钢铁厂废物循环中的重金属物质流及排放：以Pb为例

朱素龙; 高成康; 田国; 张新虹; 李晓军; 宫璇

doi:10.13205/j.hjgc.202308028

钢铁厂废物循环中的重金属物质流及排放：以Pb为例

doi: 10.13205/j.hjgc.202308028

朱素龙^1,2,
高成康^1,2, ,,
田国³,
张新虹^1,2,
李晓军⁴,
宫璇⁵

1. 东北大学国家环境保护生态工业重点实验室, 沈阳 110819;
2. 东北大学冶金学院, 沈阳 110819;
3. 葫芦岛市工业和信息化局, 辽宁葫芦岛 125000;
4. 中国科学院应用生态研究所污染生态与环境工程重点实验室, 沈阳 110016;
5. 东北大学资源与土木工程学院, 沈阳 110004

基金项目:

第二次青藏高原综合科学考察研究(2019QZKK1003)

国家自然科学基金(41871212)

中央高校重点科学研究引导项目(N2025008)

详细信息

作者简介:
朱素龙(1994-),男,博士研究生,主要研究方向为冶金工业的环境工程。zhu_sl@126.com

通讯作者:
高成康(1977-),女,博士,教授,主要研究方向为流程工业的环境系统研究,工业、区域污染源解析。gaock@smm.neu.edu.cn

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出版历程
- 收稿日期: 2022-10-10
- 网络出版日期: 2023-11-15

HEAVY METAL EMISSIONS FROM STEELWORKS BASED ON SOLID WASTE RESOURCE RECYCLING: A CASE STUDY ON LEAD

1. State Environmental Protection Key Laboratory of Eco-Industry, Northeastern University, Shenyang 110819, China;
2. School of Metallurgy, Northeastern University, Shenyang 110819;
3. Huludao Municipal Bureau of Industry and Information Technology, Huludao 125000, China;
4. Key Laboratory of Pollution Ecology and Environment Engineering, Institute of Applied Ecology, Chinese Academy of Science, Shenyang 110016, China;
5. College of Resources and Civil Engineering, Northeastern University, Shenyang 110004, China

摘要

摘要: 近期国家相继出台了一系列关于重金属污染防治的政策、意见和规划。但在推进重金属减排的过程中存在一些阻碍,如摸底不清、缺乏定量路径研究和减排路径不系统。首先,钢铁厂的重金属排放因子未能考虑废物循环带来的二次排放问题。其次,有关钢铁厂重金属的物质流研究尚未报道。最后,已有的减排研究着重于某一生产环节或者某一具体问题,而缺乏系统性的减排潜力分析。鉴于上述问题,以Pb为例,采用物质流的分析方法,首次建立了钢铁厂的Pb素流,分析了钢铁厂重金属Pb的流动路径和关键排放节点;以源头削减和过程控制为减排思路,基于投入产出分析和情景设置,分析了当前重金属Pb的流动网络,探究钢铁厂重金属Pb的减排潜力。结果表明:系统Pb的输入量、循环量和输出量各值分别为341.32,357.06,129.41 g/t 粗钢;Pb主要在烧结工序和炼铁工序间富集循环;Pb主要来源于铁精矿和块矿,随着炉渣、废气和热轧卷输出;经源头削减和末端治理优化措施后,钢铁产品的Pb含量的削减比例在16.06%~30.69%。
- 钢铁厂 /
- 重金属Pb /
- 物质流 /
- 减排潜力
Abstract: Recently, China has issued policies, opinions and plans on heavy metal pollution prevention and control respectively. However, there were still some obstacles in the process of promoting heavy metal emission reduction, such as unclear accounting, lack of quantitative pathway studies and unsystematic emission reduction pathways. Specifically, firstly, the emission factors of heavy metals from the steelworks failed to consider the secondary emissions from waste recycling. Secondly, studies on the material flow of heavy metals from steelworks have not been reported. Finally, previous emission reduction studies focused on a specific production step or problem, but lacked a systematic analysis of emission reduction potential. In view of the above problems, this paper, taking the lead (Pb) as an example, adopted the substance flow analysis method to establish the Pb flow in steelworks for the first time, and analyzed the flow mechanism of Pb in steelworks. With source reduction, process control, and end-of-pipe treatment as emission reduction ideas, based on the input-output multi-objective optimization method, the current Pb flow network was optimized to explore the emission reduction potential of Pb in steelworks and provided technical suggestions for the reduction of Pb-content pollution in the steel industry. The results showed that the values of input, circulation, and output of Pb were 341.32 g/t-crude steel, 357.06 g/t-crude steel and 129.41 g/t-crude steel, respectively. Pb is enriched and circulated mainly between the sinter plant and the BF plant. Pb was mainly derived from iron ore concentrate and lump ore and exported with slag, waste gas and hot rolled coils. After source reduction and end-of-pipe treatment optimization, the reduction ratio of Pb content of steel products was between 16.06% and 30.69%.
- steelworks /
- heavy metal Pb /
- substance flow analysis /
- discharge reduction potential

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参考文献(16)

[1]	构建绿色低碳循环可持续发展的钢铁工业发展体系[J].科技导报,2021,39(16):56-61.
[2]	重金属污染综合防治“十二五”规划-中国知网[EB/OL].[2022-08-29].https://kns.cnki.net/kcms/detail/detail.aspx?dbcode=SNAD&dbname=SNAD&filename=SNAD000001595773&uniplatform=NZKPT&v=TjRX_0fSS4slom7I3eVZgRDU6D2WBIg2bsPBNDsRTftlHfGnbvL7WzEel0fpZMSLS_-o_Lm5E6I%3d.
[3]	王艳,程轲,易鹏,等.中国工业过程大气铅排放特征[J].环境科学学报,2016,36(5):1589-1594.
[4]	CHENG K,WANG Y,TIAN H,et al.American chemical society,2015.atmospheric emission characteristics and control policies of five precedent-controlled toxic heavy metals from anthropogenic sources in China[J].Environmental Science & Technology,2015,49(2):1206-1214.
[5]	王堃,滑申冰,田贺忠,等.2011年中国钢铁行业典型有害重金属大气排放清单[J].中国环境科学,2015,35(10):2934-2938.
[6]	SHA Q E,LU M H,HUANG Z J,et al.Anthropogenic atmospheric toxic metals emission inventory and its spatial characteristics in Guangdong province,China[J].Science of the Total Environment,2019,670:1146-1158.
[7]	白钢钉.铅锌杂质在高炉炼铁中的循环研究[J].金属制品,2022,48(2):60-62.
[8]	刘江伟,黄帮福,王伟伟,等.低品位矿高炉铅平衡探究[J].河南冶金,2018,26(1):4-6 ,40.
[9]	薛飞.高炉中铅元素的循环富集及其抑制措施[J].山东冶金,2014,36(2):44-45.
[10]	杨金福,王霞,张英才,等.高炉中有害元素的平衡分析及其脱除[J].中国冶金,2007(11):35-40.
[11]	魏晨曦,罗立群,郑波涛.铅锌在高炉炼铁中的循环过程与影响评析[J].现代化工,2020,40(3):30-35.
[12]	蔡九菊,杜涛,陆钟武,等.钢铁生产流程环境负荷评价体系的研究方法[J].钢铁,2002(8):66-70.
[13]	《清洁生产评价指标体系编制通则》(试行稿)[EB/OL].[2022-11-21].https://www.mee.gov.cn/gkml/hbb/gwy/201306/t20130617_253853.htm.
[14]	王成立,顾林娜.Pb在高炉冶炼过程中的变化与分配[J].冶金丛刊,2008(6):5-9.
[15]	卢郑汀,董瑞章,仇友金,等.昆钢2500 m³高炉有害元素分析与控制[J].炼铁,2015,34(5):33-35.
[16]	尚海霞,李海铭,魏汝飞,等.钢铁尘泥的利用技术现状及展望[J].钢铁,2019,54(3):9-17.