福州地区垃圾焚烧飞灰中矿物组分和重金属污染特征

张宇晨; 陈小朵; 桂思; 苏桦; 张伟芳; 刘常青; 吴春山; 郑育毅

doi:10.13205/j.hjgc.202208014

福州地区垃圾焚烧飞灰中矿物组分和重金属污染特征

doi: 10.13205/j.hjgc.202208014

张宇晨^1,2,3,4,5,
陈小朵¹,
桂思¹,
苏桦¹,
张伟芳^1,2,3,4, ,,
刘常青^2,3,6,
吴春山^1,2,3,4,
郑育毅^1,2,3,4

1. 福建师范大学环境科学与工程学院, 福州 350007;
2. 福建师范大学环境科学研究所, 福州 350007;
3. 城市废物资源化技术与管理福建省高校工程研究中心, 福州 350007;
4. 福建省污染控制与资源循环利用重点实验室, 福州 350007;
5. 福建技术师范学院近海流域环境测控治理福建省高校重点实验室, 福建福清 350300;
6. 福建师范大学地理科学学院, 福州 350007

基金项目:

近海流域环境测控治理福建省高校重点实验室开放课题(S1-KF2002)

福建师范大学大学生创新训练计划项目(cxxl-2021331)

详细信息

作者简介:
张宇晨(1996-),男,研究生在读,主要研究方向为固体废物资源化利用。yczhang0419@163.com

通讯作者:
张伟芳(1989-),男,博士,副教授,主要研究方向为固体废物处理与资源化利用。wfzhang@fjnu.edu.cn

计量
- 文章访问数: 222
- HTML全文浏览量: 46
- PDF下载量: 8
- 被引次数: 0
出版历程
- 收稿日期: 2021-11-29
- 刊出日期: 2022-11-08

MINERAL COMPONENTS AND HEAVY METAL POLLUTION CHARACTERISTICS IN WASTE INCINERATION FLY ASH IN FUZHOU

ZHANG Yuchen^1,2,3,4,5,
CHEN Xiaoduo¹,
GUI Si¹,
SU Hua¹,
ZHANG Weifang^{1,2,3,4
, ,},
LIU Changqing^2,3,6,
WU Chunshan^1,2,3,4,
ZHENG Yuyi^1,2,3,4

1. College of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, China;
2. Institute of Environmental Science, Fujian Normal University, Fuzhou 350007, China;
3. Urban Waste Resource Technology and Management Fujian University Engineering Research Center, Fuzhou 350007, China;
4. Key Laboratory of Resource Cycle and Pollution Control of Fujian Province, Fujian Normal University, Fuzhou 350007, China;
5. Fujian Provincial Key Laboratory of Coastal Basin Environmental Measurement and Control, Fujian Polytechnic Normal University, Fuqing 350300, China;
6. College of Geography Science, Fujian Normal University, Fuzhou 350007, China

摘要

摘要: 采集福州某焚烧发电厂飞灰,分析和对比不同地区矿物组分和重金属污染特征。结果表明:此飞灰主要矿物组分除CaCO₃和SiO₂外,还包含可溶性氯盐(NaCl、KCl)和不可溶氯盐(AlOCl)。重金属总量顺序为Zn＞Pb＞Cu＞Cd＞Cr＞Ni。与全国不同地区的飞灰一致,Zn和Pb总量均较高;Pb超出GB 16889—2008《生活垃圾填埋场污染物控制标准》的浸出毒性标准限值。形态分析结果表明,Cd(83.3%)和Cu(66.2%)的不稳定态占比高,Zn(47.0%)和 Pb(36.6%)的不稳定态也具有一定占比。相比于短期浸出和浸提剂种类(纯水、醋酸和盐酸),5 mol/L盐酸长时间重金属浸出效果显著,Zn和Pb浸出浓度明显增强,且Zn最大;受形态和总量影响,Cu、Cd、Cr和Ni浸出浓度相对较低。因此,飞灰长期堆积在环境中仍具有较高的潜在风险。不同区域飞灰的矿物相及其重金属污染特征存在一定普遍规律,并具有地域特征。该研究成果可为后期飞灰固定稳定化方法提供数据支撑。
- 飞灰 /
- 重金属 /
- 浸出行为 /
- 赋存形态 /
- 矿物组分 /
- 福州
Abstract: This study collected fly ash from an incineration power plant in Fuzhou, analyzed and compared the mineral components and heavy metal pollution characteristics in different areas in China. The results showed that the main mineral included the soluble chloride salts(NaCl, KCl) and insoluble chloride salts(AlOCl), apart from CaCO₃ and SiO₂. The order of heavy metal total amount was Zn>Pb>Cu>Cd>Cr>Ni, and the total amount of Zn and Pb was higher, the same as that in some other areas in China; the leaching concentration of Pb exceeded the standard limit, GB 16889—2008 in the leaching toxicity test. The morphological analysis also showed that the unstable state of Cd (83.3%) and Cu (66.2%) accounted for high proportions, and that of Pb (36.6%) and Zn (47.0%) also accounted for certain proportions. Compared with the short-term leaching and the types of extractants (UPW, acetic acid and HCl), 5 mol/L HCl had a significant leaching effect under the long-term leaching condition, and the leaching concentrations of Zn and Pb significantly rose, and Zn leaching concentration was the highest in all heavy metal elements; the leaching concentrations of Cu, Cd, Cr, and Ni were relatively lower under the influence of total amount and speciation of heavy metal. Therefore, long-term storage of fly ash in the environment still possessed a high potential risk. The mineral components and heavy metal pollution characteristics of fly ash in different areas have certain universal laws and regional characteristics, which can provide data support for the development of fly ash immobilization and stabilization methods.
- fly ash /
- heavy metal /
- leaching behavior /
- speciation /
- mineral component /
- Fuzhou

HTML全文

参考文献(41)

[1]	WANG L,JIN Y Y,NIE Y F.Investigation of accelerated and natural carbonation of MSWI fly ash with a high content of Ca[J].Journal of Hazardous Materials,2010,174(1/2/3):334-343.
[2]	国家统计局.中国统计年鉴[M].北京:中国统计出版社,2021.
[3]	WANG P,HU Y A,CHENG H F.Municipal solid waste (MSW) incineration fly ash as an important source of heavy metal pollution in China[J].Environmental Pollution,2019,252:461-475.
[4]	李清毅,宋凯,何亮,等.生活垃圾填埋场中飞灰固化体动态/半动态浸出行为[J].环境工程,2019,37(11):149-154.
[5]	倪海凤,旦增,周文武,等.拉萨市垃圾焚烧飞灰重金属特性分析及风险评价[J/OL].环境工程:1-7[2021-10-10 ].http://kns.cnki.net/kcms/detail/11.2097.x.20211004.1946.002.html.
[6]	李建陶,曾鸣,杜兵,等.垃圾焚烧飞灰药剂稳定化矿物学特性[J].中国环境科学,2017,37(11):4188-4194.
[7]	LI W H,SUN Y J,XIN M X,et al.Municipal solid waste incineration fly ash exposed to carbonation and acid rain corrosion scenarios:release behavior,environmental risk,and dissolution mechanism of toxic metals[J].Science of the Total Environment,2020,744:140857.
[8]	赵友杰,孙英杰,范新秀,等.渗滤液浸沥下稳定化飞灰中重金属的浸出行为[J].中国环境科学,2018,38(4):1411-1416.
[9]	范新秀,陈璐,马丽,等.3种有机浸提剂对螯合稳定化飞灰中Ba、Pb、Zn浸出特性的影响[J].环境科学与技术,2018,41(11):44-48.
[10]	HAN C J,LI H L,YAN Y J,et al.Effect of different pretreatment solutions on electrokinetic remediation of heavy metals from municipal solid waste incineration fly ash[J].International Journal of Electrochemical Science,2020,15:8694-8709.
[11]	林涛,谢巧玲,陈福明,等.基于重金属提取的垃圾焚烧飞灰无害化处理[J].环境工程学报,2018,12(9):2642-2649.
[12]	HYKS J,ASTRUP T,CHRISTENSEN T H.Long-term leaching from MSWI air-pollution-control residues:leaching characterization and modeling[J].Journal of Hazardous Materials,2009,162(1):80-91.
[13]	李朝辉.垃圾焚烧飞灰中重金属的浸出特性及化学稳定研究[D].重庆:重庆大学,2017.
[14]	LIU Z Y,YUE Y,LU M,et al.Comprehension of heavy metal stability in municipal solid waste incineration fly ash with its compositional variety:a quick prediction case of leaching potential[J].Waste Management,2019,84:329-339.
[15]	QUINA M J,BORDADO J C,QUINTA-Ferreira R M.Chemical stabilization of air pollution control residues from municipal solid waste incineration[J].Journal of Hazardous Material,2010,179(1/2/3):382-392.
[16]	VERHULST R,BUEKENS A,SPENCER P J,et al.Thermodynamic behavior of metal chlorides and sulfides under the conditions of incineration furnaces[J].Environmental Science & Technology,1996,30(1):50-56.
[17]	章骅,于思源,邵立明,等.烟气净化工艺和焚烧炉类型对生活垃圾焚烧飞灰性质的影响[J].环境科学,2018,39(1):467-476.
[18]	FUJIMORI T,TAKAOKA M,TAKEDA N.Influence of Cu,Fe,Pb and Zn chlorides and oxides on formation of chlorinated aromatic compounds in MSWI fly ash[J].Environmental Science & Technology,2009,43(21):8053-8059.
[19]	范新秀,郝志鹏,王华伟,等.pH和液固比对稳定化飞灰Pb浸出的影响[J].环境工程,2018,36(5):156-159 ,165.
[20]	KOMONWEERAKET K,CETIN B,BENSON C H,et al.Leaching characteristics of toxic constituents from coal fly ash mixed soils under the influence of pH[J].Waste Management,2015,38(1):174-184.
[21]	童立志,韦黎华,王峰,等.焚烧飞灰重金属含量及浸出长期变化规律研究[J].中国环境科学,2020,40(5):2132-2139.
[22]	杨凤玲,李鹏飞,叶泽甫,等.城市生活垃圾焚烧飞灰组成特性及重金属熔融固化处理技术研究进展[J].洁净煤技术,2021,27(1):169-180.
[23]	施惠生,袁玲.城市垃圾焚烧飞灰中重金属的化学形态分析[J].环境科学研究,2004,17(6):46-49.
[24]	RYAN P C,HILLIER S,WALL A J.Stepwise effects of the BCR sequential chemical extraction procedure on dissolution and metal release from common ferromagnesian clay minerals:a combined solution chemistry and X-ray powder diffraction study[J].Science of the Total Environment,2008,407(1):603-614.
[25]	HELTAI G,REMETEIOVÁ D,HORVATH M,et al.Various fractionation procedures in study of heavy metals mobility in the environment[J].Ecological Chemistry and Engineering S,2011,18(1):55-65.
[26]	PAN Y,WU Z M,ZHOU J Z,et al.Chemical characteristics and risk assessment of typical municipal solid waste incineration (MSWI) fly ash in China[J].Journal of Hazardous Materials,2013,261:269-276.
[27]	TEASDALE P R,APTE S C,FORD P W,et al.Geochemical cycling and speciation of copper in waters and sediments of Macquarie Harbour,Western Tasmania[J].Estuarine Coastal and Shelf Science,2003,57(3):475-487.
[28]	韩大健,王文祥,孙水裕,等.城市生活垃圾焚烧飞灰中钾盐浸出研究[J].环境科学学报,2017,37(6):2223-2231.
[29]	孙杨雨,焦春磊,谭笑,等.生活垃圾焚烧飞灰中重金属的稳定化及其机理研究[J].中国科学·化学,2016,46(7):716-724.
[30]	JIANG J G,XU X,WANG J,et al.Investigation of basic properties of fly ash from urban waste incinerators in China[J].Journal of Environmental Sciences,2017,19(4):458-463.
[31]	GREENBAUM M A,BLAUER J A,ARSHADI M R,et al.Heat offormation of AlOCl (g)[J].Transactions of the Faraday Society,1964,60:1592-1597.
[32]	陈禹衡,董发勤,张伟,等.自发极化电气石对CaCO₃结晶过程和晶体形貌的影响[J/OL].矿物学报:1-9[2021-10-04 ].https://doi.org/10.16461/j.cnki.1000-4734.2021.41.098.
[33]	TIAN Z P,ZHANG B R,HE C J,et al.The physiochemical properties and heavy metal pollution of fly ash from municipal solid waste incineration[J].Process Safety and Environmental Protection,2015,98:333-341.
[34]	SAIKIA N,KATO S,KOJIMA T.Production of cement clinkers from municipal solid waste incineration (MSWI) fly ash[J].Waste Management,2007,27(9):1178-1189.
[35]	柴晓利,王冬扬,高桥史武,等.我国典型垃圾焚烧飞灰物化特性对比[J].同济大学学报(自然科学版),2012,40(12):1857-1862.
[36]	武博然,王冬扬,柴晓利.生活垃圾焚烧飞灰生物脱氯机制研究[J].中国环境科学,2015,35(8):2470-2476.
[37]	马倩,陈玉放,靳焘,等.城市生活垃圾焚烧发电飞灰中重金属的固定化研究[J].生态环境学报,2018,27(9):1716-1723.
[38]	张厚坚,刘海娟,黄世清,等.城市生活垃圾焚烧处理过程中重金属迁移规律研究[J].环境工程学报,2013,7(11):4569-4574.
[39]	王月香,邵兰燕,徐天男,等.垃圾焚烧飞灰中氯元素存在形态及深度脱氯的研究[J].无机盐工业,2021,53(5):78-83.
[40]	张芝昆,王晶,李浩天,等.城市垃圾焚烧飞灰的水洗脱氯与水泥固化技术[J].科学技术与工程,2019,19(35):395-401.
[41]	FA C J,LIAN Z,ZHONG B D,et al.Study on the species of heavy metals in MSW incineration fly ash and their leaching behavior[J].Fuel Processing Technology,2016,152:108-115.