连续流分段进水短程反硝化-厌氧氨氧化耦合工艺的反硝化脱氮特性

张树军; 黄剑明; 马淑勍; 王聪; 田夏迪; 李琨; 赵丹; 韩晓宇

doi:10.13205/j.hjgc.202211002

连续流分段进水短程反硝化-厌氧氨氧化耦合工艺的反硝化脱氮特性

doi: 10.13205/j.hjgc.202211002

张树军^1,2,
黄剑明^1,2,3,
马淑勍²,
王聪^1,2,
田夏迪^1,2,
李琨^1,2,
赵丹^1,2,
韩晓宇^1,2, ,

1. 北京市资源化工程技术研究中心, 北京 100124;
2. 北京城市排水集团有限责任公司, 北京 100044;
3. 北京北排科技有限公司, 北京 100044

基金项目:

北京市科技计划项目（Z181100005518003）

详细信息

作者简介:
张树军(1970-),男,教授级高工,主要研究方向为污水生物处理理论与技术。bdc_amx@126.com

通讯作者:
韩晓宇(1984-),男,高工,主要研究方向为污水生物处理理论与技术。hanxiaoyu@bdc.cn

计量
- 文章访问数: 97
- HTML全文浏览量: 12
- PDF下载量: 7
- 被引次数: 0
出版历程
- 收稿日期: 2022-07-05
- 网络出版日期: 2023-03-24

NITROGEN REMOVAL CHARACTERISTICS OF A STEP-FEED CONTINUOUS FLOW PARTIAL DENITRIFICATION-ANAEROBIC AMMONIUM OXIDATION COUPLED WITH DENITRIFICATION PROCESS

ZHANG Shujun^1,2,
HUANG Jianming^1,2,3,
MA Shuqing²,
WANG Cong^1,2,
TIAN Xiadi^1,2,
LI Kun^1,2,
ZHAO Dan^1,2,
HAN Xiaoyu^{1,2
, ,}

1. Beijing Engineering Research Center of Wastewater Resource, Beijing 100124, China;
2. Beijing Drainage Group Co., Ltd, Beijing 100044, China;
3. Beijing Drainage Technology Co., Ltd, Beijing 100044, China

摘要

摘要: 采用连续流分段进水短程反硝化-厌氧氨氧化（partial denitrification-anaerobic ammonium oxidation，PD-Anammox）耦合反硝化工艺处理低C/N生活污水，研究了污染物去除、典型周期COD及氮素沿程变化特征、短程反硝化-厌氧氨氧化和反硝化对TN去除贡献。结果表明：在平均进水ρ（COD）、ρ（NH₄⁺-N）、ρ（TN）为193.1，58.6，60.3 mg/L的条件下，系统出水平均ρ（COD）、ρ（NH₄⁺-N）、ρ（TN）分别为46.3，1.5，13.4 mg/L，低于GB 18918—2002《城镇污水处理厂污染物排放标准》一级A标准。采用NO₃^--N预缺氧和进水点后置，可实现缺氧区NO₃^--N→NO₂^--N转化，同时完成厌氧氨氧化过程；缺氧区设置厌氧氨氧化悬浮填料，可提高系统TN去除率。通过缺氧区物料衡算，缺氧1区厌氧氨氧化对TN去除贡献率（ΔPD-Anammox/ΔTN）均值为54.37%，缺氧2区的ΔPD-Anammox/ΔTN均值为64.17%。
- 分段进水 /
- 连续流 /
- 短程反硝化-厌氧氨氧化 /
- 预缺氧 /
- 贡献率
Abstract: The low C/N domestic sewage was treated by a step-feed continuous flow partial denitrification-anaerobic ammonium oxidation (PD-Anammox) process coupled with denitrification, the pollutants' removal characteristics, pollutants' concentrations in different stages of the system at a typical operation cycle, and total nitrogen(TN) removal contribute efficiencies of PD-anammox and denitrification were studied. The results showed that when the average influent concentrations of COD, NH₄⁺-N, and TN were 193.1, 58.6 and 60.3 mg/L respectively, their effluent concentrations were 46.3, 1.5, and 13.4 mg/L respectively, complying with the first level A criteria specified in the Discharge Standard of Pollution for Municipal Wastewater Treatment Plants (GB 18918-2002). The nitrate transformed to nitrite in anoxic by nitrate pre-starvation and post-inlet to provide the anammox matrix of nitrite and ammonium. The TN efficiency got improved by setting anammox filler in the anoxic zones. The average PD-Anammox process's contribution rates to TN removal of anoxic zone Ⅰ and Ⅱ were 54.37% and 64.17% respectively, through mass balance calculation at the anoxic zones.
- step-feed /
- continuous flow /
- PD-Anammox /
- pre starvation /
- contribution rates

HTML全文

参考文献(19)

[1]	LIJO L, MALAMIS S, GONZALEZ-GARCIA S, et al. Technical and environmental evaluation of an integrated scheme for the co-treatment of wastewater and domestic organic waste in small communities[J]. Water Research, 2017, 109:173-185.
[2]	ALI M,OKABE S. Anammox-based technologies for nitrogen removal:advances in process st and remaining issues[J]. Chemosphere, 2015, 141:144-153.
[3]	李航,董立春,吕利平.强化脱氮工艺在污水处理中的研究与应用进展[J].工业水处理,2021,41(8):20-24 ,91.
[4]	袁忠玲,秦彦荣,张民安,等.曝气参数对短程硝化的影响及氮素等高线分析[J].中国环境科学,2021,41(2):650-659.
[5]	巩有奎,李永波,彭永臻.不同曝气方式下亚硝化反应器的启动及N₂O释放[J].工业水处理,2019,39(4):21-24 ,57.
[6]	HENDRIKUS J. LAANBROE K, SASKIA G. Competition for limiting amounts of oxygen between Nitrosomonas europaea and Nitrobacter winogradskyi grown in mixed continuous cultures[J]. Archives of Microbiology, 1993, 159(5):453-459.
[7]	BLACKBURNE R, VADIVELU V M, YUAN Z G, et al. Kinetic characterization of an enriched Nitrospira culture with comparison to Nitrobacter[J]. Water Research, 2007, 41(14):3033-3042.
[8]	WANG Z, ZHANG L, ZHANG F Z, et al. Nitrite accumulation in comammox-dominated nitrification-denitrification reactors:effects of DO concentration and hydroxylamine addition[J]. Journal of Hazardous Materials, 2020, 384:121357.
[9]	李捷,徐浩,罗凡,等.城市生活污水短程硝化的两个关键控制因素研究[J].给水排水,2018,54(6):29-32.
[10]	钱光磊,谢陈鑫,赵慧,等.限时曝气下pH对SBR亚硝化快速启动及其过程影响[J].工业水处理,2018,38(1):23-27.
[11]	彭永臻,李璐凯,李夕耀,等.不同pH值及碱性物质对短程硝化的影响[J].北京工业大学学报,2017,43(10):1554-1562.
[12]	XU X X, MA B, LU W K, et al. Effective nitrogen removal in a granule-based partial-denitrification/anammox reactor treating low C/N sewage[J].Bioresource Technology, 2020,297:122167.
[13]	DU R, PENG Y Z, JI J T, et al. Partial denitrification providing nitrite:opportunities of extending application for anammox[J]. Environment International,2019,131,105001.
[14]	CAO S B, DU R, ZHANG H Y, et al. Understanding the granulation of partial denitrification sludge for nitrite production[J].Chemosphere,2019,236:124389.
[15]	APHA. Standard methods for the examination of water and wastewater[M].21st ed. Washington, DC:American Public Health Association,2007.
[16]	FERNÁNDEZ-NAVA Y, MARAÑÓN E, SOONS J, et al. Denitrification of high nitrate concentration wastewater using alternative carbon sources[J]. Journal of Hazardous Materials, 2010, 173(1/2/3):682-688.
[17]	ZHANG Z Z, ZHANG Y, CHEN Y G.Recent advances in partial denitrification in biological nitrogen removal:from enrichment to application[J].Bioresource Technology,2020,298:122444.
[18]	MAITE P, ANNA RIBERA-GUARDIA, JOSE L B, et al. Effect of COD on mainstream anammox:evaluation of process performance, granule morphology and nitrous oxide production[J]. Science of the Total Environment,2020,712:136372.
[19]	KORNAROS M, ZAFIRI C, LYBERATOS G. Kinetics of denitrification by Pseudomonas denitrificans under growth conditions limited by carbon and/or nitrate or nitrite[J]. Water Environment Research, 1996, 68(5):934-945.