全光谱条件下WO<sub>3-<i>x</i></sub>光催化降解甲氧苄啶

陈书鑫; 周菁清; 孙琴琴; 王昆; 刘铮铮; 余磊; 刘劲松; 王静

doi:10.13205/j.hjgc.202302019

全光谱条件下WO_3-x光催化降解甲氧苄啶

doi: 10.13205/j.hjgc.202302019

陈书鑫^1,2,
周菁清^1,2,
孙琴琴^1,2,
王昆³,
刘铮铮^1,2,
余磊^1,2,
刘劲松^1,2,
王静^1,2, ,

1. 浙江省生态环境监测中心, 杭州 310012;
2. 浙江省生态环境监测预警及质控研究重点实验室, 杭州 310012;
3. 浙江大学环境科学系, 杭州 310058

基金项目:

浙江省生态环境科研和成果推广项目(2021XM0006,2021HT0004)

浙江省科技计划项目(2021C03176)

详细信息

作者简介:
陈书鑫(1995-),男,硕士,助理工程师,主要研究方向为有机污染物环境监测与评价。1412240161@qq.com

通讯作者:
王静(1978-),女,教授级高工,主要研究方向为有机污染物环境监测与评价。348417706@qq.com

计量
- 文章访问数: 144
- HTML全文浏览量: 26
- PDF下载量: 3
- 被引次数: 0
出版历程
- 收稿日期: 2022-03-31
- 网络出版日期: 2023-05-25
- 刊出日期: 2023-02-01

PHOTOCATALYTIC DEGRADATION OF TRIMETHOPRIM BASED ON WO_3-x UNDER FULL SPECTRUM

CHEN Shuxin^1,2,
ZHOU Jingqing^1,2,
SUN Qinqin^1,2,
WANG Kun³,
LIU Zhengzheng^1,2,
YU Lei^1,2,
LIU Jinsong^1,2,
WANG Jing^{1,2
, ,}

1. Zhejiang Ecological and Environmental Monitoring Center, Hangzhou 310012, China;
2. Zhejiang Key Laboratory of Ecological and Environmental Monitoring, Forewarning and Quality Control, Hangzhou 310012, China;
3. Department of Environmental Science, Zhejiang University, Hangzhou 310058, China

摘要

摘要: 光催化作为一项绿色、高效的污染物治理技术,其传统光催化材料缺少对全光谱中红外光区的利用,会在一定程度上造成资源的浪费,限制了污染物降解能力上限。因此,利用WO_3-x光催化降解甲氧苄啶(TMP),探索了不同光谱下的降解性能以及在最优降解条件下的降解机理。结果表明:黑暗和红外光条件下,TMP几乎未发生降解。全光谱条件下TMP的降解率相较于紫外-可见光提高44.8%。2种体系中WO_3-x光催化反应降解TMP的机理较为相似,O^-₂·和H₂O₂是发挥主要作用的活性物种。在降解过程中,大量的活性自由基在催化剂表面产生,然后进入均相体系,促进TMP降解;同时,WO_3-x对全光谱中红外光区间段的有效吸收展现出优异的降解能力。此外,温度在反应体系中并不是提升降解率的主导因素。
- 光催化 /
- 全光谱 /
- 甲氧苄啶 /
- 氢化氧化钨
Abstract: Photocatalysis is a green and efficient pollutant treatment technology. The lack of utilization of the mid-infrared light region by traditional photocatalytic materials causes a waste of resources and limits the upper limit of pollutants' degradation efficiency. This study used photocatalytic degradation of TMP based on WO_3-x to explore the degradation performance under different spectra and the degradation mechanism under the optimal degradation condition. The results showed that TMP was hardly degraded under dark and infrared light conditions. Compared with UV-visible light, the degradation of TMP under full spectrum conditions was increased by 44.8%. The mechanism of TMP degradation by WO_3-x photocatalytic reaction in the two systems was similar, and O^-₂· and H₂O₂ were the active species that played the main role. During the degradation process, a large number of active radicals were generated on the catalyst surface and then entered the homogeneous system to promote the degradation of TMP. At the same time, temperature was not the dominant factor in improving the degradation rate in the reaction system, because WO_3-x exhibited excellent degradation ability due to the effective absorption of the mid-infrared light region of the full spectrum.
- photocatalysis /
- full-spectrum /
- trimethoprim /
- WO_3-x

HTML全文

参考文献(28)

[1]	朱昊, 韦起壮, 陈云, 等. 硫酸头孢喹肟联合甲氧苄啶作用下金黄色葡萄球菌体外药效及适应性耐药研究[J]. 黑龙江畜牧兽医, 2021(17):1-5.
[2]	YANG J F, YING G G, ZHAO J L, et al. Spatial and seasonal distribution of selected antibiotics in surface waters of the Pearl Rivers, China[J]. Journal of Environmental Science & Health Part B, 2011, 46(3):272-280.
[3]	JU H, ZHANG J, SUN C. Occurrence, spatial distribution and risk and hazard assessments of antibiotics in drinking water sources of a polluted large river basin in China[J]. Aquatic Ecosystem Health & Management, 2017,21(1):107-117.
[4]	ABOU-EISHA A. Evaluation of cytogenetic and DNA damage induced by the antibacterial drug, trimethoprim[J]. Toxicology in Vitro, 2006, 20(5):601-607.
[5]	郑恒, 丁水平. 液相色谱-串联质谱法测定人血浆中磺胺甲噁唑和甲氧苄啶的浓度[J]. 中国临床药理学杂志, 2020, 36(18):2901-2904 , 2935.
[6]	KONG J, LI R B, WANG F L, et al. Sulfate radical-induced transformation of trimethoprim with CuFe₂O₄/MWCNTs as a heterogeneous catalyst of peroxymonosulfate:mechanisms and reaction pathways[J]. RSC Advances, 2018, 8(44):24787-24795.
[7]	MICHAEL I, HAPESHI E, MICHAEL C, et al. Superiority of solar Fenton oxidation over TiO₂ photocatalysis for the degradation of trimethoprim in secondary treated effluents[J]. Water Science and Technology, 2013, 67(6):1260-1271.
[8]	贺全宝, 胡征, 葛明. BiOX(X=Cl,Br,I)复合光催化材料降解水体中抗生素研究进展[J]. 应用化学, 2021, 38(7):754-766.
[9]	马瑞霄, 周浩, 张燕辉. RGO-ZnO光催化降解抗生素及还原Cr(Ⅵ)的研究[J]. 工业水处理, 2021, 41(3):53-56.
[10]	PATEL P, KUMAR D, GANANADHAMU S, R. Srinivas, characterization of the stress degradation products of tolvaptan by UPLC-Q-TOF-MS/MS[J]. RSC Advances, 2015, 5(27):21142-21152.
[11]	WINGERT N R, SANTOS N O, NUNES A G, et al. Characterization of three main degradation products from novel oral anticoagulant rivaroxaban under stress conditions by UPLC-Q-TOF-MS/MS[J]. Journal of Pharmaceutical & Biomedical Analysis, 2016,1:10-15.
[12]	张素娟, 段世祥, 陈高礼, 等. MoS₂/Zn₃In₂S₆复合光催化剂构建:高效提升可见光驱动甲酸制氢[J]. 催化学报, 2021, 42(1):193-204.
[13]	巫杨, 贾赟婧, 吴筱原, 等.紫外光催化降解水溶液中甲氧苄氨嘧啶的实验研究[J]. 2015, 4(2):32-36.
[14]	TIAN J, SANG Y H, YU G W, et al. A Bi₂WO₆-based hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation[J]. Advanced Materials, 2013, 25(36):5074.
[15]	龚洁, 赵凤怡, 邹曦, 等. g-C₃N₄/Ag₂O复合光催化剂的制备及其近红外光催化性能[J]. 武汉科技大学学报, 2021, 44(2):100-106.
[16]	丁倩, 陈涛, 李政, 等. Cr₂O₃-Rh/Ga₂O₃光催化分解水的时间分辨红外光谱研究[J]. 催化学报, 2021, 42(5):818-816.
[17]	张代生. 上转换微纳米晶@TiO₂核/壳结构红外光催化材料的制备和表征[D]. 长春:吉林大学, 2011.
[18]	RAMIS G, CRISTIANI C, ELMI A S, et al. Characterization of the surface properties of polycrystalune WO₃[J]. Journal of Molecular Catalysis, 1990, 61(3):319-331.
[19]	BAZARJANI M S, HOJAMBERDIEV M, MORITA K, et al. Visible light photocatalysis with c-WO_3-x/WO₃×H₂O nanoheterostructures in situ formed in mesoporous polycarbosilane-siloxane polymer[J]. Journal of the American Chemical Society, 2013, 135(11):4467-4475.
[20]	SHEN Z G, ZHAO Z Y, QIAN J W, et al. Synthesis of WO_3-x nanomaterials with controlled morphology and composition for highly efficient photocatalysis[J]. Journal of Materials Research, 2016, 31(8):1065-1076.
[21]	YAN M, LI G L, GUO C S, et al. WO_3-x sensitized TiO₂ spheres with full-spectrum-driven photocatalytic activities from UV to near infrared[J]. Nanoscale, 2016, 8(41):17828-17835.
[22]	费学宁, 崔良福, 申丛丛, 等. TiO₂纳米颗粒在甲醇-水溶液中对3,4-二氯硝基苯的光催化性能[J]. 环境工程学报, 2021, 15(5):1509-1518.
[23]	黄有鹏, 吴福礼, 李兵, 等. WO₃/g-C₃N₄复合光催化剂制备及其可见光催化性能[J]. 复合材料学报, 2021, 38(12):4265-4272.
[24]	张华, 张子鹏, 张澜澜, 等. H₂O₂强化光催化处理苯胺化工废水的应用试验[J]. 化工进展, 2020, 39(12):5299-5308.
[25]	HE Y P, ZHAO Y P. Near-infrared laser-induced photothermal coloration in WO₃·H₂O nanoflakes[J]. The Journal of Physical Chemistry C, 2008, 112(1):61-68.
[26]	SIRTORI C, AGUEERA A, GERNJAK W, et al. Effect of water-matrix composition on Trimethoprim solar photodegradation kinetics and pathways[J]. Water Research, 2010, 44(9):2735-2744.
[27]	JI Y F, XIE W P, YAN F, et al. Degradation of trimethoprim by thermo-activated persulfate oxidation:reaction kinetics and transformation mechanisms[J]. Chemical Engineering Journal, 2016, 286(10):16-24.
[28]	ZHANG R C, Sun P Z, BOYER T H, et al. Degradation of pharmaceuticals and metabolite in synthetic human urine by UV, UV/H₂O₂, and UV/PDS[J]. Environmental Science & Technology, 2015, 49(5):3056-3066.