PYROLYSIS CHARACTERISTICS AND MATERIAL TRANSFORMATION CHARACTERISTICS OF CAMPUS ORGANIC WASTE TREATED BY VERMICOMPOSTING
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摘要: 以校园餐厨垃圾为主要原料,校园绿化垃圾、废纸、锯末为调理剂,利用热重、荧光、红外等技术探讨了校园有机垃圾蚯蚓堆肥就地处理的热稳定性和物质转化特征。结果表明:将餐厨垃圾、树叶、废纸以1:1:1(干重)物料配比混合进行蚯蚓堆肥,堆肥周期较短(10周),有机物稳定化和资源化效果较好;热重分析表明:堆肥前后堆料失质量大幅减少,由71.44%降低至41.44%,堆体的稳定性增强。通过动力学模型计算发现,堆肥后该处理组的活化能降低了6.163 kJ/mol,三者组合堆肥加快了堆肥进程;对DOM转化的腐殖化表征可知:堆肥后,其腐植酸含量增加了20.13%,而蛋白类物质减少了17.3%;与堆肥前相比,蚓粪中的速效氮、速效磷含量分别提高了6.54,1.82倍。校园餐厨垃圾、绿化垃圾与废纸的联合蚯蚓堆肥处理,可有效加快堆肥进程,提高有机物稳定化和资源化利用的程度,实现校园垃圾就地处理。Abstract: The thermal stability and material transformation characteristics of organic waste treated by vermicomposting were investigated with campus kitchen waste assisted by campus green waste, wasted paper and sawdust. The results indicated that vermicomposting with kitchen waste, leaves and waste paper (1:1:1, by dry weight) with a vermicomposting cycle of 10 weeks, gained better organic stabilization and resource recovery effect. Furthermore, the thermogravimetric analysis showed that the weight loss of the heap decreased from 71.44% to 41.44% after vermicomposting, and the stability of vermicompost was enhanced. Additionally, the kinetic model deduced that the activation energy of the composting group decreased by 6.163 kJ/mol after vermicomposting, indicating that the composting process was accelerated. Humic acid and protein content increased by 20.13% and 17.3% after composting. The content of available nitrogen and available phosphorus in vermicompost increased by 6.54 times and 1.82 times, respectively, after vermicomposting. The vermicomposting treatment of campus kitchen waste, green waste and waste paper effectively accelerated the composting process, improved the degree of organic stabilization and resource utilization, and has the potential in realizing onsite treatment of campus organic wastes.
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Key words:
- campus organic wastes /
- vermicompost /
- organic conversion /
- pyrolysis characteristics /
- humification
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[1] 李欢,周颖君,刘建国,等.我国厨余垃圾处理模式的综合比较和优化策略[J].环境工程学报, 2021, 15(7):2398-2408. [2] 王晓槐,李军,魏肖楠,等."无废城市"建设下校园餐厨垃圾处理现状及对策研究:以兰州高校为例[J].环境科学与管理, 2021, 46(10):96-100. [3] 张晓婷. 兰州市高校食堂餐厨垃圾处理监管研究[D].兰州:西北师范大学, 2019. [4] YANG F, LI G X, YANG Q Y, et al. Effect of bulking agents on maturity and gaseous emissions during kitchen waste composting[J]. Chemosphere, 2013, 93(7):1393-1399. [5] DING Y W, WEI J, XIONG J J, et al. Effects of operating parameters on in situ NH3 emission control during kitchen waste composting and correlation analysis of the related microbial communities[J]. Environmental Science and Pollution Research, 2019, 26(12):11756-11766. [6] WANG X J, ZHANG W W, GU J, et al. Effects of different bulking agents on the maturity, enzymatic activity, and microbial community functional diversity of kitchen waste compost[J]. Environmental Technology, 2016, 37(20):2555-2563. [7] LI M, LI F, ZHOU J, et al. Fallen leaves are superior to tree pruning as bulking agents in aerobic composting disposing kitchen waste[J]. Bioresource Technology, 2022, 346:126374. [8] 陈瑞建,章伟伟,云虹,等.废纸在人造板领域中的回收利用技术及研究进展[J].林产工业, 2019, 46(7):7-10. [9] BHAT S A, SINGH J, VIG A P. Earthworms as organic waste managers and biofertilizer producers[J]. Waste and Biomass Valorization, 2018, 9(7):1073-1086. [10] NDEGWA P M, THOMPSON S A. Effects of C-to-N ratio on vermicomposting of biosolids[J]. Bioresource Technology, 2000, 75(1):7-12. [11] SOOBHANY N, GUNASEE S, RAGO Y P, et al. Spectroscopic, thermogravimetric and structural characterization analyses for comparing Municipal Solid Waste composts and vermicomposts stability and maturity[J]. Bioresource Technology, 2017, 236:11-19. [12] HANC A, ENEV V, HREBECKOVA T, et al. Characterization of humic acids in a continuous-feeding vermicomposting system with horse manure[J]. Waste Management, 2019, 99:1-11. [13] SRIVASTAVA V, GOEL G, THAKUR V K, et al. Analysis and advanced characterization of municipal solid waste vermicompost maturity for a green environment[J]. Journal of Environmental Management, 2020, 255:109914. [14] LU M Y, SHI X S, FENG Q, et al. Effects of humic acid modified oyster shell addition on lignocellulose degradation and nitrogen transformation during digestate composting[J]. Bioresource Technology, 2021, 329:124834. [15] WANG X Q, WANG M M, ZHANG J, et al. Contributions of the biochemical factors and bacterial community to the humification process of in situ large-scale aerobic composting[J]. Bioresource Technology, 2021, 323:124599. [16] KURAJICA L, UJEVIĆ BOŠNJAK M, KINSELA A S, et al. Effects of changing supply water quality on drinking water distribution networks:changes in NOM optical properties, disinfection byproduct formation, and Mn deposition and release[J]. Science of the Total Environmen, 2021, 762:144159. [17] RODRÍGUEZ-VIDAL F J, GARCÍA-VALVERDE M, ORTEGA-AZABACHE B, et al. Using excitation-emission matrix fluorescence to evaluate the performance of water treatment plants for dissolved organic matter removal[J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 2021, 249:119298. [18] MAGO M, YADAV A, GUPTA R, et al. Management of banana crop waste biomass using vermicomposting technology[J]. Bioresource Technology, 2021, 326:124742. [19] ARORA M, KAUR A. Azolla pinnata, Aspergillus terreus and Eisenia fetida for enhancing agronomic value of paddy straw[J]. Scientific Reports, 2019, 9(1):1341. [20] BORUAH T, BARMAN A, KALITA P, et al. Vermicomposting of citronella bagasse and paper mill sludge mixture employing Eisenia fetida[J]. Bioresource Technology, 2019, 294:122147. [21] DEVI C, KHWAIRAKPAM M. Management of invasive weed Parthenium hysterophorus through vermicomposting using a polyculture of Eisenia fetida and Eudrilus eugeniae[J]. Environmental Science and Pollution Research, 2021, 28(23):29710-29719. [22] SHARMA D, PANDEY A K, YADAV K D, et al. Response surface methodology and artificial neural network modelling for enhancing maturity parameters during vermicomposting of floral waste[J]. Bioresource Technology, 2021, 324:124672. [23] 李英凯,王亚利,杨晓磊,等.蚯蚓堆肥处理畜禽粪便的影响因素及其产物的应用综述[J].环境工程,2020,38(1):162-166, 127. [24] ZMORA-NAHUM S, MARKOVITCH O, TARCHITZKY J, et al. Dissolved organic carbon (DOC) as a parameter of compost maturity[J]. Soil Biology and Biochemistry, 2005, 37(11):2109-2116. [25] 高健. 基于热重分析的延边地区主要乔木树种的燃烧性研究[D].哈尔滨:东北林业大学,2020. [26] YANG H P, YAN R, CHEN H P, et al. Characteristics of hemicellulose, cellulose and lignin pyrolysis[J]. Fuel, 2007, 86(12/13):1781-1788. [27] CHEN W, WESTERHOFF P, LEENHEER J A, et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter[J]. Environmental Science & Technology, 2003, 37(24):5701-5710.
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