流域水环境硝酸盐源解析方法研究进展

赵婉宁; 崔纪京; 白利勇; 于小晶; 戴九兰

doi:10.13205/j.hjgc.202308036

流域水环境硝酸盐源解析方法研究进展

doi: 10.13205/j.hjgc.202308036

1. 山东大学环境研究院, 山东青岛 266237;
2. 博山区数字农业农村发展中心, 山东淄博 255200

基金项目:

国家重点研发计划“黄淮海粮食主产区面源和重金属污染综合防治技术示范”(2018YFD0800303)

博山水利技术服务项目“博山区地下水硝酸盐溯源研究”(1460021014)

详细信息

作者简介:
赵婉宁(1997-),女,硕士研究生,主要研究方向为流域水体污染防治。z2572555049@126.com

通讯作者:
戴九兰(1975-),女,教授,主要研究方向为面源污染控制与生态修复。daijiulan@sdu.edu.cn

计量
- 文章访问数: 70
- HTML全文浏览量: 8
- PDF下载量: 7
- 被引次数: 0
出版历程
- 收稿日期: 2022-11-02
- 网络出版日期: 2023-11-15

RESEARCH PROGRESS ON NITRATE SOURCE ANALYSIS METHODS FOR WATER ENVIRONMENT IN WATERSHEDS

1. Environment Research Institute, Shandong University, Qingdao 266237, China;
2. Digital Agriculture and Rural Development Center of Boshan District, Zibo 255200, China

摘要

摘要: 污染源的精准识别和量化是解决流域水体硝酸盐(NO^-₃)污染问题的前提。综述流域水环境NO^-₃源解析方法研究进展,分析NO^-₃来源定性识别方法(水化学分析、多元统计分析、稳定同位素示踪等)的优缺点,总结NO^-₃来源定量计算模型(多元统计模型、同位素定量解析模型)的发展历程。建议从多学科融合、多维度交叉的角度开拓新的溯源方法,准确识别氮素迁移转化过程;定量计算模型应重点考虑确定同位素的分馏效应及对模型的改进等方面,以期提高溯源的准确性,为流域水体NO^-₃源解析工作的开展提供方法选择依据和理论参考。
- 硝酸盐 /
- 源解析 /
- 污染来源 /
- 同位素 /
- 定量模型
Abstract: Accurate identification and quantification of pollution sources is a prerequisite for solving the problem of nitrate (NO₃^-) pollution in watersheds. We reviewed the research progress of NO₃^- source analysis methods in watershed environments, analyzed the advantages and disadvantages of qualitative NO₃^- source identification methods (including water chemistry analysis, multivariate statistical analysis, stable isotope tracing, and so on), and summarized the development of quantitative NO₃^- source models (including multivariate statistical models and quantitative isotope analysis models). To improve traceability accuracy and provide a basis for method selection and a theoretical reference for the development of NO₃^- source analysis in watersheds, it is suggested that new traceability methods should be developed from the perspectives of multidisciplinary integration and multidimensional intersection, to accurately identify nitrogen migration and transformation processes; quantitative calculation models should focus on determining the fractionation effects of isotopes and improving the models.
- nitrate /
- source analysis /
- pollution sources /
- isotopes /
- quantitative model

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参考文献(76)

[1]	陈新明,马腾,蔡鹤生,等.地下水氮污染的区域性调控策略[J].地质科技情报,2013,32(6):130-143.
[2]	赵永宏,邓祥征,战金艳,等.我国湖泊富营养化防治与控制策略研究进展[J].环境科学与技术,2010,33(3):92-98.
[3]	HORD N G.Dietary nitrates,nitrites,and cardiovascular disease[J].Current Atherosclerosis Reports,2011,13(6):484-492.
[4]	DANNI S O,BOUCHAOU L,ELMOUDEN A,et al.Assessment of water quality and nitrate source in the Massa catchment (Morocco) using δ¹⁵N and δ¹⁸O tracers[J].Applied Radiation and Isotopes,2019,154:108859.
[5]	MOFFAT A S.Global nitrogen overload problem grows critical[J].Science,1998,279(5353):988-989.
[6]	RICHA A,TOUIL S,FIZIR M.Recent advances in the source identification and remediation techniques of nitrate contaminated groundwater:a review[J].Journal of Environmental Management,2022,316:115265.
[7]	NEJATIJAHROMI Z,NASSERY H R,HOSONO T,et al.Groundwater nitrate contamination in an area using urban wastewaters for agricultural irrigation under arid climate condition,southeast of Tehran,Iran[J].Agricultural Water Management,2019,221:397-414.
[8]	HUANG X,JIN M G,MA B,et al.Identifying nitrate sources and transformation in groundwater in a large subtropical basin under a framework of groundwater flow systems[J].Journal of Hydrology,2022,610:127943.
[9]	WU P Y,XIAO Q,GUO Y L,et al.Migration,transformation and nitrate source in the Lihu underground river based on dual stable isotopes of δ¹⁵N-NO₃^- and δ¹⁸O-NO₃^-[J].Environmental Science and Pollution Research,2022,29(32):48661-48674.
[10]	MADISON R J,BRUNETT J O.Overview of the occurrence of nitrate in groundwater of the United States[J].U.S.Geological Survey Water Supply Paper,1985,2275:93-105.
[11]	OGRINC N,TAMŠE S,ZAVADLAV S,et al.Evaluation of geochemical processes and nitrate pollution sources at the Ljubljansko polje aquifer (Slovenia):a stable isotope perspective[J].Science of the Total Environment,2019,646:1588-1600.
[12]	谢伟.美国清洁水法原理:从命令控制的视角[M].北京:法律出版社,2018:154.
[13]	XU G C,CHENG S D,LI P,et al.Soil total nitrogen sources on dammed farmland under the condition of ecological construction in a small watershed on the Loess Plateau,China[J].Ecological Engineering,2018,121:19-25.
[14]	杜新强,方敏,冶雪艳.地下水“三氮”污染来源及其识别方法研究进展[J].环境科学,2018,39(11):5266-5275.
[15]	QIAO C L,LIU L L,HU S J,et al.How inhibiting nitrification affects nitrogen cycle and reduces environmental impacts of anthropogenic nitrogen input[J].Global Change Biology,2015,21(3):1249-1257.
[16]	于璐,郑天元,郑西来.地下水硝酸盐污染源解析及氮同位素分馏效应研究进展[J].现代地质,2022,36(2):563-573.
[17]	肖勇,莫培,尹世洋,等.北京南郊平原地下水化学特征及成因分析[J].环境工程,2021,39(8):99-107.
[18]	GAO J B,LI Z Q,CHEN Z J,et al.Deterioration of groundwater quality along an increasing intensive land use pattern in a small catchment[J].Agricultural Water Management,2021,253:106953.
[19]	TORRES-MARTÍNEZ J A,MORA A,MAHLKNECHT J,et al.Estimation of nitrate pollution sources and transformations in groundwater of an intensive livestock-agricultural area (Comarca Lagunera),combining major ions,stable isotopes and MixSIAR model[J].Environmental Pollution,2021,269:115445.
[20]	PASTÉN-ZAPATA E,LEDESMA-RUIZ R,HARTER T,et al.Assessment of sources and fate of nitrate in shallow groundwater of an agricultural area by using a multi-tracer approach[J].Science of the Total Environment,2014,470:855-864.
[21]	HE S,LI P Y,SU F M,et al.Identification and apportionment of shallow groundwater nitrate pollution in Weining Plain,northwest China,using hydrochemical indices,nitrate stable isotopes,and the new Bayesian stable isotope mixing model (MixSIAR)[J].Environmental Pollution,2022,298:118852.
[22]	刘贯群,周书玉,黄修东,等.多种方法识别青岛大沽河平原区地下水硝酸盐污染来源[J].环境科学学报,2017,37(1):347-356.
[23]	LI J,ZHU D N,ZHANG S,et al.Application of the hydrochemistry,stable isotopes and MixSIAR model to identify nitrate sources and transformations in surface water and groundwater of an intensive agricultural karst wetland in Guilin,China[J].Ecotoxicology and Environmental Safety,2022,231:113205.
[24]	米红,张文璋.实用现代统计分析方法与SPSS应用[M].北京:当代中国出版社,2002.
[25]	丁言者,李飞,徐敏,等.南通近岸海域水质特征的因子及聚类分析研究[J].海洋学报,2014,36(8):1-11.
[26]	王贺,谷洪彪,迟宝明,等.柳江盆地浅层地下水硝酸盐分布特征及影响因素分析[J].环境科学,2016,37(5):1699-1706.
[27]	VASELLI O,BUCCIANTI A,DESIENA C,et al.Geochemical characterization of ophiolitic soils in a temperate climate:a multivariate statistical approach[J].Geoderma,1997,75(1/2):117-133.
[28]	谢琼,付青,昌盛,等.江库连通条件下珠海市饮用水源水质分布特征及水资源调配措施[J].环境工程技术学报,2022,12(4):1075-1085.
[29]	KOHL D H,SHEARER G B,COMMONER B.Fertilizer nitrogen:contribution to nitrate in surface water in a corn belt watershed source[J].Science,1971,174(4016):1331-1334.
[30]	KENDALL C,ELLIOTT E M,WANKEL S D.Tracing anthropogenic inputs of nitrogen to ecosystems[J].Stable Isotopes in Ecology and Environmental Science,2007,2(1):375-449.
[31]	XUE D M,BOTTE J,DE BAETS B,et al.Present limitations and future prospects of stable isotope methods for nitrate source identification in surface- and groundwater[J].Water Research,2009,43(5):1159-1170.
[32]	FANG Y T,KOBA K,MAKABE A,et al.Low δ¹⁸O values of nitrate produced from nitrification in temperate forest soils[J].Environmental Science & Technology,2012,46(16):8723-8730.
[33]	YU L,ZHENG T Y,ZHENG X L,et al.Nitrate source apportionment in groundwater using Bayesian isotope mixing model based on nitrogen isotope fractionation[J].Science of The Total Environment,2020,718:137242.
[34]	ZHANG H,XU Y,CHENG S Q,et al.Application of the dual-isotope approach and Bayesian isotope mixing model to identify nitrate in groundwater of a multiple land-use area in Chengdu Plain,China[J].Science of The Total Environment,2020,717:137134.
[35]	RYU H D,KIM S J,BAEK U I,et al.Identifying nitrogen sources in intensive livestock farming watershed with swine excreta treatment facility using dual ammonium (δ¹⁵N_NH₄) and nitrate (δ¹⁵N_NO₃) nitrogen isotope ratios axes[J].Science of The Total Environment,2021,779:146480.
[36]	ZHANG Q Q,WANG H W.Assessment of sources and transformation of nitrate in the alluvial-pluvial fan region of north China using a multi-isotope approach[J].Journal of Environmental Sciences,2020,89:9-22.
[37]	CAO X,SHI Y Y,HE W,et al.Impacts of anthropogenic groundwater recharge (AGR) on nitrate dynamics in a phreatic aquifer revealed by hydrochemical and isotopic technologies[J].Science of the Total Environment,2022,839:156187.
[38]	HOSONO T,TOKUNAGA T,TSUSHIMA A,et al.Combined use of δ¹³C,δ¹⁵N,and δ³⁴S tracers to study anaerobic bacterial processes in groundwater flow systems[J].Water Research,2014,54:284-296.
[39]	NIGRO A,SAPPA G,BARBIERI M.Strontium isotope as tracers of groundwater contamination[J].Procedia Earth and Planetary Science,2017,17:352-355.
[40]	WIDORY D,PETELET-GIRAUD E,NÉGREL P,et al.Tracking the sources of nitrate in groundwater using coupled nitrogen and boron isotopes:a synthesis[J].Environmental Science & Technology,2005,39(2):539-548.
[41]	JIANG Y J,WU Y X,YUAN D X.Human impacts on karst groundwater contamination deduced by coupled nitrogen with strontium isotopes in the Nandong underground river system in Yunan,China[J].Environmental Science & Technology,2009,43(20):7676-7683.
[42]	XIAO Y K,WANG L.The effect of pH and temperature on the isotopic fractionation of boron between saline brine and sediments[J].Chemical geology,2001,171(3/4):253-261.
[43]	BALLESTÉ E,BELANCHE-MUÑOZ L A,FARNLEITNER A H,et al.Improving the identification of the source of faecal pollution in water using a modelling approach:from multi-source to aged and diluted samples[J].Water Research,2020,171:115392.
[44]	BRIAND C,PLAGNES V,SEBILO M,et al.Combination of nitrate (N,O) and boron isotopic ratios with microbiological indicators for the determination of nitrate sources in karstic groundwater[J].Environmental Chemistry,2013,10(5):365-369.
[45]	SHU W,WANG P,ZHAO J,et al.Sources and migration similarly determine nitrate concentrations:integrating isotopic,landscape,and biological approaches[J].Science of The Total Environment,2022,852:158216.
[46]	JAFFÉ R,BOYER J N,LU X,et al.Source characterization of dissolved organic matter in a subtropical mangrove-dominated estuary by fluorescence analysis[J].Marine Chemistry,2004,84(3/4):195-210.
[47]	MA Z F,YANG Y,LIAN X Y,et al.Identification of nitrate sources in groundwater using a stable isotope and 3DEEM in a landfill in Northeast China[J].Science of The Total Environment,2016,563:593-599.
[48]	MAHLKNECHT J,DAESSLE L,ESTELLER M,et al.Groundwater flow processes and human impact along the arid US-Mexican border,evidenced by environmental tracers:the case of Tecate,Baja California[J].International Journal of Environmental Research and Public Health,2018,15(5):887.
[49]	LINHOFF B.Deciphering natural and anthropogenic nitrate and recharge sources in arid region groundwater[J].Science of the Total Environment,2022,848:157345.
[50]	LV J S,LIU Y.An integrated approach to identify quantitative sources and hazardous areas of heavy metals in soils[J].Science of The Total Environment,2019,646:19-28.
[51]	李娇,吴劲,蒋进元,等.近十年土壤污染物源解析研究综述[J].土壤通报,2018,49(1):232-242.
[52]	LU Z J,LIU Q Y,XIONG Y,et al.A hybrid source apportionment strategy using positive matrix factorization (PMF) and molecular marker chemical mass balance (MM-CMB) models[J].Environmental Pollution,2018,238:39-51.
[53]	ZANOTTI C,ROTIROTI M,FUMAGALLI L,et al.Groundwater and surface water quality characterization through positive matrix factorization combined with GIS approach[J].Water Research,2019,159:122-134.
[54]	YU L,ZHENG T Y,YUAN R Y,et al.APCS-MLR model:A convenient and fast method for quantitative identification of nitrate pollution sources in groundwater[J].Journal of Environmental Management,2022,314:115101.
[55]	JIN L,YE H Y,SHI Y S,et al.Using PCA-APCS-MLR model and SIAR model combined with multiple isotopes to quantify the nitrate sources in groundwater of Zhuji,East China[J].Applied Geochemistry,2022,143:105354.
[56]	ZHANG H,CHENG S Q,LI H F,et al.Groundwater pollution source identification and apportionment using PMF and PCA-APCA-MLR receptor models in a typical mixed land-use area in Southwestern China[J].Science of The Total Environment,2020,741:140383.
[57]	MILLER M S,FRIEDLANDER S K,HIDY G M.A chemical element balance for the pasadena aerosol[J].Journal of Colloid and Interface Science,1972,39(1):165-176.
[58]	PHILLIPS D L.Mixing models in analyses of diet using multiple stable isotopes:a critique[J].Oecologia,2001,127(2):166-170.
[59]	PHILLIPS D L,GREGG J W.Uncertainty in source partitioning using stable isotopes[J].Oecologia,2001,127(2):171-179.
[60]	PHILLIPS D L,KOCH P L.Incorporating concentration dependence in stable isotope mixing models[J].Oecologia,2002,130(1):114-125.
[61]	KOCH P L,PHILLIPS D L.Incorporating concentration dependence in stable isotope mixing models:a reply to Robbins,Hilderbrand and Farley (2002)[J].Oecologia,2002,133(1):14-18.
[62]	PHILLIPS D L,GREGG J W.Source partitioning using stable isotopes:coping with too many sources[J].Oeclogia,2003,136(2):261-269.
[63]	PHILLIPS D L,NEWSOME S D,GREGG J W.Combining sources in stable isotope mixing models:alternative methods[J].Oecologia,2005,144(4):520-527.
[64]	ZHANG Y,SHI P,SONG J X,et al.Application of nitrogen and oxygen isotopes for source and fate identification of nitrate pollution in surface water:a review[J].Applied Sciences,2019,9(1):18.
[65]	MOORE J W,SEMMENS B X.Incorporating uncertainty and prior information into stable isotope mixing models[J].Ecology Letters,2008,11(5):470-480.
[66]	JACKSON A L,INGER R,BEARHOP S,et al.Erroneous behaviour of MixSIR,a recently published Bayesian isotope mixing model:a discussion of Moore & Semmens (2008)[J].Ecology Letters,2009,12(3):E1-E5.
[67]	SEMMENS B X,MOORE J W,WARD E J.Improving Bayesian isotope mixing models:a response to Jackson et al.(2009)[J].Ecology Letters,2009,12(3):E6-E8.
[68]	王锐,章新平,戴军杰,等.亚热带湿润区樟树吸水的土层来源及研究方法对比[J].水土保持学报,2020,34(5):267-276.
[69]	NOSRATI K,COLLINS A L,MADANKAN M.Fingerprinting sub-basin spatial sediment sources using different multivariate statistical techniques and the Modified MixSIR model[J].CATENA,2018,164:32-43.
[70]	PARNELL A C,INGER R,BEARHOP S,et al.Source partitioning using stable isotopes:coping with too much variation[J].PLoS One,2010,5(3):e9672.
[71]	ZHANG J,CAO M D,JIN M G,et al.Identifying the source and transformation of riverine nitrates in a karst watershed,North China:comprehensive use of major ions,multiple isotopes and a Bayesian model[J].Journal of Contaminant Hydrology,2022,246:103957.
[72]	HUANG X Y,ZHANG D,ZHAO Z Q,et al.Determining hydrogeological and anthropogenic controls on N pollution in groundwater beneath piedmont alluvial fans using multi-isotope data[J].Journal of Geochemical Exploration,2021,229:106844.
[73]	STOCK B C,JACKSON A L,WARD E J,et al.Analyzing mixing systems using a new generation of Bayesian tracer mixing models[J].PeerJ,2018,6:e5096.
[74]	MING X X,GROVES C,WU X Y,et al.Nitrate migration and transformations in groundwater quantified by dual nitrate isotopes and hydrochemistry in a karst World Heritage site[J].Science of the Total Environment,2020,735:138907.
[75]	XUE D M,De BAETS B,Van CLEEMPUT O,et al.Use of a Bayesian isotope mixing model to estimate proportional contributions of multiple nitrate sources in surface water[J].Environmental Pollution,2012,161:43-49.
[76]	JI X L,SHU L L,CHEN W L,et al.Nitrate pollution source apportionment,uncertainty and sensitivity analysis across a rural-urban river network based on δ¹⁵N/δ¹⁸O-NO₃^- isotopes and SIAR modeling[J].Journal of Hazardous Materials,2022,438:129480.