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基于富集因子法与MLR-APCS模型应用的农田土壤重金属人为来源定量识别

李延雪,  张梦竹,  舒莎莎,  邹君晗,  焦伟,  周峻宇

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文章导航 > 环境工程  > 2022 >  40(9): 173-177,232
李延雪, 张梦竹, 舒莎莎, 邹君晗, 焦伟, 周峻宇. 基于富集因子法与MLR-APCS模型应用的农田土壤重金属人为来源定量识别[J]. 环境工程, 2022, 40(9): 173-177,232. doi: 10.13205/j.hjgc.202209023
引用本文: 李延雪, 张梦竹, 舒莎莎, 邹君晗, 焦伟, 周峻宇. 基于富集因子法与MLR-APCS模型应用的农田土壤重金属人为来源定量识别[J]. 环境工程, 2022, 40(9): 173-177,232. doi: 10.13205/j.hjgc.202209023
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LI Yan-xue, ZHANG Meng-zhu, SHU Sha-sha, ZOU Jun-han, JIAO Wei, ZHOU Jun-yu. QUANTITATIVE IDENTIFICATION OF ANTHROPOGENIC HEAVY METAL SOURCES IN FARMLAND SOIL BASED ON ENRICHMENT FACTOR AND MLR-APCS MODEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 173-177,232. doi: 10.13205/j.hjgc.202209023
Citation: LI Yan-xue, ZHANG Meng-zhu, SHU Sha-sha, ZOU Jun-han, JIAO Wei, ZHOU Jun-yu. QUANTITATIVE IDENTIFICATION OF ANTHROPOGENIC HEAVY METAL SOURCES IN FARMLAND SOIL BASED ON ENRICHMENT FACTOR AND MLR-APCS MODEL[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(9): 173-177,232. doi: 10.13205/j.hjgc.202209023
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基于富集因子法与MLR-APCS模型应用的农田土壤重金属人为来源定量识别

doi: 10.13205/j.hjgc.202209023

  • 1. 临沂大学 资源环境学院 山东省水土保持与环境保育重点实验室, 山东 临沂 276000;

  • 2. 湖南省土壤肥料研究所, 长沙 410125

基金项目: 

湖南省自然科学基金项目(2020JJ5320)

国家自然科学基金项目(41601515)

山东省大学生创新创业训练计划项目(S202110452107)

山东省自然科学基金项目(ZR2021MD105,ZR2016DB20)

详细信息
    作者简介:

    李延雪(2002-),女,主要研究方向为土壤重金属污染评价。liyanxue0719@163.com

    通讯作者:

    焦伟(1985-),男,副教授,主要研究方向为流域重金属污染防控。jiaowei19856261@163.com

    周峻宇(1987-),男,助理研究员,主要研究方向为土壤资源利用与农业生态环境。zhoujunyu@hunaas.cn

QUANTITATIVE IDENTIFICATION OF ANTHROPOGENIC HEAVY METAL SOURCES IN FARMLAND SOIL BASED ON ENRICHMENT FACTOR AND MLR-APCS MODEL

  • 1. Shandong Provincial Key Laboratory of Water and Soil Conservation and Environmental Protection, College of Resources and Environment, Linyi University, Linyi 276000, China;

  • 2. Hunan Soil and Fertilizer Institute, Changsha 410125, China

    摘要
  • 摘要: 准确定量识别农田土壤重金属的人为污染来源对于后续实施精准防控具有重要意义。采集典型农业区土壤样品,基于富集因子法和多元线性回归-绝对主成分得分(MLR-APCS)模型对农田表层土壤重金属的人为来源进行定量识别研究。结果表明:研究区农田表层土壤中Pb、Cu、Zn、Cr、Ni均受到不同程度的人为污染影响,其平均含量相比当地背景土壤分别提高了112.37%、71.21%、59.38%、69.67%和64.54%。5种重金属富集因子顺序为Pb>Cu>Cr>Ni>Zn。其中,Pb总体已达到中等富集水平,来自人为污染源含量占比超过50%。基于人为源重金属含量,大气沉降和有机肥施用被识别为该研究区2种主要人为重金属污染来源。MLR-APCS模拟进一步表明:大气沉降对Pb、Cr、Ni的污染贡献率分别为42.41%、37.58%和37.26%,而有机肥施用对Cu、Zn的污染贡献率分别为41.67%和39.39%。综上,提出了一种可靠的农田土壤重金属人为来源定量识别方法,可推广应用于其他相似区域。
    Abstract: An accurate and quantitative identification of anthropogenic heavy metal sources in farmland soil is vital for the subsequent implementation of more precise prevention and control. In this study, soil samples were collected from a typical agricultural area, and the anthropogenic sources of heavy metals in the surface soils were quantitatively identified by using the enrichment factor(EF) and multiple linear regression of absolute principal component scores(MLR-APCS) model.Resultsshowed that heavy metals like Pb, Cu, Zn, Cr and Ni in the surface soil have been affected by anthropogenic sources to different extents. The average increases rates in Pb, Cu, Zn, Cr and Ni were 112.37%, 71.21%, 59.38%, 69.67% and 64.54% respectively, when comparing their total contents in the surface soils with the contents in the local background soils. The EF values of heavy metals decreased with the order of Pb, Cu, Cr, Ni and Zn. Among them, Pb reached a medium enrichment level, and its anthropogenic content was more than 50% of the total content. Based on the anthropogenic heavy metal contents, atmospheric deposition and livestock manure were identified as the two main anthropogenic heavy metal sources. The MLR-APCS simulation results showed that atmospheric deposition could contribute on average 42.41%, 37.58% and 37.26% of total Pb, Cr and Ni contents, respectively, while livestock manure contributed 41.67% of total Cu and 39.39% of total Zn contents. In general, this study provided a reliable method for quantitative identification of anthropogenic heavy metal sources in farmland soil, which can be applied in other similar areas.
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    • 参考文献(34)
  • [1] SHAO D W,ZHAN Y,ZHOU W J,et al.Current status and temporal trend of heavy metals in farmland soil of the Yangtze River Delta Region:field survey and meta-analysis[J].Environmental Pollution,2016,219:329-336.
    [2] 窦韦强,安毅,秦莉,等.农田土壤重金属垂直分布迁移特征及生态风险评价[J].环境工程,2021,39(2):166-172.
    [3] 郑影怡,刘杰,蒋萍萍,等.河池市某废弃冶炼厂周边农田土壤重金属污染特征及风险评价[J].环境工程,2021,39(5):238-245.
    [4] TOTH G,HERMANN T,da SILVA M R,et al.Heavy metals in agricultural soils of the European Union with implications for food safety[J].Environment International,2016,88:299-309.
    [5] 安外尔·艾力,麦麦提吐尔逊·艾则孜,靳万贵,等.新疆焉耆盆地农田土壤重金属环境容量分析[J].环境工程,2020,38(3):168-173.
    [6] 周江明.中国耕地重金属污染现状及其人为污染源浅析[J].中国土壤与肥料,2020(2):83-92.
    [7] JIAO W,NIU Y,NIU Y,et al.Spatial assessment of the anthropogenic impact on trace metal accumulation in farmland soils from a rapid industrializing region,East China[J].International Journal of Environmental Research and Public Health,2018,15:2052.
    [8] 章明奎,王浩,张慧敏.浙东海积平原农田土壤重金属来源辨识[J].环境科学学报,2008,28(10):1946-1954.
    [9] 李瑞平,郝英华,李光德,等.泰安市农田土壤重金属污染特征及来源解析[J].农业环境科学学报,2011,30(10):2012-2017.
    [10] MICO C,RECATALA L,PERIS A,et al.Assessing heavy metal sources in agricultural soils of an European Mediterranean area by multivariate analysis[J].Chemosphere,2006,65(5):863-872.
    [11] 陈雅丽,翁莉萍,马杰,等.近十年中国土壤重金属污染源解析研究进展[J].农业环境科学学报,2019,38(10):2219-2238.
    [12] 李娇,吴劲,蒋进元,等.近十年土壤污染物源解析研究综述[J].土壤通报,2018,49(1):232-242.
    [13] SHI D Q,LU X W.Accumulation degree and source apportionment of trace metals in smaller than 63 μm road dust from the areas with different land uses:a case study of Xi’an,China[J].Science of the Total Environment,2018,636:1211-1218.
    [14] 霍明珠,高秉博,乔冬云,等.基于APCS-MLR受体模型的农田土壤重金属源解析[J].农业环境科学学报,2021,40(5):978-986.
    [15] 史文昌,古正刚,冯燕,等.基于APCS-MLR的宝象河沉积物重金属污染源解析[J].环境科学与技术,2020,43(10):51-59.
    [16] YANG Y,CHRISTAKOS G,GUO M W,et al.Space-time quantitative source apportionment of soil heavy metal concentration increments[J].Environmental Pollution,2017,223:560-566.
    [17] N’GUESSAN Y M,PROBST J L,BUR T,et al.Trace elements in stream bed sediments from agricultural catchments (Gascogne region,S-W France):where do they come from[J].Science of the Total Environment,2009,407:2939-2952.
    [18] 中华人民共和国农业部.农田土壤环境质量监测技术规范:NY/T 395—2012 [S].北京:中国农业出版社,2012.
    [19] 中华人民共和国环境保护部.土壤和沉积物金属元素总量的消解微波消解法:HJ 832—2017[S].北京:中国环境出版社,2017.
    [20] BLASER P,ZIMMERMANN S,LUSTER J,et al.Critical examination of trace element enrichments and depletions in soils:As,Cr,Cu,Ni,Pb,and Zn in Swiss forest soils[J].Science of the Total Environment,2000,249:257-280.
    [21] NIU L L,YANG F X,XU C,et al.Status of metal accumulation in farmland soils across China:from distribution to risk assessment[J].Environmental Pollution,2013,176:55-62.
    [22] 中华人民共和国生态环境部.土壤环境质量农用地土壤污染风险管控标准:GB 15618—2018 (试行)[S].北京:中国环境出版社,2018.
    [23] SUTHERLAND R A.Bed sediment-associated trace metals in an urban stream,Oahu,Hawaii[J].Environmental geology,2000,39:611-627.
    [24] PALLEIRO L,PATINHA C,RODRIGUEZ-BLANCO M L,et al.Metal fractionation in topsoils and bed sediments in the Mero River rural basin:bioavailability and relationship with soil and sediment properties[J].Catena,2016,144:34-44.
    [25] ZHAO L S,YAN Y,YU R L,et al.Source apportionment and health risks of the bioavailable and residual fractions of heavy metals in the park soils in a coastal city of China using a receptor model combined with Pb isotopes[J].Catena,2020,194:104736.
    [26] 焦伟,牛勇,李斌,等.基于化学形态分析的城市道路灰尘重金属健康风险评价与人为来源解析[J].生态环境学报,2018,27(12):2269-2275.
    [27] HU Y A,CHENG H F.A method for apportionment of natural and anthropogenic contributions to heavy metal loadings in the surface soils across large-scale regions[J].Environmental Pollution,2016,214:400-409.
    [28] LOCKITCH G.Perspectives on lead toxicity[J].Clinical Biochemistry,1993,26:371-381.
    [29] 刘娟,李洋,张敏,等.滇东农田土壤铅污染健康风险评价及基准研究[J].农业工程学报,2021,37(1):241-250.
    [30] LUO L,MA Y B,ZHANG S Z,et al.An inventory of trace element inputs to agricultural soils in China[J].Journal of Environmental Management,2009,90:2524-2530.
    [31] 陆平,赵雪艳,殷宝辉,等.临沂市 PM2.5和PM10中元素分布特征及来源解析[J].环境科学,2020,41(5):2036-2043.
    [32] 张国忠,黄威,潘月鹏,等.河北典型农田大气重金属干沉降通量及来源解析[J].中国生态农业学报,2019,27(8):1245-1254.
    [33] DACH J,STARMANS D.Heavy metals balance in Polish and Dutch agronomy:actual state and previsions for the future[J].Agriculture,Ecosystems & Environment,2005,107:309-316.
    [34] JIAO W,NIU Y,NIU Y,et al.Quantitative identification of anthropogenic trace metal sources in surface river sediments from a hilly agricultural watershed,East China[J].Environmental Science and Pollution Research,2019,26:32266-32275.
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  • 收稿日期:  2021-11-19
  • 网络出版日期:  2022-11-09

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