LANDFILL LEACHATE TREATMENT BY FENTON-LIKE PROCESS WITH Fe3O4-RGO NANO-COMPOSITE CATALYST
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摘要: 采用共沉淀法制备Fe3O4-RGO纳米复合催化剂,并将其应用于类芬顿处理垃圾渗滤液,研究了反应时间、初始pH值、催化剂质量浓度和H2O2投加量对Fe3O4-RGO纳米复合催化剂类芬顿降解垃圾渗滤液COD去除率的影响。结果表明:反应时间为90 min,初始pH值为3,催化剂质量浓度为1 mg/L,H2O2投加量为0.08 mmol/L时,COD去除率达到最大值64.7%。有机物组分对比结果显示,类芬顿反应后垃圾渗滤液中大分子有机物得到较好的降解转化。Fe3O4-RGO纳米复合催化剂具有较好的重复利用性,重复使用5次后对垃圾渗滤液的COD去除率仅降低2.3%。Abstract: Fe3O4-RGO nanocomposite catalyst was prepared by coprecipitation method and then investigated in Fenton-like process when treating landfill leachate. The effect of reaction time, initial pH value, catalyst mass concentration and H2O2 dosage on COD removal rate of landfill leachate were studied. The results indicated that when the initial pH value was 3, catalyst mass concentration was 1 mg/L and H2O2 dosage was 0.08 mmol/L, the removal rate of COD removal rate reached a maximum of 64.7% after 90 minutes reaction. The comparison of organic components showed that the macromolecular organic matter in the landfill leachate was well degraded after Fenton-like treatment. The Fe3O4-RGO nanocomposite catalyst had good repeatability, and the COD removal rate of landfill leachate was only reduced by 2.3% after 5 times usage.
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Key words:
- Fe3O4-RGO /
- landfill leachate /
- Fenton-like /
- COD removal rate /
- coprecipitation method
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