PREPARATION OF SOLID WASTE-BASED SOIL CONDITIONERS AND THEIR ECOLOGICAL REMEDIATION EFFECTS ON THE MINING AREA
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摘要: 我国煤矸石产量大,利用率偏低,大量堆积没有得到合理利用,造成了土地资源浪费和严重的环境污染。以煤矸石为主要原料,通过添加铝粉发泡养护得到多孔材料,再将其与废弃有机质以及含碳辅料发酵制成固废基土壤调理剂。对比探究喷播固废基土壤调理剂(SWSC)、丛枝菌根真菌(AMF)和固废基土壤调理剂耦合菌根真菌(SWSC+AMF)的土壤理化性质以及对矿区典型植物生长的影响,研究不同处理下植物中重金属的累积量。结果表明:固废基土壤调理剂的优选配方为:当煤矸石和水泥掺比为85%∶15%时,制备的多孔材料性能最优;优选鸡粪和风化煤作为有机质和含碳辅料;当多孔颗粒、鸡粪与风化煤的质量配比为4∶2∶4时,制备的固废基土壤剂调理剂最优。对土壤调理剂的制备及应用全流程进行重金属安全性评价,重金属含量均低于国家标准中重金属的限定值。喷播SWSC+AMF的土壤中有机质含量为35.24 mg/kg,速效钾含量为261 mg/kg,有效磷含量为278 mg/kg,碱性磷酸酶含量可达到293.07 mg/kg,且喷播SWSC+AMF对披碱草的株高和根长生成具有促进作用,可有效减少对披碱草中重金属Cd、Pb、Ni的累积,同时对改善土壤结构,提升土壤肥力方面有积极作用。Abstract: In China, the output of coal gangue is large, and the utilization rate is low. A large amount of accumulation has not been reasonably utilized, resulting in the wasting of land resources and environmental pollution. In this paper, coal gangue was used as the main raw material, and porous materials were obtained by adding aluminum powder for foaming and curing, and then fermented with waste organic matter and carbon-containing auxiliary materials to make solid waste-based soil conditioners. The soil physicochemical properties of spraying solid waste-based soil conditioner (SWSC), arbuscular mycorrhizal fungi (AMF) and solid waste-based soil conditioner coupled with mycorrhizal fungi (SWSC+AMF), and their effects on the growth of typical plants in the mining area were compared. The accumulation of heavy metals in plants under different treatments was compared. A proportion of gangue and cement at 85%∶15% was best for making the porous material. Chicken manure and weathered coal were selected as organic matter and carbon excipients. When the ratio of porous particles, chicken manure and weathered coal was 4∶2∶4, the prepared solid waste-based soil conditioner was the best. When the mass ratio of porous particles, chicken manure and weathered coal was 4∶2∶4, the prepared solid waste-based soil agent conditioner was the best. The whole process of preparation and application of soil conditioners was evaluated for heavy metal safety, and the heavy metal content met the limit values in the corresponding national standards. The content of organic matter in the soil sprayed with SWSC+AMF was 35.2 mg/kg, the content of available potassium and available phosphorus was 261 mg/kg and 278 mg/kg, and the content of alkaline phosphatase could reach 293.07 mg/kg. Moreover, spraying SWSC+AMF could promote the growth of plant height and root length, which can effectively reduce the accumulation of Cd, Pb and Ni element in Elymus grass, and improve soil structure and fertility.
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Key words:
- gangue /
- soil conditioner /
- mycorrhizal fungi /
- heavy metal /
- ecological restoration
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[1] 黄伟, 杨凯, 张乾, 等.橡胶补强填料中煤矸石活化改性的研究进展[J].洁净煤技术,2022,28(1):166-174. [2] LIU H B, LIU Z L. Recycling utilization patterns of coal mining waste in China[J]. Resources Conservation & Recycling, 2010, 54(6):1331-1340. [3] 程蓉, 廖祥文, 舒荣波, 等. 利用硅酸盐细菌制备煤矸石矿物肥料[J]. 矿产综合利用, 2017(6):115-118. [4] LONG J, ZHANG S X, LUO K L. Selenium in Chinese coal gangue:distribution, availability, and recommendations[J]. Resources, Conservation & Recycling, 2019, 149:140-150. [5] 张殿云, 秦宪英, 邵淑杰, 等. 利用煤矸石生产生物复合肥料研究[C]//2003年内蒙古自治区自然科学学术年会论文集. 呼和浩特:内蒙古科学技术出版社, 2003:68-70. [6] BLAGODATSKAYA E, KUZYAKOV Y. Active microorganisms in soil:critical review of estimation criteria and approaches[J]. Soil Biology & Biochemistry, 2013, 67(67):192-211. [7] 王顺, 陈敏, 陈孝杨, 等. 煤矸石充填重构土壤水分再分布与剖面气热变化试验研究[J].水土保持学报, 2017, 31(4):93-98,126. [8] 黄俊达.土壤在中国海绵城市建设中的作用研究进展综述[J]. 风景园林, 2017(9):106-112. [9] 毕银丽, 龚云丽, 杨惠惠, 等. 微生物复垦区接菌沙棘叶绿素含量光谱估测[J]. 中国矿业大学学报, 2021,50(1):190-196. [10] 苏迪, 高宏宇, 廖洪强,等. 孔土壤与天然土壤特性对比研究[J].矿产保护与利用,2020,40(3):106-109. [11] 宋慧平, 傅垣洪, 冯政君,等. 一种固废基多孔材料、制备及用于煤矸石山生态修复方法[P].2021-10-11. [12] 国家质量监督检验检疫总局,国家标准化管理委员会. 轻集料及其试验方法. 第2部分:轻集料试验方法:GB/T 17431.2-2010[S]. 2010. [13] 卢锦斌, 张利敏, 徐秀容, 等. 改良凯氏定氮法的研究进展[J]. 家畜生态学报, 2020, 41(12):84-87. [14] 韩张雄, 李敏, 杨树俊, 等.土壤中有效磷的快速测定方法[J]. 农业与技术, 2021, 41(13):33-35. [15] 徐国华, 鲍士旦. 不同作物的吸钾能力及其与根系参数的关系[J].南京农业大学学报, 1995, 18(1):49-52. [16] 郝国辉, 邵劲松. 土壤有机质含量测定方法的改进研究[J].农业环境学报, 2014, 31(2):202-204. [17] 鲁如坤. 土壤农化分析[M]. 北京:中国农业科技出版社, 2000. [18] 苏文渐. 生活垃圾焚烧飞灰浸出毒性适宜方法的研究[J]. 广东化工, 2018, 45(19):64-65. [19] 生态环境部,国家市场监督管理局.土壤环境质量 农用地土壤污染风险管控标准(试行):GB 15618-2018[S]. 北京:中国环境科学出版社, 2018. [20] 国家环境保护总局,国家质量监督检验检疫总局. 危险废物鉴别标准:浸出毒性鉴别:GB 5085.3-2007[S]. 北京:中国环境科学出版社, 2007. [21] 黄晓红, 顾黄辉, 许福涛, 等. 浅析NY 525-2012《有机肥料》技术指标标识方法的修订[J].上海蔬菜, 2015 (5):21-23. [22] 高科, 郭宗昊, 薛晨, 等. 生物炭与炭基肥对采煤塌陷复垦区土壤硝化和反硝化微生物群落的影响[J]. 应用生态学报, 2021, 32(8):2949-2957. [23] 陈伏生, 曾德慧, 陈广生, 等. 风沙土改良剂对白菜生理特性和生长状况的影响[J]. 水土保持学报, 2003,17(2):152-155. [24] EVELIN H, GIRI B. Contribution of Glomus intraradices inoculation to nutrient acquisition and mitigation of ionic imbalance in NaCl-stressed Trigonella foenum-graecum[J]. Mycorrhiza, 2011, 22(16):203-217. [25] ZHANG L, XU M G, LIU Y, et al. Carbon and phosphorus exchange may enable cooperation between an arbuscular mycorrhizal fungus and a phosphate-solubilizing bacterium[J]. New Phytologist, 2016, 210(2):1022-1032. [26] 祁娟, 姚拓, 白小明, 等. 复合菌肥替代部分磷肥对苜蓿草地生产力及土壤肥力的影响[J]. 草业学报, 2017, 26(10):118-128. [27] 李莹飞, 耿玉清, 周红娟, 等. 基于不同方法测定土壤酸性磷酸酶活性的比较[J]. 中国生态农业学报, 2016, 24(1):98-104. [28] 杜倩, 黄容, 李冰, 等. 生物炭还田对植烟土壤活性有机碳及酶活性的影响[J]. 核农学报, 2021, 35(6):1440-1450. [29] 悦飞雪, 李继伟. 生物炭和AM真菌提高矿区土壤养分有效性的机理[J].植物营养与肥料学报, 2019, 25(8):1325-1334. [30] 李立青, 张明生, 梁作盼, 等. 丛枝菌根真菌促进入侵植物紫茎泽兰的生长和对本地植物竞争效应[J]. 生态学杂志, 2016, 35(1):79-86. [31] 孙吉庆,刘润进, 李敏, 等. 丛枝菌根真菌提高植物抗逆性的效应及其机制研究进展[J]. 植物生理学报, 2012, 48(9):845-852. [32] SONG X M, RAZAVI B S, LUDWIG B, et al. Combined biochar and nitrogen application stimulates enzyme activity and root plasticity[J]. Science of the Total Environment, 2020, 735(3):139393. [33] BONA E, CANTAMESSA S, MASSAN, et al. Arbuscular mycorrhizal fungi and plant growth-promoting pseudomonads improve yield, quality and nutritional value of tomato:a field study[J]. Mycorrhiza, 2016, 27(5):1-11. [34] FAN H M, WANG X M, SUN X, et al. Effects of humic acid derived from sediments on growth, photosynthesis and chloroplast ultrastructure in chrysanthemum[J]. Scientia Horticulturae, 2014, 177(6):118-123. [35] 陈保冬, 张莘, 伍松林, 等.丛枝菌根影响土壤-植物系统中重金属迁移转化和累积过程的机制及其生态应用[J]. 岩矿测试, 2019, 38(1):1-25. [36] RASK AK, JOHANSEN JL, K R, et al. Differences in arbuscular mycorrhizal colonisation influence cadmium uptake in plants[J]. Environmental and Experimental Botany, 2019, 162(6):223-229. [37] CHEN B D, LI X L, TAO H Q, et al. The role of arbuscular mycorrhiza in zinc uptake by red clover growing in a calcareous soil spiked with various quantities of zinc[J]. Chemosphere, 2003, 50(9):839-846. [38] SUN J Q, LIU R J, LI M, et al. Advances in the study of increasing plant stress resistance and mechanisms by arbuscular mycorrhizal fungi[J]. Plant Physiology Journal, 2012(4):845-852.
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