BOTTLENECK OF APPLICATION OF DISPOSAL TECHNOLOGIES FOR FLY ASH FROM MUNICIPAL SOLID WASTE INCINERATION
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摘要: 生活垃圾焚烧飞灰富含二噁英、重金属和可溶盐,属于危险废物,需进行无害化处理。但当前垃圾焚烧产业普遍存在“重烟气、轻飞灰”问题,造成飞灰处置技术和能力不足,已成为当前制约垃圾焚烧产业发展的重要瓶颈。综述了飞灰的产生、物化特性以及处置技术。重点介绍了当前普遍采用的3种处理方式以及技术应用难点,包括螯合稳定耦合填埋、水洗脱盐耦合水泥窑协同处置和熔融玻璃化处理等,以期为垃圾焚烧飞灰的无害化处置行业提供技术参考。Abstract: Municipal solid waste incineration fly ash is rich in dioxins, heavy metals and soluble salts, and belongs to hazardous waste and needs harmless treatment. But in waste incineration industry in China, laying heavy emphasis on flue gas and ignoring fly ash is a prevalent problem, and becomes a bottleneck of the development of waste incineration at present. This paper reviewes the generation, physicochemical properties and disposal techniques of fly ash incineration. Three mainstream fly ash treatment methods and their technical difficulties in application, including chelating stable coupling landfill, water washing desalting coupling cement kiln co-treatment and thermal treatment were introduced emphatically. This paper can provide technical references for the harmless treatment of waste incineration fly ash.
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Key words:
- fly ash /
- heavy metal /
- soluble slat /
- washing /
- melting
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[1] 国家统计局.中国统计年鉴[J].http://wwwstatsgovcn/tjsj/ndsj/2020/indexchhtm,2020. [2] 国家生态环境部.生活垃圾焚烧发电厂自动监测数据公开平台.https://ljgkenvsccn/indexhtml,2020. [3] QUINA M J,BORDADO J C,QUINTA FERREIRA R M.Treatment and use of air pollution control residues from MSW incineration:an overview[J].Waste Management,2008,28(11):2097-2121. [4] ZHANG H Y,ZHAO Y C,QI J Y.Characterization of heavy metals in fly ash from municipal solid waste incinerators in Shanghai[J].Process Safety and Environmental Protection,2010,88(2):114-124. [5] LIN Y S,CHEN K S,LIN Y C,et al.Polychlorinated dibenzo-p-dioxins/dibenzofurans distributions in ash from different units in a municipal solid waste incinerator[J].Journal of Hazardous Materials,2008,154(1):954-962. [6] 蒋旭光,陈钱,赵晓利,孔莉倓.水热法稳定垃圾焚烧飞灰中重金属研究进展[J].化工进展,2021,40(8):4473-4485. [7] MAO Y P,WU H,WANG W L,et al.Pretreatment of municipal solid waste incineration fly ash and preparation of solid waste source sulphoaluminate cementitious material[J].Journal of Hazardous Materials,2020,385:121580. [8] YAN M,ZHOU Z H,ZHENG R D,et al.Low-temperature sintering behavior of fly ash from hazardous waste incinerator:effect of temperature and oxygen on ash properties[J].Journal of Environmental Chemical Engineering,2021,9(3):105261. [9] TANG P,CHEN W,XUAN D X,et al.Immobilization of hazardous municipal solid waste incineration fly ash by novel alternative binders derived from cementitious waste[J].Journal of Hazardous Materials,2020,393:122386. [10] WONG G J,FAN X H,GAN M,et al.Resource utilization of municipal solid waste incineration fly ash in iron ore sintering process:a novel thermal treatment[J].Journal of Cleaner Production,2020,263:121400. [11] BOGUSH A A,STEGEMANN J A,ROY A.Changes in composition and lead speciation due to water washing of air pollution control residue from municipal waste incineration[J].Journal of Hazardous Materials,2019,361:187-99. [12] WEI Y L,CHENG S H,CHEN W J,et al.Influence of various sodium salt species on formation mechanism of lightweight aggregates made from coal fly ash-based material[J].Construction and Building Materials,2020,239:117890. [13] XIE K,HU H Y,CAO J X,et al.A novel method for salts removal from municipal solid waste incineration fly ash through the molten salt thermal treatment[J].Chemosphere,2020,241:125107. [14] COLANGELO F,CIOFFI R,MONTAGNARO F,et al.Soluble salt removal from MSWI fly ash and its stabilization for safer disposal and recovery as road basement material[J].Waste Management,2012,32(6):1179-1185. [15] ZHANG S,CHEN Z L,LIN X Q,et al.Kinetics and fusion characteristics of municipal solid waste incineration fly ash during thermal treatment[J].Fuel,2020,279:118410. [16] YU S Y,DU B,BAHEIDUOLA A,et al.HCB dechlorination combined with heavy metals immobilization in MSWI fly ash by using n-Al/CaO dispersion mixture[J].Journal of Hazardous Materials,2020,392:122510. [17] WANG X X,JI G Z,ZHU K Y,et al.Integrated thermal behavior and compounds transition mechanism of municipal solid waste incineration fly ash during thermal treatment process[J].Chemosphere,2021,264:128406. [18] 侯霞丽.生活垃圾焚烧飞灰特性对二噁英生成影响的研究[D].杭州:浙江大学,2015. [19] 冯军会,何品晶,章骅,等.二噁英类化合物在生活垃圾焚烧飞灰中的分布[J].中国环境科学,2005,25(6):737-741. [20] MCKAY G.Dioxin characterisation,formation and minimisation during municipal solid waste (MSW) incineration:review[J].Chemical Engineering Journal,2002,86(3):343-368. [21] 魏炫坤,张作泰.城市生活垃圾焚烧处理中二噁英的产生机理及防控[C]//中国环境科学学会2020科学技术年会,2020. [22] BONTE J L,FRITSKY K J,PLINKEB M A,et al.Catalytic destruction of PCDD/F in a fabric filter:experience at a municipal waste incinerator in Belgium[J].Waste Management,2002,22(14):421-426. [23] TEJIMA H,NAKAGAWA I,SHINODA T A,et al.PCDDs/PCDFs reduction by good combustion technology and fabric filter with/without activated carbon injection[J].Chemosphere,1996,32(1):169-175. [24] TUPPURAINEN K,HALONEN I,RUOKOJARVI P,et al.Formation of PCDDs and PCDFs in municipal waste incineration and its inhibition mechanisms:A review[J].Chemosphere,1998,36(7):1493-1511. [25] 陈志良.机械化学法降解垃圾焚烧飞灰中二噁英及协同稳定化重金属的机理研究[D].杭州:浙江大学,2019. [26] LANE D J,SIPPULA O,KOPONEN H,et al.Volatilisation of major,minor,and trace elements during thermal processing of fly ashes from waste-and wood-fired power plants in oxidising and reducing gas atmospheres[J].Waste Management,2020,102:698-709. [27] LI B H,DENG Z Y,WANG W X,et al.Degradation characteristics of dioxin in the fly ash by washing and ball-milling treatment[J].Journal of Hazardous Materials,2017,339:191-199. [28] LI M G,SUN C J,GAU S H,et al.Effects of wet ball milling on lead stabilization and particle size variation in municipal solid waste incinerator fly ash[J].Journal of Hazardous Materials,2010,174(1):586-591. [29] ZERZOURI M,BOUCHENAFA O,HAMZAOUI R,et al.Physico-chemical and mechanical properties of fly ash based-geopolymer pastes produced from pre-geopolymer powders obtained by mechanosynthesis[J].Construction and Building Materials,2021,288:123135. [30] 谷忠伟.稳定剂对垃圾焚烧飞灰中重金属的稳定化效果研究[D].杭州:浙江大学,2020. [31] SU Y,YANG J,LIU D,et al.Effects of municipal solid waste incineration fly ash on solidification/stabilization of Cd and Pb by magnesium potassium phosphate cement[J].Journal of Environmental Chemical Engineering,2016,4(1):259-265. [32] CHEN Q Y,TYRER M,HILLS C D,et al.Immobilisation of heavy metal in cement-based solidification/stabilisation:a review[J].Waste Management,2009,29(1):390-403. [33] 张芝昆,王晶,李浩天,等.城市垃圾焚烧飞灰的水洗脱氯与水泥固化技术[J].科学技术与工程,2019,19(35):395-401. [34] ZHU F F,XIONG Y Q,WANG Y Y,et al.Heavy metal behavior in "Washing-Calcination-Changing with Bottom Ash" system for recycling of four types of fly ashes[J].Waste Management,2018,75:215-225. [35] 朱芬芬,高冈昌辉,大下和徹,等.焚烧飞灰预处理工艺及其无机氯盐的行为研究[J].环境科学,2013,34(6):2473-2478. [36] 蒋建国,赵振振,王军,等.焚烧飞灰水泥固化技术研究[J].环境科学学报,2006(2):230-235. [37] 邓燚超.垃圾焚烧飞灰低中温热处理过程中氯及重金属的迁徙特性分析[D].杭州:浙江大学,2007. [38] LOGINOVA E,PROSKURNIN M,BROUWERS H J H.Municipal solid waste incineration (MSWI) fly ash composition analysis:a case study of combined chelatant-based washing treatment efficiency[J].Journal of Environmental Management,2019,235:480-488. [39] 王晴,王新锐,游旭佳,等.飞灰基地聚合物固化重金属的研究现状与发展趋势[J].硅酸盐通报,2020,39(9):2849-2956. [40] 马保国,苏华伟,李相国,等.城市垃圾焚烧飞灰预处理技术研究[J].武汉理工大学学报,2013,35(4):22-26. [41] CHEN X F,BI Y F,ZHANG H B,et al.Chlorides removal and control through water-washing process on MSWI fly ash[J].Procedia Environmental Sciences,2016,31:560-566. [42] 凌永生,金宜英,聂永丰.焚烧飞灰水泥窑煅烧资源化水洗预处理实验研究[J].环境保护科学,2012,38(4):1-5. [43] ITO R,DODBIBA G,FUJITA T,et al.Removal of insoluble chloride from bottom ash for recycling[J].Waste Management,2008,28(8):1317-1323. [44] 王雨婷.炉排炉垃圾焚烧飞灰的水洗脱氯及二噁英降解试验研究[D].杭州:浙江大学,2019. [45] 李海雁,赖初泉,钟光亮.水泥窑协同处置固体废物情况综述[J].水泥,2017(增刊1):13-16. [46] 张冬冬,王朝雄,方明.水泥窑协同处置垃圾焚烧飞灰的技术途径[J].水泥技术,2020(6):17-22. [47] DONTRIROS S,LIKITLERSUANG S,JANJAROEN D.Mechanisms of chloride and sulfate removal from municipal-solid-waste-incineration fly ash (MSWI FA):effect of acid-base solutions[J].Waste Management,2020,101:44-53. [48] 叶英英.水泥窑协同处置生活垃圾焚烧飞灰项目难点[J].水泥工程,2020(增刊1):51-52. [49] MA W C,SHI W B,SHI Y J,et al.Plasma vitrification and heavy metals solidification of MSW and sewage sludge incineration fly ash[J].Journal of Hazardous Materials,2021,408:124809. [50] 张楚,王爽.城市垃圾焚烧飞灰高温熔融处理实验研究[J].辽宁石油化工大学学报,2019,39(6):31-35. [51] 宋珍霞,王里奥,林祥,等.城市垃圾焚烧飞灰特性及水泥固化试验研究[J].环境科学研究,2008,21(4):163-168. [52] 王峰,王伟,万晓.定pH值下垃圾焚烧飞灰酸中和容量与元素浸出行为的研究[J].环境科学,2008,29(2):2529-2534. [53] 郑丽婷,刘阳生.水洗及酸洗过程对焚烧飞灰中Cu、Zn和Pb洗脱率影响的试验研究[J].北京大学学报(自然科学版),2009,45(3):502-510. [54] KARLFELDT FEDJE K,EKBERG C,SKARNEMARK G,et al.Removal of hazardous metals from MSW fly ash:an evaluation of ash leaching methods[J].Journal of Hazardous Materials,2010,173(1):310-317. [55] 熊祖鸿,范根育,鲁敏,等.垃圾焚烧飞灰处置技术研究进展[J].化工进展,2013,32(7):1678-1684. [56] 纪莎莎,李晓东,徐旭,等.关于医疗垃圾飞灰中二噁英在惰性气氛下的低温热脱附研究[J].环境科学,2012,33(11):3999-4005. [57] 毛琼晶,彭政,陆胜勇,等.医疗垃圾焚烧飞灰中OCDD/OCDF的球磨机械化学法降解试验研究[J].化学学报,2012,70(5):659-666. [58] NATH S K,KUMAR S.Reaction kinetics of fly ash geopolymerization:role of particle size controlled by using ball mill[J].Advanced Powder Technology,2019,30(5):1079-1088. [59] 宋倩楠,王峰,唐一,等.螯合剂稳定飞灰的条件优化及螯合产物的稳定性评价[J].环境工程,2020,38(10):190-195,215. [60] ZHANG Y Y,WANG L,CHEN L,et al.Treatment of municipal solid waste incineration fly ash:state-of-the-art technologies and future perspectives[J].Journal of Hazardous Materials,2021,411:125132.
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