RESEARCH ON TREATMENT PERFORMANCE AND DYNAMICS OF ZINC CONTAINING WASTEWATER BY SPRAY BED ELECTRO-DEPOSITION
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摘要: 采用自主设计的喷射床电沉积装置处理模拟采矿含锌废水。通过改变喷射床电沉积处理过程的pH值、电流强度、含锌废水浓度以及鼓入氮气等实验参数,研究不同处理条件下喷射床电沉积反应器对含锌废水的处理效果。结果表明:废水Zn2+浓度为1000 mg/L时,采用粒径为1.8 mm铜微粒电极,反应过程pH值为4.5,恒电流强度为15 A,向废水中鼓入600 L/h氮气的条件下处理效果最好,电沉积反应180 min后,Zn2+去除率达到49.44%,平均电流效率为41.63%。并以实验结论为基础,通过动力学模拟分析,建立了单金属离子电沉积过程的动力学模型,验证了实验结果的可靠性和准确性。Abstract: Experiments were carried out by using self-designed spray bed electro-deposition devices to treat zinc-containing wastewater under different conditions including pH value, current intensity, zinc ions concentration and bubbling nitrogen. The effect of the spray bed electro-deposition system on treatment of zinc-containing wastewater was investigated and the parameters were optimized. The results showed that the optimized condition was as follows:the particle size of electrode of 1.8 mm, zinc ions concentration of 1000 mg/L, wastewater pH value of 4.5, current value of 15 A and bubbling nitrogen of 600 L/h, then the removal rate of zinc ions was up to 49.44% and the current efficiency was 41.63%. On this basis, the dynamic model of single metal ion electro-deposition was established by dynamic simulation analysis, which proved the reliability of the measured data and the accuracy of the experimental results.
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Key words:
- spray bed /
- electro-deposition /
- zinc-containing wastewater /
- particle electrode /
- dynamic simulation
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[1] 黄俊文. 铅锌选矿废水净化处理与循环回用试验研究[J]. 矿冶工程,2021,41(3):64-67. [2] 向中兰. 补锌过量对人体的危害[J]. 现代医药卫生,2001,17(9):727. [3] XU Z, ZHANG Q R, LI X C, et al. A critical review on chemical analysis of heavy metal complexes in water/wastewater and the mechanism of treatment methods[J]. Chemical Engineering Journal,2022,429:131688. [4] 于栋,罗庆,苏伟,等. 重金属废水电沉积处理技术研究及应用进展[J]. 化工进展,2020,39(5):1938-1949. [5] 崔志新,任庆凯,艾胜书,等. 重金属废水处理及回收的研究进展[J]. 环境科学与技术,2010,33(12):375-377. [6] THILAKAVATHI R,BALASUBRAMANIAN N,BASHA C A. Modeling electrowinning process in an expanded bed electrode[J]. Journal of Hazardous Materials,2009,162(1):154-160. [7] GRIMSHAW P, CALO J M, HRADIL G. Co-electrodeposition/removal of copper and nickel in a spouted electrochemical reactor[J]. Industrial & Engineering Chemistry Research,2011,50(16):9532-9538. [8] GONZÁLEZ M A, TRÓCOLI R, PAVLOVIC I, et al. Capturing Cd(Ⅱ) and Pb(Ⅱ) from contaminated water sources by electro-deposition on hydrotalcite-like compounds[J]. Physical Chemistry Chemical Physics,2016,18(3):1838-1845. [9] YA V, MARTIN N, CHOU Y, et al. Efficient Cu removal from CuEDTA complex-containingwastewaterusing electrochemically controlled sacrificial iron anode[J]. Chemosphere,2021,264(2):128573. [10] 胡美清,金伟. 电吸附-电沉积联合作用下的低浓度铜离子分离[J]. 过程工程学报,2021,21(8):976-984.
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