碳基材料与挥发性有机污染物相互作用行为和机制研究进展

梁妮; 刘凯; 孔颖; 起兆雄; 陈全

doi:10.13205/j.hjgc.202307035

碳基材料与挥发性有机污染物相互作用行为和机制研究进展

doi: 10.13205/j.hjgc.202307035

梁妮^1,2,
刘凯^1,2,
孔颖^1,2,
起兆雄^1,2,
陈全^1,2, ,

1. 昆明理工大学环境科学与工程学院, 昆明 650500;
2. 云南省土壤固碳与污染控制重点实验室, 昆明 650500

基金项目:

国家自然科学基金地区项目（42167055，42277399）

详细信息

作者简介:
梁妮(1979-),女,博士,讲师,主要研究方向为环境土壤科学。liangnikust@163.com

通讯作者:
陈全(1989-),男,博士,副教授,主要研究方向为污染物环境行为及归趋。18814122937@163.com

计量
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- 被引次数: 0
出版历程
- 收稿日期: 2022-09-25

RESEARCH PROGRESS ON INTERACTION BEHAVIORS AND MECHANISM OF CARBON-BASED MATERIALS AND VOLATILE ORGANIC COMPOUNDS

LIANG Ni^1,2,
LIU Kai^1,2,
KONG Ying^1,2,
QI Zhaoxiong^1,2,
CHEN Quan^{1,2
, ,}

1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China;
2. Yunnan Provincial Key Lab of Soil Carbon Sequestration and Pollution Control, Kunming 650500, China

摘要

摘要: 挥发性有机物（VOCs）是常见的污染物，可通过工农业生产活动进入环境，并对生态环境和人类健康构成潜在威胁。碳基材料具有多种优点且极具工程应用潜力，被广泛应用于VOCs污染防治的研究中。因此明确碳基材料与VOCs间的作用机制有着切实的环境意义。首先综述了VOCs的主要来源、危害。并以碳基材料为主要关注对象，论述了各种改性或未改性碳基材料对VOCs的吸附和降解效率；详细介绍了吸附和降解过程中两者间可能发生的作用机制；然后从碳基材料和VOCs本身的物理化学性质以及环境因素角度出发，探讨碳基材料吸附或降解VOCs过程中的影响因素；最后阐明了两者之间的关联和区别，总结出判定去除VOCs过程中相互作用的方法。基于此，碳基材料在VOCs治理过程中起到重要作用，具有重要的环境意义。研究成果可为碳基材料的结构调控方向、应用性能评价及其在VOCs吸附或降解中的应用提供参考。
- 吸附 /
- 降解 /
- 相互作用机制 /
- 降解途径 /
- 自由基
Abstract: Volatile organic compounds (VOCs) are a class of common pollutants. They can enter the environment through industrial and agricultural activities and cause pollution, thus posing a potential threat to the ecological environment and human health. Carbon-based materials are widely used in the research of VOCs pollution prevention and control,due to their advantages and great engineering application potential. Therefore, it is of practical environmental significance to clarify the interaction mechanism between carbon-based materials and VOCs. In this review, the primary sources, hazards and common treatment methods of VOCs were first summarized. Taking carbon-based materials as the primary research object, the adsorption and degradation efficiency of various modified or unmodified carbon-based materials on VOCs were discussed. The possible interaction mechanism between them in the process of adsorption and degradation was described in detail. Then, from the perspective of the physicochemical properties of carbon-based materials and VOCs themselves as well as environmental factors, the factors influencing the adsorption or degradation of VOCs by carbon-based materials were discussed. Finally, the correlation and differences between the two were clarified, and the interaction methods in the process of determining the removal of VOCs were summarized. Based on the in-depth understanding of the efficiency, mechanism and influencing factors in the adsorption and degradation of VOCs by carbon-based materials, this review could provide a deeper understanding of the critical role of carbon-based materials in the VOCs treatment process, which could provide theoretical guidance for the future regulation direction of the structure of carbon-based materials, application performance evaluation and their application in adsorption or degradation of VOCs.
- adsorption /
- degradation /
- interaction mechanism /
- degradation pathway /
- free radicals

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