The current knowledge and research status including membrane pollution prevention, pollutant removal and disinfection by-product degradation is summarized. The future development direction is also predicted according to the review. It is expected that the preparation and modification of ceramic membrane materials, the confined nano space effect of membrane pore and the ozone aeration mode will be the key focuses of ozone/ceramic membrane technology in the future.
- ozonation /
- ceramic membrane /
- heterogeneous catalysis /
- membrane fouling /
- disinfection by-products

HTML全文

参考文献(85)

[1]	SCHLICHTER B, MAVROV V, CHMIEL H. Study of a hybrid process combining ozonation and membrane filtration-filtration of model solutions[J].Desalination,2003,156(1):257-265.
[2]	SCHLICHTER B, MAVROV V, CHMIEL H. Study of a hybrid process combining ozonation and microfiltration/ultrafiltration for drinking water production from surface water[J].Desalination,2004,168:307-317.
[3]	KARNIK B S, DAVIES S H R, CHEN K C, et al. Effects of ozonation on the permeate flux of nanocrystalline ceramic membranes[J].Water Research,2005,39(4):728-734.
[4]	KARNIK B S, DAVIES S H, BAUMANN M J, et al. The effects of combined ozonation and filtration on disinfection by-product formation[J].Water Research,2005,39(13):2839-2850.
[5]	BYUN S, DAVIES S H, ALPATOVA A L, et al. Mn oxide coated catalytic membranes for a hybrid ozonation-membrane filtration:comparison of Ti, Fe and Mn oxide coated membranes for water quality[J].Water Research,2011,45(1):163-170.
[6]	PARK H, KIM Y, AN B, et al. Characterization of natural organic matter treated by iron oxide nanoparticle incorporated ceramic membrane-ozonation process[J].Water Research,2012,46(18):5861-5870.
[7]	ALPATOVA A L, DAVIES S H, MASTEN S J. Hybrid ozonation-ceramic membrane filtration of surface waters:the effect of water characteristics on permeate flux and the removal of DBP precursors, dicloxacillin and ceftazidime[J].Separation and Purification Technology,2013,107:179-186.
[8]	谢宇铭,张锡辉.陶瓷膜组合工艺对水中甲硫醚去除效果研究[J].环境科学与技术,2011,34(8):131-133.
[9]	郭建宁,张锡辉,王凌云,等.臭氧预氧化对不同孔径陶瓷膜过滤微污染饮用水的影响[J].中南大学学报(自然科学版),2013,44(9):3925-3932.
[10]	范小江,雷颖,韦德权,等.臭氧/陶瓷膜集成工艺的饮用水安全性研究[J].中国给水排水,2014,30(15):44-49.
[11]	张建国,盛德洋,郭建宁,等.陶瓷膜在高浊度给水处理中的试验研究[J].水处理技术,2012, 38(2):115-118.
[12]	郭建宁,张锡辉,胡江泳,等.臭氧氧化对陶瓷膜超滤工艺降低饮用水中浊度的影响[J].环境科学学报,2013,33(4):968-975.
[13]	WANG J L, BAI Z Y. Fe-based catalysts for heterogeneous catalytic ozonation of emerging contaminants in water and wastewater[J].Chemical Engineering Journal,2017,31:79-98.
[14]	NAWAZ F, XIEY B, XIAO J D. The influence of the substituent on the phenol oxidation rate and reactive species in cubic MnO₂ catalytic ozonation[J].Catalysis Science&Technology,2016:7875-7884.
[15]	WANG J L, CHEN H. Catalytic ozonation for water and wastewater treatment:recent advances and perspective[J]. Science of the Total Environment,2020,704:135249.
[16]	QI F, CHU W, XU B B. Comparison of phenacetin degradation in aqueous solutions by catalytic ozonation with CuFe₂O₄ and its precursor:surface properties, intermediates and reaction mechanisms[J].Chemical Engineering Journal,2016,284:28-36.
[17]	MANSAS C, MENDRET J, BROSILLON S, et al. Coupling catalytic ozonation and membrane separation:a review[J].Separation and Purification Technology,2020,236:116221.
[18]	BING J S, HU C, ZHANG L L. Enhanced mineralization of pharmaceuticals by surface oxidation over mesoporous γ-Ti-Al₂O₃ suspension with ozone[J].Applied Catalysis B:Environmental,2017,202:118-126.
[19]	YU D Y, WANG L P, YANG T Y, et al. Tuning Lewis acidity of iron-based metal-organic frameworks for enhanced catalytic ozonation[J].Chemical Engineering Journal,2021,404(6):127075.
[20]	AHMAD M, XIE Q, CHEN S, et al. Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti₃C₂ nanosheets for efficient photo-Fenton reaction[J].Applied Catalysis B:Environmental,2020,264:118534.
[21]	HUANG Y X, SUN Y R, XU Z X, et al. Removal of aqueous oxalic acid by heterogeneous catalytic ozonation with MnO_<em>x/sewage sludge-derived activated carbon as catalysts[J].Science of The Total Environment,2017,575:50-57.
[22]	HUANG Y X, CUI C C, ZHANG D F, et al. Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon[J].Chemosphere,2015,119:295-301.
[23]	RASOOL R, ALIZADEH R,Ghareshabani E. Enhanced heterogeneous catalytic ozonation of pharmaceutical pollutants using a novel nanostructure of iron-based mineral prepared via plasma technology:a comparative study[J].Journal of Hazardous Materials,2020,392:122269.
[24]	LEE W J, BAO Y P, HU X, et al. Hybrid catalytic ozonation-membrane filtration process with CeO_<em>x and MnO_<em>x impregnated catalytic ceramic membranes for micropollutants degradation[J].Chemical Engineering Journal,2019,378:121670.
[25]	CHEN G, ZHU X, CHEN R, et al. Gas-liquid-solid monolithic microreactor with Pd nanocatalyst coated on polydopamine modified nickel foam for nitrobenzene hydrogenation[J].Chemical Engineering Journal, 2018, 334:1897-1904.
[26]	FENG H, ZHU X, CHEN R, et al. High-performance gas-liquid-solid microreactor with polydopamine functionalized surface coated by Pd nanocatalyst for nitrobenzene hydrogenation[J]. Chemical Engineering Journal, 2016,306:1017-1025.
[27]	FREEMAN S, SHORNEY-DARBY H. What's the buzz about ceramic membranes?[J]. Journal American Water Works Association,2011,103(12):12-13.
[28]	MENG L, GUO H Z, DONG Z Y, et al. Ceramic hollow fiber membrane distributor for heterogeneous catalysis:effects of membrane structure and operating conditions[J].Chemical Engineering Journal,2013,223:356-363.
[29]	WATTS P, WILES C. Recent advances in synthetic micro reaction technology[J].Chemical Communications,2007(5):443-467.
[30]	CHEN Y Q, YIN S, LI Y L, et al. Curvature dependence of single-walled carbon nanotubes for SO₂ adsorption and oxidation[J].Applied Surface Science,2017,404:364-369.
[31]	PANIĆ S, KUKOVECZ Á, BOSKOVIC G. Design of catalytic carbon nanotube-based reactor for water denitration:the impact of active metal confinement[J]. Applied Catalysis B:Environmental,2018,225:207-217.
[32]	ZHANG S, QUAN X, WANG D. Catalytic ozonation in arrayed zinc oxide nanotubes as highly efficient mini-column catalyst reactors (MCRs):augmentation of hydroxyl radical exposure[J].Environmental Science&Technology,2018, 52(15):8701-8711.
[33]	LIN J Y, CHEN S, XIAO H Y, et al. Ultra-efficient and stable heterogeneous iron-based Fenton nanocatalysts for degrading organic dyes at neutral pH via a chelating effect under nanoconfinement[J].Chemical Communications,2020,56:6571-6574.
[34]	ZHANG S, HEDTKE T, ZHOU X C, et al. Environmental applications of engineered materials with nanoconfinement[J].ACS ES&T engineering,2021.
[35]	CHOI H, AL-ABED S R, AGARWAL S, et al. Synthesis of reactive nano-Fe/Pd bimetallic system-impregnated activated carbon for the simultaneous adsorption and dechlorination of PCBs[J].Chemistry of Materials,2008,20(11):3649-3655.
[36]	ZHANG S, SUN M, HEDTKE T, et al. Mechanism of heterogeneous fenton reaction kinetics enhancement under nanoscale spatial confinement[J]. Environmental Science&Technology,2020,54(17):10868-10875.
[37]	LAVERNE J A. The production of OH radicals in the radiolysis of water with 4He ions[J]. Radiation research,1989,118(2):201-210.
[38]	CHEN Y, ZHANG G, LIU H J, et al. Confining free radicals in close vicinity to contaminants enables ultrafast Fenton-like processes in the interspacing of MoS₂ membranes[J].Angewandte Chemie International Edition,2019,58(24):8134-8138.
[39]	鄢忠森,瞿芳术,梁恒,等.超滤膜污染以及膜前预处理技术研究进展[J].膜科学与技术,2014, 34(4):108-114 ,127.
[40]	HER N, AMY G, FOSS D, et al. Optimization of method for detecting and characterizing NOM by HPLC-size exclusion chromatography with UV and on-line dOC Detection[J]. Environmental Science&Technology,2002,36(5):1069-1076.
[41]	TIAN J Y, WU C W, YU H R, et al. Applying ultraviolet/persulfate (UV/PS) pre-oxidation for controlling ultrafiltration membrane fouling by natural organic matter (NOM) in surface water[J].Water Research,2018,132:190-199.
[42]	BOKSOON K, PARK N, JAEWEON C. Effect of algae on fouling and efficiency of UF membranes[J].Desalination,2004, 179(1):203-214.
[43]	SONG Z L, LI Y N, WANG Z, et al. Effect of the coupling modes on EfOM degradation and fouling mitigation in ozonation-ceramic membrane filtration[J].Chemical Engineering Journal,2020,394:124935.
[44]	YIN Z L, WEN T C, LI Y, et al. Alleviating reverse osmosis membrane fouling caused by biopolymers using pre-ozonation[J]. Journal of Membrane Science,2020,595:117546.
[45]	YIN Z L,WEN T C, LI Y, et al. Pre-ozonation for the mitigation of reverse osmosis (RO) membrane fouling by biopolymer:the roles of Ca²⁺ and Mg²⁺[J].Water Research,2020,171:115437.
[46]	SONG J, ZHANG Z H, ZHANG X H. A comparative study of pre-ozonation and in-situ ozonation on mitigation of ceramic UF membrane fouling caused by alginate[J].Journal of Membrane Science,2017,538:50-57.
[47]	关羽琪,王凯伦,祝学东,等.臭氧-CNT膜改性联用工艺对PVDF中空纤维膜污染进程的缓解[J].环境科学,2018, 39(8):3744-3752.
[48]	ASIF M B, LI C Y, REN B Y, et al. Elucidating the impacts of intermittent in-situ ozonation in a ceramic membrane bioreactor:micropollutant removal, microbial community evolution and fouling mechanisms[J].Journal of Hazardous Materials,2021, 402:123730.
[49]	LI F, CHEN J, DENG C. The kinetics of crossflow dynamic membrane bioreactor[J].Water SA,2006,32(2):199-203.
[50]	SUN H F, LIU H, HAN J R, et al. Chemical cleaning-associated generation of dissolved organic matter and halogenated byproducts in ceramic MBR:ozone versus hypochlorite[J].Water Research,2018,140:243-250.
[51]	SUN H F, LIU H, WANG S Y, et al. Ceramic membrane fouling by dissolved organic matter generated during on-line chemical cleaning with ozone in MBR[J]. Water Research,2018,146:328-336.
[52]	POLLICE A, LAERA G, CASSANO D, et al. Removal of nalidixic acid and its degradation products by an integrated MBR-ozonation system[J].Journal of Hazardous Materials,2012, 203:46-52.
[53]	TANG S Y, LI J Y, ZHANG Z H, et al. Comparison of long-term ceramic membrane bioreactors without and with in-situ ozonation in wastewater treatment:membrane fouling, effluent quality and microbial community[J].Science of the Total Environment,2019,652:788-799.
[54]	SEMBLANTE G S, HAI F I, DIONYSIOS D D, et al. Holistic sludge management through ozonation:a critical review[J]. Journal of Environmental Management,2017,185:79-95.
[55]	GUO Y, SONG Z L, XU B B, et al. A novel catalytic ceramic membrane fabricated with CuMn₂O₄ particles for emerging UV absorbers degradation from aqueous and membrane fouling elimination[J].Journal of Hazardous Materials,2018,344:1229-1239.
[56]	CHEN S, YU J Q, WANG H, et al. A pilot-scale coupling catalytic ozonation-membrane filtration system for recirculating aquaculture wastewater treatment[J].Desalination,2015,363:37-43.
[57]	KUKUZAKI M, FUJIMOTO K, KAI S, et al. Ozone mass transfer in an ozone-water contacting process with Shirasu porous glass (SPG) membranes-A comparative study of hydrophilic and hydrophobic membranes[J].Separation and Purification Technology,2010,72(3):347-356.
[58]	SONG Z L, SUN J Y, WANG W H, et al. Stable synergistic decontamination and self-cleaning performance of powerful N-rGO catalytic ozonation membrane:clustering effect of free electrons and role of interface properties[J].Applied Catalysis B:Environmental,2021,283:119662.
[59]	STYLIANOU S K, SKLARI S D, ZAMBOULIS D, et al. Development of bubble-less ozonation and membrane filtration process for the treatment of contaminated water[J].Journal of Membrane Science,2015,492:40-47.
[60]	ZHANG J L, YU H T, QUAN X, et al. Ceramic membrane separation coupled with catalytic ozonation for tertiary treatment of dyestuff wastewater in a pilot-scale study[J].Chemical Engineering Journal,2016,301:19-26.
[61]	ZHU Y Q, CHEN S, QUAN X, et al. Hierarchical porous ceramic membrane with energetic ozonation capability for enhancing water treatment[J].Journal of Membrane Science,2013,431:197-204.
[62]	ZHU B, HU Y X, KENNEDY S, et al. Dual function filtration and catalytic breakdown of organic pollutants in wastewater using ozonation with titania and alumina membranes[J]. Journal of Membrane Science,2011,378(1):61-72.
[63]	IM D, NAKADA N, KATO Y, et al. Pretreatment of ceramic membrane microfiltration in wastewater reuse:a comparison between ozonation and coagulation[J].Journal of Environmental Management,2019,251:109555.
[64]	CHEN C J,FANG P Y, CHEN F. Permeate flux recovery of ceramic membrane using TiO₂ with catalytic ozonation[J].Ceramics International,2017,43:S758-S764.
[65]	ZHANG K, ZHANG Z Z,WANG H, et al. Synergistic effects of combining ozonation, ceramic membrane filtration and biologically active carbon filtration for wastewater reclamation[J].Journal of Hazardous Materials,2020,382:121091.
[66]	HAMID K I A, SANCIOLO P,GRAY S, et al. Impact of ozonation and biological activated carbon filtration on ceramic membrane fouling[J].Water Research,2017,126:308.
[67]	WEI D Q, TAO Y T, ZHANG Z H, et al. Effect of in-situ ozonation on ceramic UF membrane fouling mitigation in algal-rich water treatment[J].Journal of Membrane Science,2016, 498:116-124.
[68]	GUO J N, HU J Y, TAO Y, et al. Effect of ozone on the performance of a hybrid ceramic membrane-biological activated carbon process[J].Journal of Environmental Sciences,2014,26(4):783-791.
[69]	刘治界,杨春鹏,秦冰.陶瓷膜催化臭氧氧化处理苯酚模拟水的研究[J].石油炼制与化工,2020, 51(2):93-97.
[70]	王卓,袁骋,程延峰,等.臭氧氧化耦合陶瓷膜过滤处理煤制气废水研究[J].水处理技术,2019,45(2):82-86.
[71]	陈天翼,李根,王卓,等.粉末活性炭-陶瓷膜臭氧催化氧化深度处理煤气化废水研究[J].水处理技术,2018,44(2):80-83 , 99.
[72]	李博文,李响,周丽,等.臭氧陶瓷膜工艺处理微污染原水效果与膜污染研究[J].水处理技术,2018,44(1):114-117.
[73]	GRESS J, OLIVEIRA D L M, SILVA D E B, et al. Cleaning-induced arsenic mobilization and chromium oxidation from CCA-wood deck:potential risk to children[J].Environment International,2015,82:35-40.
[74]	YUSOF M S M, OTHMAN M H Z, WAHAB R A, et al. Effects of pre and post-ozonation on POFA hollow fibre ceramic adsorptive membrane for arsenic removal in water[J].Journal of the Taiwan Institute of Chemical Engineers,2020,110:100-111.
[75]	PARK H, CHOI H. As (Ⅲ) removal by hybrid reactive membrane process combined with ozonation[J].Water Research,2011, 45(5):1933-1940.
[76]	KUROKAWA Y, MAEKAWA A, TAKAHASHI M, et al. Toxicity and carcinogenicity of potassium bromate-a new renal carcinogen[J]. Environmental Health Perspectives,1990,87:309-335.
[77]	GUNTEN U V. Ozonation of drinking water:Part Ⅱ. Disinfection and by-product formation in presence of bromide, iodide or chlorine[J].Water Research,2003,37(7):1469-1487.
[78]	WEI K J, ZHUO W, OUYANG C P, et al. A hybrid fluidized-bed reactor (HFBR) based on arrayed ceramic membranes (ACMs) coupled with powdered activated carbon (PAC) for efficient catalytic ozonation:a comprehensive study on a pilot scale[J]. Water Research,2020,173:115536.
[79]	MOSLEMI M, DAVIES S H, MASTEN S J. Empirical modeling of bromate formation during drinking water treatment using hybrid ozonation membrane filtration[J].Desalination,2012,292:113-118.
[80]	HAMID K I A, SCALES P J, ALLARD S, et al. Ozone combined with ceramic membranes for water treatment:Impact on HO radical formation and mitigation of bromate[J].Journal of Environmental Management,2020,253:109655.
[81]	LIU J, HE K Y, ZHANG J X, et al. Coupling ferrate pretreatment and in-situ ozonation/ceramic membrane filtration for wastewater reclamation:water quality and membrane fouling[J].Journal of Membrane Science,2019,590:117310.
[82]	CHO Y H,JEONG S M,KIM S J,et al. Sacrificial graphene oxide interlayer for highly permeable ceramic thin film composite membranes[J].Journal of Membrane Science,2021,618:118442.
[83]	OUADDARI H, KARIM A, ACHIOU B, et al. New low-cost ultrafiltration membrane made from purified natural clays for direct Red 80 dye removal[J].Journal of Environmental Chemical Engineering,2019,7(4):103268.
[84]	XIA Z R, HU L M. Treatment of organics contaminated wastewater by ozone micro-nano-bubbles[J].Water,2019, 11:55.
[85]	JOTHINATHAN L, CAI Q Q, ONG S L, et al. Organics removal in high strength petrochemical wastewater with combined microbubble-catalytic ozonation process[J].Chemosphere,2021,263:127980.