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CO2催化合成衍生柴油的基础研究

李函霏 吴畏 白露露

赵晓佳, 王少坡, 于贺, 邱春生, 孙力平, 王晨晨, 赵乐军, 宋现财. 天津中心城区典型下垫面降雨径流污染冲刷特征分析[J]. 环境工程, 2019, 37(7): 34-38. doi: 10.13205/j.hjgc.201907007
引用本文: 李函霏, 吴畏, 白露露. CO2催化合成衍生柴油的基础研究[J]. 环境工程, 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001
LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO2 CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001
Citation: LI Han-fei, WU Wei, BAI Lu-lu. FUNDAMENTAL RESEARCH ON CO2 CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 1-8. doi: 10.13205/j.hjgc.202209001

CO2催化合成衍生柴油的基础研究

doi: 10.13205/j.hjgc.202209001
基金项目: 

国家自然科学基金“生活垃圾催化气化合成衍生燃油机理及二次污染发生特性研究”(51478092)

详细信息
    作者简介:

    李函霏(1993-),女,硕士,主要研究方向为固体废弃物处理与资源化技术。672048999@qq.com

    通讯作者:

    吴畏(1967-),男,副教授,主要研究方向为固体废弃物处理与资源化技术。wuwei@mail.neu.edu.cn

FUNDAMENTAL RESEARCH ON CO2 CATALYTIC SYNTHESIS OF DERIVATIVE DIESEL

  • 摘要: 为促进我国“双碳”政策的推行,拓展CO2的循环利用技术,开展了CO2合成柴油的实验探索,利用铁基催化剂,以CO2作为原料,探讨了CO2加氢合成衍生柴油的可行性研究。在科学验证CO2合成衍生柴油可行性的基础上,进一步考察了催化剂载体的酸碱性、催化剂组元Fe含量以及助剂添加对催化活性的影响。研究表明:CO2加氢的合成产物的主要组分及组分分布特点与商用柴油高度一致。以γ-Al2O3为载体负载铁基催化剂可有效促进CO2的逆水煤气反应和芬顿反应;作为催化剂助剂,金属元素K的添加对提高催化活性有较好的辅助作用。反应温度和压力是该反应的可控因子,其中,压力为决定因素,当压力>1.6 MPa时,反应才可以在250℃以上的温度域顺利发生。此外,载体的酸碱性、催化组元Fe及助剂K含量对合成产物的组分分布情况及与柴油的相似度也具有重要影响。
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  • 收稿日期:  2022-02-16
  • 网络出版日期:  2022-11-09

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