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淀粉纳米晶接枝聚乙烯亚胺对阴离子染料的吸附

陈启杰 梁春艳 赵雅兰 游娜 谢广阳 魏雅琴 郑小玲

陈启杰, 梁春艳, 赵雅兰, 游娜, 谢广阳, 魏雅琴, 郑小玲. 淀粉纳米晶接枝聚乙烯亚胺对阴离子染料的吸附[J]. 环境工程, 2023, 41(3): 57-64. doi: 10.13205/j.hjgc.202303008
引用本文: 陈启杰, 梁春艳, 赵雅兰, 游娜, 谢广阳, 魏雅琴, 郑小玲. 淀粉纳米晶接枝聚乙烯亚胺对阴离子染料的吸附[J]. 环境工程, 2023, 41(3): 57-64. doi: 10.13205/j.hjgc.202303008
CHEN Qijie, LIANG Chunyan, ZHAO Yalan, YOU Na, XIE Guangyang, WEI Yaqin, ZHENG Xiaoling. ADSORPTION OF ANIONIC DYES BY STARCH NANOCRYSTALS GRAFTED POLYETHYLENEIMINE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(3): 57-64. doi: 10.13205/j.hjgc.202303008
Citation: CHEN Qijie, LIANG Chunyan, ZHAO Yalan, YOU Na, XIE Guangyang, WEI Yaqin, ZHENG Xiaoling. ADSORPTION OF ANIONIC DYES BY STARCH NANOCRYSTALS GRAFTED POLYETHYLENEIMINE[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(3): 57-64. doi: 10.13205/j.hjgc.202303008

淀粉纳米晶接枝聚乙烯亚胺对阴离子染料的吸附

doi: 10.13205/j.hjgc.202303008
基金项目: 

长沙理工大学研究生科研创新项目(CXCLY2022122)

湖南省教育厅科研项目(22A0208)

湖南省高新技术产业科技创新引领计划项目(2021GK4040)

湖南省企业科技创新创业团队项目(201918)

详细信息
    作者简介:

    陈启杰(1980-),男,博士,教授,主要研究方向为生物基吸附材料。chenqijie@126.com

    通讯作者:

    陈启杰(1980-),男,博士,教授,主要研究方向为生物基吸附材料。chenqijie@126.com

ADSORPTION OF ANIONIC DYES BY STARCH NANOCRYSTALS GRAFTED POLYETHYLENEIMINE

  • 摘要: 以戊二醛为交联剂、淀粉纳米晶(SNCs)为基材接枝聚乙烯亚胺(PEI),成功制备了一种新型生物基吸附剂(SNCs-PEI)。利用粒径、Zeta电位、红外光谱(FTIR)和能量色散X射线谱(EDX)对SNCs-PEI进行表征,并探究其对阴离子染料的吸附效果。当pH=3时,SNCs-PEI 的Zeta电位达到+37.9 mV,对阴离子染料甲基橙(MO)和刚果红(CR)均具有良好的吸附性能,考察了吸附时间、pH值、染料初始浓度、温度对SNCs-PEI吸附性能的影响。研究表明:在pH为3,SNCs-PEI投加量为0.1 g,MO、CR初始浓度为130 mg/L的条件下,SNCs-PEI对MO和CR的吸附过程均符合准二级动力学和Langmuir吸附模型,SNCs-PEI对MO、CR的最大吸附量分别为82.10,57.34 mg/g,吸附过程属于一个自发的吸热过程。该新型生物吸附剂的研究对含阴离子染料工业废水的去除提供了一种新途径。
  • [1] SINGH N J, WAREPPAM B, GHOSH S, et al. Alkali-cation incorporated and functionalized iron oxide nanoparticles for methyl blue removal/decomposition[J]. Nanotechnology, 2020, 31(42):125867-125908.
    [2] PUTRI R A, SAFNI S, JAMARUN N, et al. Kinetics study and degradation pathway of methyl orange photodegradation in the presence of C-N-codoped TiO2 catalyst[J]. Egyptian Journal of Chemistry, 2019, 62(2):563-575.
    [3] SHABANI S, DINARI M. Itaconic acid-modified layered double hydroxide/gellan gum nanocomposites for Congo red adsorption[J]. Scientific Reports, 2022, 12(1):4356-4368.
    [4] 赵雅兰, 陈启杰, 谢琼华,等. 淀粉基化学品用作吸附剂的应用研究进展[J]. 工业水处理, 2021, 41(7):19-24

    ,33.
    [5] CHEN Q J, ZHENG X M, ZHOU L L, et al. Adsorption of Cu(Ⅱ) and methylene blue by succinylated starch nanocrystals[J]. Starch-Stärke, 2019, 71(7/8):1-12.
    [6] CHEN Y, DAI G F, GAO Q Y. Starch nanoparticles-graphene aerogels with high supercapacitor performance and efficient adsorption[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(16):14064-14073.
    [7] ZHANG N, ZANG G L, SHI C, et al. A novel adsorbent TEMPO-mediated oxidized cellulose nanofibrils modified with PEI:preparation, characterization, and application for Cu (Ⅱ) removal[J]. Journal of Hazardous Materials, 2016, 316(5):11-18.
    [8] MENG L H, YU L, LI S, et al. Improvement of interfacial interaction between hydrophilic starch film and hydrophobic biodegradable coating[J]. Acs Sustainable Chemistry & Engineering, 2019, 7(10):9506-9514.
    [9] HONG H J, YU H, HONG S, et al. Modified tunicate nanocellulose liquid crystalline fiber as closed loop for recycling platinum-group metals[J]. Carbohydrate Polymers, 2019, 228:115424-115431.
    [10] HONG H J, YU H, PARK M, et al. Recovery of platinum from waste effluent using polyethyleneimine-modified nanocelluloses:effects of the cellulose source and type[J]. Carbohydrate Polymers, 2019, 210(1):167-174.
    [11] KAUR S, KEMPSON I, XU H L, et al.Bio-template assisted synthesis of porous glutaraldehyde-polyethyleneimine particulate resin for selective copper ion binding and recovery[J]. RSC Adv, 2018, 8(22):12043-12052.
    [12] YUSOF N H, FOO K Y, WILSON L D, et al. Microwave-assisted synthesis of polyethyleneimine grafted chitosan beads for the adsorption of acid red 27[J]. Journal of Polymers and the Environment, 2019, 28(2):542-552.
    [13] AJELOU Z, NIKFARJAM N, DENG Y L, et al. Expanded polystyrene via stabilized water droplet by in-situ modified starch Nanocrystals[J]. Colloids and Surfaces A, 2019, 582:1-12.
    [14] WEI B X, SUN B H, ZHANG B, et al. Synthesis, characterization and hydrophobicity of silylated starch nanocrystal[J]. Carbohydrate Polymers, 2016, 136(10):1203-1208.
    [15] MENG Q, WU S D, SHEN C. Polyethylenimine-grafted-corncob as a multifunctional biomaterial for removing heavy metal ions and killing bacteria from water[J]. Industrial & Engineering Chemistry Research, 2020, 59(39):17476-17482.
    [16] NI S Z, WANG C J, BIAN H Y, et al. Enhancing physical performance and hydrophobicity of paper-based cellulosic material via impregnation with starch and PEI-KH560[J]. Cellulose, 2018, 25(2):1365-1375.
    [17] GADHAVE R V, MAHANWAR P A, GADEKAR P T. Effect of glutaraldehyde on thermal and mechanical properties of starch and polyvinyl alcohol blends[J]. Designed Monomers & Polymers, 2019, 22(1):164-170.
    [18] ZEWDE D, GEREMEW B. Removal of Congo red using Vernonia amygdalina leaf powder:optimization, isotherms, kinetics, and thermodynamics studies[J]. Environmental Pollutants and Bioavailability, 2022, 24(1):88-101.
    [19] CAO F J, LIAN C, YU J G, et al. Study on the adsorption performance and competitive mechanism for heavy metal contaminants removal using novel multi-pore activated carbons derived from recyclable long-root Eichhornia crassipes[J]. Bioresour Technol, 2019, 276:211-218.
    [20] LU N Q, HU T J, ZHAI Y B, et al. Fungal cell with artificial metal container for heavy metals biosorption:equilibrium, kinetics study and mechanisms analysis[J]. Environ Res, 2020, 182:109061.
    [21] WANG J L, GUO X. Adsorption isotherm models:classification, physical meaning, application and solving method[J]. Chemosphere, 2020, 258:127279.
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出版历程
  • 收稿日期:  2022-04-25
  • 网络出版日期:  2023-05-26
  • 刊出日期:  2023-03-01

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